中国含硼无机产品60年发展历程及未来发展趋势

doi:10.11962/1006-4990.2020-0492

摘要/Abstract

摘要：

总结概况了中国含硼无机产品60 a来的发展历程。中国含硼无机产品经历了从硼酸、硼砂工业的诞生到碳化硼、氮化硼等各类含硼新材料新产品的开发生产,经历了从工艺路线的不断更新到新工艺、新装备的趋于完善。但是,目前中国高品位硼资源日趋紧缺,环境保护更加严格,基础硼产品竞争力弱。基于国内外发展现状展望了含硼无机产品的未来发展趋势。指出中国的硼化工企业应充分利用国外进口的基础硼产品,以市场为导向,结合国家重大战略需求,生产高附加值硼产品和含硼材料,比如含硼导热及耐高温材料、含硼新能源材料、含硼催化材料等。

关键词: 硼化物, 技术, 发展趋势

Abstract:

From the perspective of respecting history and looking forward to the future,the development of boron containing inorganic products in China in the past 60 years were summarized.The history from the birth of boric acid and borax industry to the development and production of various boron containing new materials and new products such as boron carbide and boron nitride et al was introduced.Also the development of the industry from the continuous updating of process routes to the improvement of new processes and new equipment was reviewed.However,China′s high-grade boron resources are increasingly scarce,environmental protection is more stringent,and the competitiveness of basic boron products is weak.Based on the current development status at home and abroad,the future development trend of boron containing inorganic products was prosepected.It was indicated that China′s boron chemical enterprises should make full use of the basic boron products imported from abroad,take the market as the guidance and combine with the major strategic needs of the country to produce high value-added boron products and boron containing materials,such as boron containing thermal conductive and high temperature resistant materials,boron containing new energy materials,boron containing catalytic materials,etc.

Key words: boron compounds, technology, development trend

中图分类号:

TQ128

仲剑初,宁桂玲. 中国含硼无机产品60年发展历程及未来发展趋势[J]. 无机盐工业, 2020, 52(10): 1-8.

Zhong Jianchu,Ning Guiling. Future trend and development course of inorganic boron compounds for sixty years in China[J]. Inorganic Chemicals Industry, 2020, 52(10): 1-8.

参考文献 41

[1]	陶连印. 国内硼砂(酸)工业生产概况及展望[J]. 无机盐工业, 1981(2):50-53.
[2]	冉启培. 庆祝中国硼工业建立45周年[J]. 辽宁化工, 2001,30(7):280-281.
[3]	余盛纲. 自贡盐化工生产及其展望[J]. 井矿盐技术, 1980(4):49-51.
[4]	陶连印. 我国硼工业建立45周年回顾与展望[J]. 辽宁化工, 2001,30(7):278-279.
[5]	吕宗凯, 张承泽. 再谈高台沟硼矿地质特征及其成因[J]. 吉林地质, 1985(3):62-66.
[6]	冉启培, 姚樾, 郑学家, 等. 硼化物的制造与应用[M]. 沈阳: 辽宁科技出版社, 1985.
[7]	王文侠, 严芝兰. 青藏地区硼资源的开发利用[J]. 青海科技, 2002(2):25-26.
[8]	李国忠. 45年的历程45年的丰碑——纪念中国硼工业建立45周年[J]. 辽宁化工, 2001,30(7):282-283,286.
[9]	沈阳市农药厂. 碳碱法生产硼砂[J]. 辽宁化工, 1977(5):16-18.
[10]	全跃, 曲勃, 仲剑初, 等. 硼及硼产品研究与进展[M]. 大连: 大连理工大学出版社, 2008.
[11]	王彦顺. 碳化硼合成工艺及其产业化[J]. 辽宁化工, 2014,43(7):880-882.
[12]	程宪惠. 密压机在硼砂生产上的应用[J]. 无机盐工业, 1984(4):29-31.
[13]	王丕林. 用硼砂厂废弃硼泥制造砖瓦[J]. 辽宁城乡科技, 1997,17(1):73-74.
[14]	于俊生, 岳龙泉, 刘律镁. TN1150/1200型压滤机在硼砂生产中的应用及其技术经济分析[J]. 工业技术经济, 1990(10):83-85.
[15]	屈晓梅, 岳龙泉, 解绍芹. 硼砂生产中无蒸发工艺的应用及其经济效果[J]. 工业技术经济, 1990(10):81-83.
[16]	李英堂, 简少芳, 李琦, 等. 辽宁凤城翁泉沟含铀铁硼矿综合利用半工业试验[C]// 中国地质科学院文集(1995中英文合订本), 1995: 78-81.
[17]	陈楼. 试剂优级纯硼酸已批量生产[J]. 化学世界, 1983(4):38.
[18]	葛秀萍. 多硼酸钠-硫酸法生产硼酸新工艺[J]. 无机盐工业, 1984(10):21-24.
[19]	刘其昌. 硼酸锌试生产技术鉴定会在镇江召开[J]. 无机盐工业, 1987(4):38.
[20]	凤城硼矿. 东台子硼镁铁矿石生产硼砂的工业试验[J]. 化工矿山技术, 1991(6):56.
[21]	杨军, 郑学家, 仲剑初. 含铀硼铁矿及其应用[M]. 北京: 化学工业出版社, 2017.
[22]	辽宁化工. 硼-10酸合成中试通过鉴定[J]. 辽宁化工, 1993(1):61.
[23]	孙效信. 一步法硼酸钙试生产成功[J]. 无机盐工业, 1993(3):46.
[24]	张浩. 高纯氯化锂联产高纯硼酸项目试车成功[J]. 化工管理, 2015(34):78.
[25]	沈镇平. 牡丹江碳化硼产业形成规模[J]. 杭州化工, 2004,34(2):29.
[26]	Cai Q, Scullion D, Gan W, et al. High thermal conductivity of highquality monolayer boron nitride and its thermal expansion[J]. Science Advances, 2019,5(6):eaav0129.
[27]	Dames C. Ultrahigh thermal conductivity confirmed in boron arsenide[J]. Science, 2018,361(6402):549-550.
[28]	彭易发, 李争显, 陈云飞, 等. 硼化物超高温陶瓷的研究进展[J]. 陶瓷学报, 2018,39(2):119-126.
[29]	Jie H, Luzin V, Zaman M, et al. Evaluation of isotopic boron (¹¹B) for the fabrication of low activation Mg¹¹B₂ superconductor for next generation fusion magnets[J]. Journal of the American Ceramic Society, 2020,103(10):5488-5495.
[30]	王建萍, 杨华春, 叶家铭. 新型锂盐二氟草酸硼酸锂制备工艺研究进展[J]. 河南化工, 2020,37(5):9-12.
[31]	孙海峰, 卓军. 热电池阳极材料锂硼合金研究进展[J]. 材料导报, 2017,31(S1):195-197.
[32]	Loiland J A, Zhao Z, Patel A, et al. Boron-containing catalysts for the oxidative dehydrogenation of ethane/propane mixtures[J]. Industrial & Engineering Chemistry Research, 2019,58(6):2170-2180.
[33]	Lu W D, Wang D, Zhao Z, et al. Supported boron oxide catalysts for selective and low-temperature oxidative dehydrogenation of propane[J]. ACS Catalysis, 2019,9(9):8263-8270.
[34]	Pasupulety N, Daous M A, Al-Zahrani A A, et al. Alumina-boron catalysts for oxidative dehydrogenation of ethylbenzene to styrene:Influence of alumina-boron composition and method of preparation on catalysts properties[J]. Chinese Journal of Catalysis, 2019,40(11):1758-1765.
[35]	苏静, 王艳辉, 董亮, 等. 碳化硅和碳化硼在电催化中的应用[J]. 无机化学学报, 2018,34(1):1-10.
[36]	卢一鑫, 杨森林, 赵小侠. 基于三硼酸锂晶体高功率紫外脉冲激光器[J]. 激光技术, 2018,42(1):100-103.
[37]	Kara U, Susoy G, Issa S A M, et al. Scanning electron microscopy (SEM),energy-dispersive X-ray(EDX) spectroscopy and nuclear radiation shielding properties of[α-Fe³+O(OH)]-doped lithium borate glasses[J]. Applied Physics A:Materials Science & Processing, 2020,126(7):185-195.
[38]	任晓剑, 樊自拴. 硼化物金属陶瓷涂层的研究进展[J]. 材料保护, 2018,51(1):90-95.
[39]	Verma P C, Mishra S K. Synjournal of iron boride powder by carbothermic reduction method[J]. Materials Today:Proceedings, 2020,28:902-906.
[40]	许少文, 贾帆豪, 乔磊, 等. 稀土六硼化物的研究进展[J]. 中国材料进展, 2020,39(2):124-132.
[41]	杨芳, 闫果, 李少强, 等. 三元硼化物 AlMgB₁₄ 超硬材料的研究进展[J]. 稀有金属材料与工程, 2016,45(4):1088-1092.

首页

全国无机盐信息中心

中国化工学会

无机酸碱盐专业委员会