无机盐工业 ›› 2022, Vol. 54 ›› Issue (2): 21-29.doi: 10.19964/j.issn.1006-4990.2021-0266
赵元元1(), 陈海峰1, 刘云云1, 张宏1, 吴勇民2, 张竞择2, 汤卫平2(
)
收稿日期:
2021-05-19
出版日期:
2022-02-10
发布日期:
2022-03-14
通讯作者:
汤卫平(1962— ),男,博士,主要研究方向为锂离子筛和储能电池;E-mail: Tangwp@sina.cn。作者简介:
赵元元(1996— ),男,硕士研究生,主要研究方向为盐湖提锂;E-mail: 1905061@sust.edu.cn。
ZHAO Yuanyuan1(), CHEN Haifeng1, LIU Yunyun1, ZHANG Hong1, WU Yongmin2, ZHANG Jingze2, TANG Weiping2(
)
Received:
2021-05-19
Published:
2022-02-10
Online:
2022-03-14
摘要:
随着新能源电动汽车、储能产业的快速发展,确保锂资源的供给成为热点话题。锰系锂离子筛因其有对锂离子的高选择性、高吸附量、低成本等优点,在盐湖提锂方面已成为最具发展潜力的吸附剂材料之一,然而其在循环吸、脱附过程中,锰的溶损以及Jahn-Teller效应等问题会影响离子筛结构的稳定性,使吸附剂的吸附性能降低。近年来,围绕吸附性能提升,从制备方法方面进行改良的研究工作很多,可通过不同的制备方法调控锂离子筛的结构和形态。针对其存在的问题,总结了可以改善其性能的方法,包括掺杂、表面包覆以及造粒和成膜等,并在此基础上对改性锂离子筛材料在工业应用方面的发展方向进行展望,制备出高数量级循环下稳定的锂离子筛材料是未来的主要发展方向。
中图分类号:
赵元元, 陈海峰, 刘云云, 张宏, 吴勇民, 张竞择, 汤卫平. 锰系锂离子筛的制备与改性的研究进展[J]. 无机盐工业, 2022, 54(2): 21-29.
ZHAO Yuanyuan, CHEN Haifeng, LIU Yunyun, ZHANG Hong, WU Yongmin, ZHANG Jingze, TANG Weiping. Research progress on preparation and modification of manganese based lithium ion sieve[J]. Inorganic Chemicals Industry, 2022, 54(2): 21-29.
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