分子筛在挥发性有机物（VOCs） 吸附方面的研究进展

doi:10.19964/j.issn.1006-4990.2021-0736

摘要/Abstract

摘要：

挥发性有机物（VOCs）的去除是目前大气环境治理的主要方向。其中最广泛用于去除VOCs的方法是吸附法，吸附材料的选择是吸附法的关键环节。从分子筛作为吸附材料的角度出发，简单介绍了目前在吸附VOCs方面效果卓越的MCM-41、ZSM-5和NaY 3种分子筛，重点综述了其制备方法及其对各种VOCs的吸附效果。结果表明，分子筛比表面积、孔道、硅铝比、平衡阳离子都会对吸附效果产生影响，可通过负载贵金属或金属氧化物、表面改性处理、复合材料、结构调整等方式优化分子筛吸附性能。未来，高吸附量、高疏水性、绿色环保和低成本可再生的新型分子筛在VOCs的吸附方面将有更广阔的前景。

关键词: 分子筛, 制备, 吸附, 挥发性有机化合物

Abstract:

Trapping volatile organic compounds（VOCs） is currently the primary focus of atmospheric environmental management.Adsorption is one of the most widely used methods for removing VOCs，and the selection of adsorption material is the key link in adsorption method.From the perspective of adsorption materials of zeolites，three kinds of zeolites，MCM-41，ZSM-5 and NaY，which had excellent effects in adsorbing VOCs，were briefly introduced.The research progress on preparation methods and their adsorption effects on various VOCs were mainly reviewed.The results showed that the specific surface area，the pore channel，the silica-alumina ratio and the equilibrium cation of zeolites all affected the adsorption effect and that the performance of the zeolites could be optimized by loading precious metals or oxides，surface modification treatment，composite materials and structural adjustment.In the future，the new zeolites with high adsorption capacity，high hydrophobicity，green and low-cost regenerable would have a broader prospect application in the adsorption of VOCs.

Key words: zeolites, preparation, adsorption, volatile organic compounds

中图分类号:

TQ424.2

朱元璐,高明,闫江毅,王北福. 分子筛在挥发性有机物（VOCs）吸附方面的研究进展[J]. 无机盐工业, 2022, 54(11): 32-38.

ZHU Yuanlu,GAO Ming,YAN Jiangyi,WANG Beifu. Research progress on volatile organic compounds（VOCs） adsorption by zeolites[J]. Inorganic Chemicals Industry, 2022, 54(11): 32-38.

图/表 6

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参考文献 38

1	GELLES T, KRISHNAMURTHY A, ADEBAYO B, et al.Abatement of gaseous volatile organic compounds：A material perspective[J].Catalysis Today,2020,350: 3-18.
2	KRISHNAMURTHY A, ADEBAYO B, GELLES T, et al.Abatement of gaseous volatile organic compounds：A process perspecti- ve[J].Catalysis Today,2020,350: 100-119.
3	LI Xiuquan, ZHANG Li, YANG Zhongqing, et al.Adsorption materials for volatile organic compounds（VOCs） and the key factors for VOCs adsorption process：A review[J].Separation and Purification Technology,2020,235.Doi:10.1016/j.seppur.2019.116213.
4	ROTHER J, FIEBACK T.Multicomponent adsorption measurements on activated carbon，zeolite molecular sieve and metal-organic framework[J].Adsorption,2013,19(5):1065-1074.
5	薛梦婷,李勇.VOCs在分子筛上吸附性能的研究进展[J].无机盐工业,2019,51(5):12-16.
	XUE Mengting, LI Yong.Research progress on adsorption properties of volatile organic compounds on molecular sieves[J].Inorganic Chemicals Industry,2019,51(5):12-16.
6	LYE J W P, SAMAN N, NOOR A M M, et al.Application of nanoscale zero-valent iron-loaded natural zeolite for tetracycline removal process[J].Chemical Engineering & Technology,2020,43(7):1285-1296.
7	COSTA J A S, DE JESUS R A, SANTOS D O, et al.Recent progresses in the adsorption of organic，inorganic，and gas compounds by MCM-41-based mesoporous materials[J].Microporous and Mesoporous Materials,2020,291.Doi:10.1016/j.micromeso.2019.109698.
8	COSTA J A S, DE JESUS R A, SILVA C M P DA, et al.Efficient adsorption of a mixture of polycyclic aromatic hydrocarbons （PAHs） by Si-MCM-41 mesoporous molecular sieve[J].Powder Technology,2017,308: 434-441.
9	MA C M, RUAN Ritian.Adsorption of toluene on mesoporous materials from waste solar panel as silica source[J].Applied Clay Science,2013,80/81: 196-201.
10	HU Yun, HE Yinyun, WANG Xiaowen, et al.Efficient adsorption of phenanthrene by simply synthesized hydrophobic MCM-41 molecular sieves[J].Applied Surface Science,2014,311: 825-830.
11	VETRIVEL S, CHEN C T, KAO H M.The ultrafast sonochemical synthesis of mesoporous silica MCM-41[J].New Journal of Chemistry,2010,34(10):2109-2112.
12	SADEGHI M, YEKTA S, GHAEDI H.Synthesis and application of Pb-MCM-41/ZnNiO₂ as a novel mesoporous nanocomposite adsorbent for the decontamination of chloroethyl phenyl sulfide（CEPS）[J].Applied Surface Science,2017,400: 471-480.
13	LIN Ruya, LIANG Zhijie, YANG Chun, et al.Selective and enhanced adsorption of the monosubstituted benzenes on the Fe-modified MCM-41：Contribution of the substituent groups[J].Chemosphere,2019,237.Doi:10.1016/J.CHEMOSPHERE.2019.124546.
14	ZHOU Yanni, LIU Haiyan, RAO Xiaorong, et al.Controlled synthesis of ZSM-5 zeolite with an unusual Al distribution in framework from natural aluminosilicate mineral[J].Microporous and Mesoporous Materials,2020,305.Doi:10.1016/j.micromeso.2020.110357.
15	张凯,杨仕超,罗敏,等.纳米片层状ZSM-5分子筛制备及其对室内环境VOCs吸附性能[J].环境工程,2020,38(1):60-64，74.
	ZHANG Kai, YANG Shichao, LUO Min, et al.Preparation of nano-sheet ZSM-5 zeolite and its adsorption properties for indoor environment VOCs[J].Environmental Engineering,2020,38(1):60-64，74.
16	高君安,王伟,张傑,等.用于高湿度废气中甲苯吸附净化的疏水型ZSM-5分子筛的合成及其吸附性能研究[J].化工学报,2020,71(1):337-343.
	GAO Junan, WANG Wei, ZHANG Jie, et al.Study on synthesis and adsorption performance of hydrophobic ZSM-5 zeolites for removal of toluene in high-humidity exhaust gas[J].CIESC Journal,2020,71(1):337-343.
17	高君安,李想,史东军,等.ZSM-5分子筛蜂窝状成型工艺及其吸附甲苯的性能研究[J].现代化工,2020,40(6):123-127.
	GAO Junan, LI Xiang, SHI Dongjun, et al.Honeycomb molding process of ZSM-5 molecular sieves and adsorption to toluene[J].Modern Chemical Industry,2020,40(6):123-127.
18	HUANG Daojian, HU Xiaomei, ZHAO Cheng, et al.Synthesis of mesoporous ZSM-5 zeolite and its adsorption properties for VOCs[J].IOP Conference Series：Earth and Environmental Science,2020,514(5).Doi:10.1088/1755-1315/514/5/052008.
19	DAI Jiqiang, ZHAO Cheng, HU Xiaomei, et al.One-pot synthesis of meso-microporous ZSM-5 and its excellent performance in VOCs adsorption/desorption[J].Journal of Chemical Technology & Biotechnology,2021,96(1):78-87.
20	张海明.利用粉煤灰制备多级孔ZSM-5分子筛/聚合物复合材料及其吸附VOCs的研究[D].青岛：青岛科技大学，2020.
	ZHANG Haiming.Study on preparation of a hierarchical porosity ZSM-5 zeolite/polymer composites using coal fly ash and adsorption of VOCs[D].Qingdao：Qingdao University of Science & Technology，2020.
21	刘雷璐.高硅ZSM-5分子筛的固相研磨法合成及其VOCs吸附性能研究[D].广州：华南理工大学，2020.
	LIU Leilu.Solid phase grinding synthesis of high-silica ZSM-5 zeolites and its adsorption properties of VOCs[D].Guangzhou：South China University of Technology，2020.
22	LI Renna, XUE Tianshan, LI Zhe, et al.Hierarchical structure ZSM-5/SBA-15 composite with improved hydrophobicity for ad-sorption-desorption behavior of toluene[J].Chemical Engineering Journal,2020,392.Doi:10.1016/j.cej.2020.124861.
23	LI Renna, CHONG Shijia, ALTAF N, et al.Synthesis of ZSM-5/siliceous zeolite composites for improvement of hydrophobic adsorption of volatile organic compounds[J].Frontiers in Chemistry,2019,7.Doi:10.3389/fchem.2019.00505.
24	WU Shuhui, WANG Yaquan, SUN Chao, et al.Novel preparation of binder-free Y/ZSM-5 zeolite composites for VOCs adsorpti-on[J].Chemical Engineering Journal,2021,417.Doi:10.1016/J.CEJ.2021.129172.
25	HAJITABAR FIROUZJAIE M, TAGHIZADEH M.Synthesis procedure and industrial applications of NaY zeolite for various processes：A review[J].Mini-Reviews in Organic Chemistry,2020,17(7):795-804..
26	王玉冰,王辉国.Y分子筛上间二甲苯的吸附分离[J].石油化工,2019,48(6):570-574.
	WANG Yubing, WANG Huiguo.Meta-Xylene adsorptive separation performance of Y zeolite[J].Petrochemical Technology,2019,48(6):570-574.
27	ZHANG Weiwei, QU Zhenping, LI Xinyong, et al.Comparison of dynamic adsorption/desorption characteristics of toluene on different porous materials[J].Journal of Environmental Sciences,2012,24(3):520-528.
28	薛梦婷.NaY分子筛吸附剂的制备及其对挥发性有机物的吸附效果研究[D].苏州：苏州科技大学，2019.
	XUE Mengting.Preparation of NaY zeolite adsorbent and its adsorption effect on volatile organic compounds[D].Suzhou：Suzhou University of Science and Technology，2019.
29	LV Yuting, SUN Jing, YU Guanqun, et al.Hydrophobic design of adsorbent for VOC removal in humid environment and quick regeneration by microwave[J].Microporous and Mesoporous Materials,2020,294.Doi:10.1016/j.micromeso.2019.109869.
30	张媛媛.疏水性硅基吸附剂的制备及VOCs吸附性能研究[D].成都：西南交通大学，2017.
	ZHANG Yuanyuan.Preparation of hydrophobic silicon-based adsorbents and their VOCs adsorption properties[D].Chengdu：Southwest Jiaotong University，2017.
31	万晓蕊,初春雨,白国强,等.苯在酸碱处理多级孔Y分子筛上的吸附及传质行为[J].燃料化学学报,2016,44(5):634-640.
	WAN Xiaorui, CHU Chunyu, BAI Guoqiang, et al.Adsorption and mass transfer behavior of benzene on hierarchically structured Y by acid-base treatment[J].Journal of Fuel Chemistry and Technology,2016,44(5):634-640.
32	FENG Aihu, MI Le, YU Yang, et al.Development of intracrystalline mesoporosity in NH₄HF₂-etched NaY zeolites by surfactant-templating and its effect on toluene adsorption[J].Chemical Engineering Journal,2020,390.Doi:10.1016/j.cej.2020.124529.
33	WU Xianghua, YANG Xing, YANG Hu, et al.Hierarchically structured PVP porous fibers derived from the embedding of NaY zeolite synergize the adsorption of benzene[J].Composites Part B：Engineering,2019,179.Doi:10.1016/j.compositesb.2019.107542.
34	GAO Kai, WANG Qing, DU Xuexun, et al.Efficient adsorption and eco-environmental oxidization of dimethylamine in beta zeolite[J].Microporous and Mesoporous Materials,2019,282: 219-227
35	孙慧.丝光沸石分子筛的合成及其吸附VOCs性能的研究[D].苏州：苏州科技大学，2017.
	SUN Hui.Synthesis of mordenite zeolite and the research of the adsorption performance of VOCs[D].Suzhou：Suzhou University of Science and Technology，2017.
36	SELZER C, WERNER A, KASKEL S.Selective adsorption of propene over propane on hierarchical zeolite ZSM-58[J].Industrial & Engineering Chemistry Research,2018,57(19):6609-6617.
37	LIU Yutong, TIAN Tao.Fabrication of diatomite/silicalite-1 composites and their property for VOCs adsorption[J].Materials,2019,12(4).Doi:10.3390/ma12040551.
38	LI Xianfeng, WANG Jian, GUO Yangyang, et al.Adsorption and desorption characteristics of hydrophobic hierarchical zeolites for the removal of volatile organic compounds[J].Chemical Engineering Journal,2021,411.Doi:10.1016/j.cej.2021.128558.

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