铝基锂吸附剂造粒工艺优化及其原卤提锂性能研究

doi:10.19964/j.issn.1006-4990.2024-0155

无机盐工业 ›› 2025, Vol. 57 ›› Issue (3): 36-42.doi: 10.19964/j.issn.1006-4990.2024-0155

铝基锂吸附剂造粒工艺优化及其原卤提锂性能研究

王敏锐¹^,²(), 田桂英¹^,², 张奥¹^,², 葛俊杰¹^,², 张蕾¹^,², 项军¹^,², 唐娜¹^,²()

1.天津科技大学化工与材料学院，天津 300457
2.天津市卤水化工与资源生态化利用重点实验室，天津 300457

收稿日期:2024-03-19 出版日期:2025-03-10 发布日期:2024-05-17
通讯作者: 唐娜（1972— ），女，博士，教授，博士研究生导师，主要从事海卤水资源综合利用、膜与膜过程的研究；E-mail：tjtangna@tust.edu.cn。
作者简介:王敏锐（1999— ），女，硕士，主要从事海卤水资源综合利用；E-mail：luilui1128@163.com。
基金资助:
国家自然科学基金项目(U20A20148)

Study on granulation optimization for Al-based lithium adsorbent and its lithium recovery performance from brine

WANG Minrui¹^,²(), TIAN Guiying¹^,², ZHANG Ao¹^,², GE Junjie¹^,², ZHANG Lei¹^,², XIANG Jun¹^,², TANG Na¹^,²()

1. College of Chemical Engineering and Material Science，Tianjin University of Science and Technology，Tianjin 300457，China
2. Tianjin Key Laboratory of Brine Chemical Engineering and Resource Eco-utilization，Tianjin 300457，China

Received:2024-03-19 Published:2025-03-10 Online:2024-05-17

摘要/Abstract

摘要：

铝基锂吸附剂因其对盐湖卤水中的Li⁺具有高选择性、快速吸/脱附和清水洗脱等优势而被应用于工业化提锂，但仍需进一步优化吸附剂的固定化特性和循环稳定性。基于均相沉淀工艺，利用尿素作为沉淀剂制备了层状双氢氧化物-LiAl₂（OH）₇·2H₂O（LDH）粉末，对其进行注射造粒得到吸附剂颗粒，考察了吸附性能、结构稳定性能和循环使用性能。研究结果表明，醋酸纤维素和NaHCO₃可优选作为黏合剂和成孔剂，所得最优粉末状LDH和颗粒状GLDH-1的静态吸附容量分别为7.90 mg/g和7.40 mg/g，表明造粒后多孔负载结构有效改善了黏结剂包埋活性位点的问题，且吸附容量并未显著下降。除此之外，对GLDH-1进行了动态吸附和循环性能测试，对结则茶卡盐湖原卤的动态锂吸附动力学符合准二级吸附行为，并且循环使用15次后，GLDH-1仍能保持首次容量的77%。由此可知，使用醋酸纤维素黏合剂和NaHCO₃成孔剂的注射造粒技术可有效提高铝基锂吸附剂颗粒的提锂性能。

关键词: 铝基锂吸附剂, 层状双氢氧化物, 成孔剂, 注射造粒

Abstract:

Currently，Al-based lithium adsorbent has been employed for large-scale industrial application，due to its high selectivity in original brine and fast adsorption rate using water elution，but it is also necessary to further improve absorption capacity and cycling performance.In this study，layered double hydroxide LiAl₂（OH）₇•2H₂O（LDH） powders were prepared based on a homogeneous precipitation process using urea precipitant，and injection granulation was performed to obtain adsorbent particles，and the adsorption performance，structural stability performance and recycling performance were investigated.The results showed that cellulose acetate and NaHCO₃ could be considered as the proper binder and porogenic agent，respectively.The static adsorption process proved that the adsorption capacities of powdery and granulated LDH were 7.90 mg/g and 7.40 mg/g，respectively.It was shown that the porous loading structure after granulation effectively improved the problem of binder-embedded active sites，and the adsorption capacity was not significantly decreased.In addition，the dynamic adsorption and recycling performance of GLDH-1 was tested，and the dynamic lithium adsorption kinetics to the original brine of Jiezhe Caka Salt Lake conformed to the pseudo-secondary adsorption behavior，and the GLDH-1 could still maintain 77% of the initial capacity after 15 cycles.In short，the injection granulation technique using cellulose acetate binder and NaHCO₃ porogenic agent could effectively improve the Li-extraction performance of aluminum-based lithium adsorbent particles.

Key words: Al-based lithium adsorbent, layered double hydroxide, porogenic agent, injection granulation

中图分类号:

TQ133.1

王敏锐, 田桂英, 张奥, 葛俊杰, 张蕾, 项军, 唐娜. 铝基锂吸附剂造粒工艺优化及其原卤提锂性能研究[J]. 无机盐工业, 2025, 57(3): 36-42.

WANG Minrui, TIAN Guiying, ZHANG Ao, GE Junjie, ZHANG Lei, XIANG Jun, TANG Na. Study on granulation optimization for Al-based lithium adsorbent and its lithium recovery performance from brine[J]. Inorganic Chemicals Industry, 2025, 57(3): 36-42.

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参考文献 15

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离子	C₀/ （mg·L^-1）	C_e/ （mg·L^-1）	Q_e/ （mg·g^-1）	K/ （L·g^-1）	α
Li⁺	193.83	3.91	7.59	1.95	1.00
Mg²⁺	280.03	249.50	1.22	4.90×10^-3	397.92
K⁺	2 845.13	2 839.00	0.48	1.69×10^-4	11 517.12
Na⁺	49 950.00	49 939.51	0.84	1.68×10^-5	115 992.87

黏合剂类型	w（黏合剂）/ %	吸附容量/ （mg·g^-1）	质量保持率/%
SA	10	3.71	98.98
	15	3.48	99.77
	20	2.89	99.90
PVC	10	3.03	97.83
	15	2.78	99.89
	20	2.35	99.91
CA	10	4.45	99.71
	15	3.56	99.95
	20	2.85	99.96

样品	成孔剂	比表面积/（cm²·g^-1）	孔体积/ （cm³·g^-1）	孔径/ nm
LDH	—	126.00	0.01	7.70
GLDH-0	—	99.51	0.09	11.70
GLDH-1	NaHCO₃	112.45	0.35	19.10
GLDH-2	NaCl	110.32	0.46	17.62

[1]	邹辽, 马小琳, 李小保, 叶菊娣. 木质素/LDH的制备及增强聚氨酯力学性能的研究[J]. 无机盐工业, 2025, 57(1): 64-70.
[2]	陈君,钟静,林森,于建国. 铝基吸附剂固定床分离卤水锂资源过程研究[J]. 无机盐工业, 2023, 55(1): 64-73.
[3]	程鹏高,黄传峰,甘善甜,龚经款,项军,唐娜. 铝基锂吸附剂制备及其在泰和地下卤水提锂中的应用[J]. 无机盐工业, 2021, 53(6): 140-144.

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铝基锂吸附剂造粒工艺优化及其原卤提锂性能研究

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