无机盐工业 ›› 2024, Vol. 56 ›› Issue (9): 44-53.doi: 10.19964/j.issn.1006-4990.2023-0575
田朋1(), 张浩然1, 徐金钢1, 牟晨曦1, 徐前进2, 宁桂玲1
收稿日期:
2023-11-30
出版日期:
2024-09-10
发布日期:
2024-02-18
作者简介:
田朋(1983— ),博士,副教授,主要研究方向是氧化铝精细化学品的开发与工业化基础;E-mail:tianpeng@dlut.edu.cn。
基金资助:
TIAN Peng1(), ZHANG Haoran1, XU Jingang1, MOU Chenxi1, XU Qianjin2, NING Guiling1
Received:
2023-11-30
Published:
2024-09-10
Online:
2024-02-18
摘要:
随着电动汽车和清洁能源的发展,对锂离子电池的储能能力和循环寿命提出了更高的要求。采用氧化铝溶胶浸渍-包覆法对NCM811正极材料和G/SiO负极材料进行改性。此方法与硝酸铝浸渍法相比热分解产生的氮氧化物量降低99%以上,相较于沉淀法无副产物,成本低于有机铝盐法,均匀性高于干法混合,易于实现规模化生产。表征发现氧化铝溶胶的加入并不会影响正负极材料的结构和充放电机理。电化学性能测试表明,当氧化铝添加量分别为0.3%和0.7%(质量分数)时,可以分别使得正极材料NCM811和负极材料G/SiO获得最优的倍率性能和循环稳定性能。在1C充放电下,将NCM811和0.3%氧化铝改性的NCM811分别与锂片组装成锂离子电池后循环100次,其容量分别为123.55 mA·h/g和151.02 mA·h/g。在0.1C充放电下,将G/SiO负极和0.7%氧化铝改性的G/SiO负极分别与锂片组装成锂离子电池后循环45次,其容量分别为360.57 mA·h/g和385.06 mA·h/g。
中图分类号:
田朋, 张浩然, 徐金钢, 牟晨曦, 徐前进, 宁桂玲. 氧化铝溶胶改性锂离子电池正负极材料的研究[J]. 无机盐工业, 2024, 56(9): 44-53.
TIAN Peng, ZHANG Haoran, XU Jingang, MOU Chenxi, XU Qianjin, NING Guiling. Study on aluminum sol modified anode and cathode materials for lithium ion batteries[J]. Inorganic Chemicals Industry, 2024, 56(9): 44-53.
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