无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (9): 18-.

• 论文 • 上一篇    下一篇

低品位含钾卤水蒸发结晶制备光卤石工艺研究

郭剑锋1,边红利2,成怀刚1,程芳琴1   

  1. 1.山西大学资源与环境工程研究所,国家环境保护煤炭废弃物资源化高效利用技术重点实验室,
    山西太原030006;2.青海中航资源有限公司
  • 出版日期:2013-09-10 发布日期:2013-09-13

Study on preparation technology of carnallite from low grade potassium-bearing brine by evaporation and crystallization

Guo Jianfeng1,Bian Hongli2,Cheng Huaigang1,Cheng Fangqin1   

  1. 1.State Environmental Protection Key Laboratory on Efficient Resources-Utilization Techniques of Coal Waste,Institute of
    Resources and Environment Engineering,Shanxi University,Taiyuan  030006,China;2.Qinghai CATIC Resources Co.,Ltd.
  • Published:2013-09-10 Online:2013-09-13

摘要: 随着氯化钾生产规模的扩大,高品位含钾卤水资源过量消耗,而低品位含钾卤水采用传统的溶采-盐田晒制光卤石工艺因成矿周期长、成本高、操作复杂使盐湖企业难以为继。以低品位盐湖卤水为研究对象,以相图为指导,通过真空蒸发控速结晶工艺制备光卤石,研究快速结晶成矿技术。实验结果表明,采用蒸发结晶工艺可以制得氯化钾质量分数为13.82%~14.90%的光卤石产品,成矿周期较原工艺加快近1倍。实验考察了镁钾比例、蒸发水量等因素对光卤石产量和品位的影响,结果证实运用真空蒸发控速结晶技术制备光卤石是可行的。

关键词: 低品位含钾卤水, 真空蒸发, 结晶, 光卤石

Abstract: With the expansion of KCl production scale and excessive consumption of high grade potassium-bearing brine resources,the salt lake manufacturers,which adopting traditional solution mining-sun curing process to produce carnallite,are difficult to carry on due to long mineralization period,high production cost,and complicated operation.Taking low grade salt lake brine as the study object,and phase diagram as the guidelines,carnallite was prepared by vacuum evaporation and velocity-controlled crystallization process to study the rapid crystallization and mineralization technology.Results showed the carnallite with mass fraction of 13.82%~14.90%(KCl) could be prepared by the new process and the mineralization speed doubled than that the original process.In addition,the influences of magnesium/potassium proportion and water evaporation amount etc.on the yield and quality of carnallite were investigated.Results proved that it was feasible to employ vacuum evaporation and velocity-controlled crystallization process to produce carnallite.

Key words: low grade potassium-bearing brine, vacuum evaporation, crystallization, carnallite

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