水系锌离子电池的研究和产业化进展

doi:10.19964/j.issn.1006-4990.2021-0707

摘要/Abstract

摘要：

水系锌离子电池是一种新型的绿色电池体系,不仅具有廉价、安全、环保的特点,还具有较高的功率密度,在储能等诸多领域具有很好的应用价值和发展前景。综述了水系锌离子电池正极材料、锌负极和电解液的基础研究和产业化进展,包括二氧化锰正极材料开发、电池器件制备和应用。总结了目前水系锌离子电池产业化的可行性和难点。提出了亟需解决的3个关键问题：首先,水系锌离子电池体系的反应机理仍需深入研究以指导高性能正负极材料开发;其次,高纯度二氧化锰正极材料、耐腐蚀集流体、耐刺穿隔膜等产业链关键环节缺失制约了商业化电池的开发;最后,从实验室到中试及规模化放大过程中电池性能明显降低,系统的电极制备和电池组装工艺仍需系统化研究。

关键词: 水系锌离子电池, 正极材料, 锌负极, 产业化

Abstract:

Aqueous zinc ion battery is a novel battery system with the characters of low price,safety,environmental friendly,as well as high power density,which has good application value and development prospect in many fields such as energy stor-age.The progress of the basic research and industrialization of aqueous zinc ion battery was summarized from the aspects of cathodes,zinc anode,and electrolyte,and the industrial development of manganese dioxide cathode materials,battery assem-bly and application technologies were introduced.The feasibility and difficulties for future research and industrial development were highlighted.Three main issues that needed to be urgently solved were proposed.Firstly,the energy storage mechanism of aqueous zinc ion battery system was still needed in-depth study,which was important to guide the design of high performance cathode and anode materials.Secondly,the lack of key links in the industrial chain such as high-purity manganese dioxide cathode material,corrosion-resistant collector and puncture resistant diaphragm restricted the development of commercial batteries.Finally,from laboratory to pilot test and large-scale amplification,the battery performance was significantly reduced, and the systematic electrode preparation and battery assembly process was still needed systematic research.

Key words: aqueous zinc ion battery, cathode material, Zn anode, industrialization

中图分类号:

TQ15

魏春光,梁燕,李曈,吕伟. 水系锌离子电池的研究和产业化进展[J]. 无机盐工业, 2022, 54(3): 18-22.

WEI Chunguang,LIANG Yan,LI Tong,LÜ Wei. Research and industrialization progress of aqueous zinc ion battery[J]. Inorganic Chemicals Industry, 2022, 54(3): 18-22.

图/表 5

参考文献 38

[1]	田崔钧, 田君, 陈芬, 等. 锂离子电池安全性测试分析[J]. 重庆理工大学学报:自然科学, 2018, 32(10):34-39.
[2]	BECK F, RÜETSCHI P. Rechargeable batteries with aqueous elec-trolytes[J]. Electrochimica Acta, 2000, 45(15):2467-2482. doi: 10.1016/S0013-4686(00)00344-3
[3]	HUANG Jianhang, GUO Zhaowei, MA Yuanyuan, et al. Recent pro-gress of rechargeable batteries using mild aqueous electrolytes[J]. Small Methods, 2019, 3(1).Doi: 10.1002/smtd.201800272. doi: 10.1002/smtd.201800272
[4]	肖民, 魏超, 姚寿广, 等. 单斜镍锰酸锂在不同离子电解液中的性能研究[J]. 无机盐工业, 2018, 50(7):23-26.
[5]	马慧, 张桓荣, 薛面起. 水系钠离子电池的研究进展及实用化挑战[J]. 化学学报, 2021, 79(4):388-405. doi: 10.6023/A20100492
[6]	陈丽能, 晏梦雨, 梅志文, 等. 水系锌离子电池的研究进展[J]. 无机材料学报, 2017, 32(3):225-234. doi: 10.15541/jim20160192
[7]	XU Chengjun, LI Baohua, DU Hongda, et al. Energetic zinc ion che-mistry:The rechargeable zinc ion battery[J]. Angewandte Chemie, 2012, 124(4):957-959. doi: 10.1002/ange.v124.4
[8]	LI Changgang, ZHANG Xudong, HE Wen, et al. Cathode materials for rechargeable zinc-ion batteries:From synjournal to mechanism and applications[J]. Journal of Power Sources, 2020, 449.Doi: 10.1016/j.jpowsour.2019.227596. doi: 10.1016/j.jpowsour.2019.227596
[9]	杨艳芹, 周谭, 李晓辉, 等. 锌离子电池的发展现状及展望[J]. 西部皮革, 2019, 41(23):94.
[10]	FANG Guozhao, ZHOU Jiang, PAN Anqiang, et al. Recent advanc-es in aqueous zinc-ion batteries[J]. ACS Energy Letters, 2018, 3(10):2480-2501. doi: 10.1021/acsenergylett.8b01426
[11]	SELVAKUMARAN D, PAN Anqiang, LIANG Shuquan, et al. A review on recent developments and challenges of cathode materials for rechargeable aqueous Zn-ion batteries[J]. Journal of Materials Chemistry A, 2019, 7(31):18209-18236. doi: 10.1039/C9TA05053A
[12]	戴宇航, 甘志伟, 阮雨杉, 等. 水系锌离子电池及关键材料研究进展[J]. 硅酸盐学报, 2021, 49(7):1323-1336.
[13]	SONG Ming, TAN Hua, CHAO Dongliang, et al. Recent advances in Zn-ion batteries[J]. Advanced Functional Materials, 2018, 28(41).Doi: 10.1002/adfm.201802564. doi: 10.1002/adfm.201802564
[14]	MING Jun, GUO Jing, XIA Chuan, et al. Zinc-ion batteries:Mate-rials,mechanisms,and applications[J]. Materials Science and En-gineering:R:Reports, 2019, 135:58-84.
[15]	ALFARUQI M H, ISLAM S, PUTRO D Y, et al. Structural transfor-mation and electrochemical study of layered MnO₂ in rechargeable aqueous zinc-ion battery[J]. Electrochimica Acta, 2018, 276:1-11. doi: 10.1016/j.electacta.2018.04.139
[16]	KONAROV A, VORONINA N, JO Jae Hyeon, et al. Present and future perspective on electrode materials for rechargeable zinc-ion batteries[J]. ACS Energy Letters, 2018, 3(10):2620-2640. doi: 10.1021/acsenergylett.8b01552
[17]	XU Dongwei, LI Baohua, WEI Chunguang, et al. Preparation and characterization of MnO₂/acid-treated CNT nanocomposites for en-ergy storage with zinc ions[J]. Electrochimica Acta, 2014, 133:254-261. doi: 10.1016/j.electacta.2014.04.001
[18]	WU Buke, ZHANG Guobin, YAN Mengyu, et al. Graphene scroll-coated α-MnO₂ nanowires as high-performance cathode materials for aqueous Zn-ion battery[J]. Small, 2018, 14(13).Doi: 10.1002/smll.201703850. doi: 10.1002/smll.201703850
[19]	PAN Huilin, SHAO Yuyan, YAN Pengfei, et al. Reversible aqueous zinc/manganese oxide energy storage from conversion reactions[J]. Nature Energy, 2016, 1.Doi: 10.1038/nenergy.2016.39. doi: 10.1038/nenergy.2016.39
[20]	SUN Kyung E K, HOANG Tuan K A, DOAN T N L, et al. Suppres-sion of dendrite formation and corrosion on zinc anode of secon-dary aqueous batteries[J]. ACS Applied Materials & Interfaces, 2017, 9(11):9681-9687.
[21]	STOCK D, DONGMO S, WALTHER F, et al. Homogeneous coating with an anion-exchange ionomer improves the cycling stability of secondary batteries with zinc anodes[J]. ACS Applied Materials & Interfaces, 2018, 10(10):8640-8648.
[22]	GUDURU R, ICAZA J. A brief review on multivalent intercalation batteries with aqueous electrolytes[J]. Nanomaterials, 2016, 6(3).Doi: 10.3390/nano6030041. doi: 10.3390/nano6030041
[23]	HU Lintong, XIAO Ping, XUE Lanlan, et al. The rising zinc anodes for high-energy aqueous batteries[J]. EnergyChem, 2021, 3(2). Doi: 10.1016/j.enchem.2021.100052. doi: 10.1016/j.enchem.2021.100052
[24]	常立民, 林丽, 聂平. 水系锌离子电池:金属锌负极研究进展[J]. 吉林师范大学学报:自然科学版, 2021, 42(3):8-15.
[25]	KANG Litao, CUI Mangwei, JIANG Fuyi, et al. Nanoporous CaCO₃ coatings enabled uniform Zn stripping/plating for long-life zinc rechargeable aqueous batteries[J]. Advanced Energy Materials, 2018, 8(25).Doi: 10.1002/aenm.201801090. doi: 10.1002/aenm.201801090
[26]	HONG Lin, WU Xiuming, MA Chao, et al. Boosting the Zn-ion tra-nsfer kinetics to stabilize the Zn metal interface for high-perfor-mance rechargeable Zn-ion batteries[J]. Journal of Materials Che-mistry A, 2021, 9(31):16814-16823.
[27]	XIA Aolin, PU Xiaoming, TAO Yayuan, et al. Graphene oxide spon-taneous reduction and self-assembly on the zinc metal surface en-abling a dendrite-free anode for long-life zinc rechargeable aqueous batteries[J]. Applied Surface Science, 2019, 481:852-859. doi: 10.1016/j.apsusc.2019.03.197
[28]	QIN Runzhi, WANG Yuetao, ZHANG Mingzheng, et al. Tuning Zn²⁺ coordination environment to suppress dendrite formation for high-performance Zn-ion batteries[J]. Nano Energy, 2021, 80.Doi: 10.1016/j.nanoen.2020.105478. doi: 10.1016/j.nanoen.2020.105478
[29]	PARKER J F, CHERVIN C N, PALA I R, et al. Rechargeable nic-kel-3D zinc batteries:An energy-dense,safer alternative to lithi-um-ion[J]. Science, 2017, 356(6336):415-418. doi: 10.1126/science.aak9991
[30]	TAO Haisheng, TONG Xiang, GAN Lu, et al. Effect of adding vari-ous carbon additives to porous zinc anode in rechargeable hybrid aqueous battery[J]. Journal of Alloys and Compounds, 2016, 658:119-124. doi: 10.1016/j.jallcom.2015.10.225
[31]	MAINAR A R, COLMENARES L C, BLÁZQUEZ J A, et al. A brief overview of secondary zinc anode development:The key of improv-ing zinc-based energy storage systems[J]. International Journal of Energy Research, 2018, 42(3):903-918. doi: 10.1002/er.v42.3
[32]	ZHANG Ning, CHENG Fangyi, LIU Junxiang, et al. Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities[J]. Nature Communications, 2017, 8.Doi: 10.1038/s41467-017-00467-x. doi: 10.1038/s41467-017-00467-x
[33]	WANG Fei, BORODIN Oleg, GAO Tao, et al. Highly reversible zinc metal anode for aqueous batteries[J]. Nature Materials, 2018, 17(6):543-549. doi: 10.1038/s41563-018-0063-z
[34]	GUO Shan, QIN Liping, ZHANG Tengsheng, et al. Fundamentals and perspectives of electrolyte additives for aqueous zinc-ion bat-teries[J]. Energy Storage Materials, 2021, 34:545-562. doi: 10.1016/j.ensm.2020.10.019
[35]	CUI Jin, LIU Xiaoyu, XIE Yihua, et al. Improved electrochemical reversibility of Zn plating/stripping:A promising approach to sup-press water-induced issues through the formation of H-bonding[J]. Materials Today Energy, 2020, 18.Doi: 10.1016/j.mtener.2020.100563. doi: 10.1016/j.mtener.2020.100563
[36]	NIAN Qingshun, WANG Jiayue, LIU Shuang, et al. Aqueous batte-ries operated at -50 ℃[J]. Angewandte Chemie International Edi-tion, 2019, 58(47):16994-16999.
[37]	LI Hongfei, HAN Cuiping, HUANG Yan, et al. An extremely safe and wearable solid-state zinc ion battery based on a hierarchical structured polymer electrolyte[J]. Energy & Environmental Science, 2018, 11(4):941-951.
[38]	GUO Xun, ZHOU Jiang, BAI Chaolei, et al. Zn/MnO₂ battery che-mistry with dissolution-deposition mechanism[J]. Materials Today Energy, 2020, 16.Doi: 10.1016/j.mtener.2020.100396. doi: 10.1016/j.mtener.2020.100396

首页

全国无机盐信息中心

中国化工学会

无机酸碱盐专业委员会