无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (12): 5-.

• 论文 • 上一篇    下一篇

新型储氢材料三氢化铝的研究进展

唐安江,史永永,潘红艳,段延萍,杜旭,汤正河   

  1. 贵州大学化学与化工学院,贵州贵阳 550003
  • 发布日期:2011-12-06

Research progress in new hydrogen storage material AlH3

TANG  An-Jiang, SHI  Yong-Yong, PAN  Hong-Yan, DUAN  Yan-Ping, DU  Xu, TANG  Zheng-He   

  1. School of Chemistry and Chemical Engineering,Guizhou University,Guiyang 550003,China
  • Online:2011-12-06

摘要: 近年来,三氢化铝作为一种理想的氢能源载体,由于其较高的储氢量(理论含氢质量分数达10%)和经过改性后可实现低于100 ℃稳定放氢,成为国内外储氢材料的研究热点。对三氢化铝的性质(物理化学性质),以及合成方法(液相间接合成法、固相直接合成法等)、改性方法(物理改性和化学掺杂改性)、应用方面(在火箭复合固体推进剂中的应用、在燃料电池车氢气储藏技术中的应用)的最新进展进行了综述,并指出其发展趋势。

关键词: 三氢化铝, 储氢材料, 合成方法, 改性, 应用

Abstract: AlH3(aluminium trihydride),as an ideal hydrogen carrier,has been received much attention in China and abroad due to a higher hydrogen storage capacity (theoretical mass fraction of hydrogen storage capacity reached 10%) and stable H2 release rate below 100 ℃ after modification.Properties (physicochemical property),synthesis methods (liquid phase indirect synthesis and solid phase direct synthesis etc.),modifications (physical modification and chemical doping modification),and application (the application in rocket composite solid propellant and the application in the hydrogen storage technology of fuel cell vehicles) of AlH3 were summarized and the trend of the hydrogen storage technology was also pointed ont.

Key words: aluminium trihydride, hydrogen storage material, synthesis methods, modification, application

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