多孔碳基非贵金属氧还原电催化剂研究进展

doi:10.19964/j.issn.1006-4990.2023-0038

摘要/Abstract

摘要：

氧还原反应电催化剂在能量储存和转换中的应用受到了广泛关注，铂基贵金属催化剂因成本高、资源稀缺等缺点限制了其规模化应用。碳基非贵金属催化剂因价格低廉、反应活性好和抗甲醇渗透能力强等优点有望成为铂基催化剂的替代品。目前，文献报道的碳基催化剂主要通过调控活性位点的电子结构、增加活性位点密度与可接近性及调控碳/金属复合材料界面结构等策略提升其氧还原活性。从非金属元素掺杂碳基催化剂、碳基非贵金属单原子催化剂和碳基非贵金属纳米颗粒催化剂3个方面综述了碳基氧还原催化剂的研究进展，总结和指出了碳基催化剂面临的问题及挑战，并对催化剂的发展前景进行了展望。

关键词: 氧还原, 碳材料, 单原子, 掺杂, 纳米颗粒

Abstract:

The application of electrocatalysts for oxygen reduction reaction in energy storage and conversion has attracted extensive attention.However，the large-scale application of platinum-based catalysts is limited by their high cost，scarce resources and poor stability.Carbon-based non noble metal catalysts are expected to be a substitute for platinum-based catalysts due to their low price，excellent reactivity and strong methanol penetration resistance.At present，the improvement of the oxygen reduction activity of carbon-based catalysts reported in the literature was regulating the electronic structure of active sites，increasing the density and accessibility of active sites，and regulating the interface structure of carbon/metal composites.The research progress of carbon-based oxygen reduction catalysts was reviewed from the following three aspects：nonmetallic elements doped carbon-based catalysts，carbon-based non noble metal single-atom catalysts and carbon-based non noble metal nanoparticles catalysts.The problems and challenges faced by carbon-based catalysts were summarized and pointed out，and the development prospects of the catalyst were prospected.

Key words: oxygen reduction, carbon materials, single-atom, doping, nanoparticles

中图分类号:

O643.36

武鲁明, 于海斌, 王亚权. 多孔碳基非贵金属氧还原电催化剂研究进展[J]. 无机盐工业, 2023, 55(10): 13-23.

WU Luming, YU Haibin, WANG Yaquan. Research progress of porous carbon-based non noble metal electrocatalysts for oxygen reduction[J]. Inorganic Chemicals Industry, 2023, 55(10): 13-23.

图/表 6

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表1

参考文献 75

1	CHEN Si， ZHAO Lanling， MA Jizhen，et al.Edge-doping modulation of N，P-codoped porous carbon spheres for high-performance rechargeable Zn-air batteries［J］.Nano Energy，2019，60：536- 544.
2	GEWIRTH A A， VARNELL J A， DIASCRO A M.Nonprecious metal catalysts for oxygen reduction in heterogeneous aqueous systems［J］.Chemical Reviews，2018，118（5）：2313-2339.
3	WANG Ling， FANG Zhongwei， ZHANG Jiawei，et al.High-performance FeCo/NC-Mo₂TiC₂/carbon nanotube hybrid support catalyst toward oxygen reduction for alkaline anion exchange membrane fuel cell［J］.ACS Sustainable Chemistry & Engineering，2022，10（48）：15735-15740.
4	ZHANG Wenjun， LI Ping， ZHAO Huimin，et al.Metal-free honeycomb-like electrocatalyst with high specific mass activity for accelerated oxygen reduction reaction in both alkaline and acidic me-dia［J］.Applied Surface Science，2022，579：152149.
5	ZHAO Xueru， SASAKI K.Advanced Pt-based core-shell electrocatalysts for fuel cell cathodes［J］.Accounts of Chemical Research， 2022，55（9）：1226-1236.
6	ADABI H， SANTORI P G， SHAKOURI A，et al.Understanding how single-atom site density drives the performance and durability of PGM-free Fe-N-C cathodes in anion exchange membrane fuel cells［J］.Materials Today Advances，2021，12：100179.
7	LU Xiangyu， XIAO Lihui， YANG Peixia，et al.Highly exposed surface pore-edge FeN_x sites for enhanced oxygen reduction performance in Zn-air batteries［J］.Inorganic Chemistry Frontiers，2023， 10（3）：815-823.
8	GONG Kuanping， DU Feng， XIA Zhenhai，et al.Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction［J］.Science，2009，323（5915）：760-764.
9	WU Gang， ZELENAY P.Nanostructured nonprecious metal catalysts for oxygen reduction reaction［J］.Accounts of Chemical Research，2013，46（8）：1878-1889.
10	GUO Donghui， SHIBUYA R， AKIBA C，et al.Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clari-fied using model catalysts［J］.Science，2016，351（6271）：361- 365.
11	YANG Hongbin， MIAO Jianwei， HUNG S F，et al.Identification of catalytic sites for oxygen reduction and oxygen evolution in N-doped graphene materials：Development of highly efficient metal-free bifunctional electrocatalyst［J］.Science Advances，2016，2（4）：e1501122.
12	REN Guangyuan， CHEN Shaoqing， ZHANG Junxian，et al.N-doped porous carbon spheres as metal-free electrocatalyst for oxygen reduction reaction［J］.Journal of Materials Chemistry A，2021， 9（9）：5751-5758.
13	ZHANG Jintao， ZHAO Zhenghang， XIA Zhenhai，et al.A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions［J］.Nature Nanotechnology，2015，10（5）：444-452.
14	YANG Chao， JIN Huile， CUI Cuixia，et al.Nitrogen and sulfur co-doped porous carbon sheets for energy storage and pH-universal oxygen reduction reaction［J］.Nano Energy，2018，54：192-199.
15	LU Ziyang， WANG Jing， HUANG Shifei，et al.N，B-codoped defect-rich graphitic carbon nanocages as high performance multifunctional electrocatalysts［J］.Nano Energy，2017，42：334-340.
16	LONG Yongde， YE Fenghui， SHI Lei，et al.N，P，and S tri-doped holey carbon as an efficient electrocatalyst for oxygen reduction in whole pH range for fuel cell and zinc-air batteries［J］.Carbon，2021，179：365-376.
17	LIU Kang， FU Junwei， LIN Yiyang，et al.Insights into the activity of single-atom Fe-N-C catalysts for oxygen reduction reaction［J］.Nature Communications，2022，13：2075.
18	ORELLANA W.Catalytic properties of transition metal-N₄ moieties in graphene for the oxygen reduction reaction：Evidence of spin-dependent mechanisms［J］.The Journal of Physical Chemistry C，2013，117（19）：9812-9818.
19	LIANG Wei， CHEN Junxiang， LIU Yuwen，et al.Density-functional-theory calculation analysis of active sites for four-electron reduction of O₂ on Fe/N-doped graphene［J］.ACS Catalysis，2014，4（11）：4170-4177.
20	LEFÈVRE M， PROIETTI E， JAOUEN F，et al.Iron-based catalysts with improved oxygen reduction activity in polymer electrolyte fuel cells［J］.Science，2009，324（5923）：71-74.
21	PROIETTI E， JAOUEN F， LEFÈVRE M，et al.Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells［J］.Nature Communications，2011，2：416.
22	SHUI Jianglan， CHEN Chen， GRABSTANOWICZ L，et al.Highly efficient nonprecious metal catalyst prepared with metal-organic framework in a continuous carbon nanofibrous network［J］.Proceedings of the National Academy of Sciences of the United States of America，2015，112（34）：10629-10634.
23	CHUNG H T， CULLEN D A， HIGGINS D，et al.Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst［J］.Science，2017，357（6350）：479-484.
24	WU Luming， NI Baoxia， CHEN Rui，et al.A general approach for hierarchically porous metal/N/C nanosphere electrocatalysts：Nano-confined pyrolysis of in situ-formed amorphous metal-ligand complexes［J］.Journal of Materials Chemistry A，2020，8（40）：21026-21035.
25	WU Luming， ZHAO Ruge， DU Guo，et al.Hierarchically porous Fe/N/S/C nanospheres with high-content of Fe-N_x for enhanced ORR and Zn-air battery performance［J］.Green Energy & Environment，2022.Doi：10.1016/j.gee.2022.03.014 .
26	XIA Dongsheng， TANG Xuan， DAI Sheng，et al.Ultrastable Fe-N-C fuel cell electrocatalysts by eliminating non-coordinating nitrogen and regulating coordination structures at high temperatures［J］.Advanced Materials，2023，35（5）：2204474.
27	QU Yunteng， LI Zhijun， CHEN Wenxing，et al.Direct transformation of bulk copper into copper single sites via emitting and trapping of atoms［J］.Nature Catalysis，2018，1（10）：781-786.
28	WANG Xiaoxia， CULLEN D A， PAN Y T，et al.Nitrogen-coordinated single cobalt atom catalysts for oxygen reduction in proton exchange membrane fuel cells［J］.Advanced Materials，2018，30（11）：1706758.
29	TIAN Han， CUI Xiangzhi， DONG Hongliang，et al.Engineering single MnN₄ atomic active sites on polydopamine-modified helical carbon tubes towards efficient oxygen reduction［J］.Energy Storage Materials，2021，37：274-282.
30	DENG Wenhui， LI Guang， WU Tianjing，et al.Heteroatom functionalized double-layer carbon nanocages as highly efficient oxygen electrocatalyst for Zn-air batteries［J］.Carbon，2022，186：589-598.
31	WANG Jing， LIU Wei， LUO Gan，et al.Synergistic effect of well-defined dual sites boosting the oxygen reduction reaction［J］.Energy & Environmental Science，2018，11（12）：3375-3379.
32	LIU Ming， LI Na， CAO Shoufu，et al.A “pre-constrained metal twins” strategy to prepare efficient dual-metal-atom catalysts for cooperative oxygen electrocatalysis［J］.Advanced Materials，2022， 34（7）：2107421.
33	CHEN Jiangyue， LI Hao， FAN Chuang，et al.Dual single-atomic Ni-N₄ and Fe-N₄ sites constructing Janus hollow graphene for selective oxygen electrocatalysis［J］.Advanced Materials，2020，32（30）：2003134.
34	BAI Jirong， GE Wenzheng， ZHOU Pin，et al.Precise constructed atomically dispersed Fe/Ni sites on porous nitrogen-doped carbon for oxygen reduction［J］.Journal of Colloid and Interface Science，2022，616：433-439.
35	LIU Qingtao， LIU Xiaofang， ZHENG Lirong，et al.The solid-phase synthesis of an Fe-N-C electrocatalyst for high-power proton-exchange membrane fuel cells［J］.Angewandte Chemie International Edition，2018，57（5）：1204-1208.
36	VARNELL J A， TSE E C M， SCHULZ C E，et al.Identification of carbon-encapsulated iron nanoparticles as active species in non-precious metal oxygen reduction catalysts［J］.Nature Communications，2016，7：12582.
37	LIU Fang， ZHANG Xinquan， ZHANG Xiaolong，et al.Dual-template strategy for electrocatalyst of cobalt nanoparticles encapsulated in nitrogen-doped carbon nanotubes for oxygen reduction reaction［J］.Journal of Colloid and Interface Science，2021，581：523-532.
38	GAO Haili， LIU Yunpeng， MA Yaqiong，et al.Synthesis of N-doped Co@C/CNT materials based on ZIF-67 and their electrocatalytic performance for oxygen reduction［J］.Ionics，2021，27（6）：2561-2569.
39	WANG Chenxu， YUAN Huifang， YU Feng，et al.Enhanced oxygen reduction reaction performance of Co@N-C derived from metal-organic frameworks ZIF-67 via a continuous microchannel reactor［J］.Chinese Chemical Letters，2023，34（1）：107128.
40	HU Yang， JENSEN J O， ZHANG Wei，et al.Hollow spheres of iron carbide nanoparticles encased in graphitic layers as oxygen reduction catalysts［J］.Angewandte Chemie，2014，53（14）：3675- 3679.
41	ZHONG Lijie， FRANDSEN C， MØRUP S，et al. ⁵⁷Fe-Mössbauer spectroscopy and electrochemical activities of graphitic layer encapsulated iron electrocatalysts for the oxygen reduction reaction［J］.Applied Catalysis B：Environmental，2018，221：406-412.
42	XIA Hongyin， ZHANG Shan， ZHU Xiaoqing，et al.Highly efficient catalysts for oxygen reduction using well-dispersed iron carbide nanoparticles embedded in multichannel hollow nanofibers［J］.Journal of Materials Chemistry A，2020，8（35）：18125-18131.
43	GANGADHARAN P K， PANDIKASSALA A， KURUNGOT S.Toward pH independent oxygen reduction reaction by polydopamine derived 3D interconnected，iron carbide embedded graphi-tic carbon［J］.ACS Applied Materials & Interfaces，2021，13（7）：8147-8158.
44	NOROUZI N， CHOUDHURY F A， EL-KADERI H M.Iron phosphide doped，porous carbon as an efficient electrocatalyst for oxygen reduction reaction［J］.ACS Applied Energy Materials，2020，3（3）：2537-2546.
45	NI Baoxia， CHEN Rui， WU Luming，et al.Encapsulated FeP nanoparticles with in situ formed P-doped graphene layers：Boosting activity in oxygen reduction reaction［J］.Science China Materials，2021，64（5）：1159-1172.
46	JIANG Hao， GU Jinxing， ZHENG Xusheng，et al.Defect-rich and ultrathin N doped carbon nanosheets as advanced trifunctional metal-free electrocatalysts for the ORR，OER and HER［J］.Energy & Environmental Science，2019，12（1）：322-333.
47	NGUYEN A T N， SHIM J H.All carbon hybrid N-doped carbon dots/carbon nanotube structures as an efficient catalyst for the oxygen reduction reaction［J］.RSC Advances，2021，11（21）：12520-12530.
48	GUO Chaozhong， LI Yanrong， XU Ya，et al.A highly nanoporous nitrogen-doped carbon microfiber derived from bioresource as a new kind of ORR electrocatalyst［J］.Nanoscale Research Letters，2019，14（1）：1-11.
49	XIANG Qin， LIU Yuping， ZOU Xuefeng，et al.Hydrothermal synthesis of a new kind of N-doped graphene gel-like hybrid as an enhanced ORR electrocatalyst［J］.ACS Applied Materials & Interfaces，2018，10（13）：10842-10850.
50	LU Xiangyu， WANG Dan， GE Liping，et al.Enriched graphitic N in nitrogen-doped graphene as a superior metal-free electrocatalyst for the oxygen reduction reaction［J］.New Journal of Chemistry，2018，42（24）：19665-19670.
51	ZHAO Yasong， WAN Jiawei， YAO Huiying，et al.Few-layer gr-aphdiyne doped with sp-hybridized nitrogen atoms at acetylenic sites for oxygen reduction electrocatalysis［J］.Nature Chemistry，2018，10（9）：924-931.
52	SU Jinquan， ZANG Jianbing， TIAN Pengfei，et al.Fe-N-Si tri-doped carbon nanofibers for efficient oxygen reduction reaction in alkaline and acidic media［J］.International Journal of Hydrogen Energy，2020，45（53）：28792-28799.
53	KOU Zongkui， ZANG Wenjie， MA Yuanyuan，et al.Cage-confinement pyrolysis route to size-controlled molybdenum-based oxygen electrode catalysts：From isolated atoms to clusters and nanoparticles［J］.Nano Energy，2020，67：104288.
54	KANG G S， JANG J H， SON S Y，et al.Pyrrolic N wrapping strategy to maximize the number of single-atomic Fe-N _x sites for oxygen reduction reaction［J］.Journal of Power Sources，2022，520：230904.
55	LI Zhijun， JI Siqi， XU Chang，et al.Engineering the electronic structure of single-atom iron sites with boosted oxygen bifunctional activity for zinc-air batteries［J］.Advanced Materials，2023，35（9）：2209644.
56	TANG Xiannong， WEI Yuanhao， ZHAI Weijuan，et al.Carbon nanocage with maximum utilization of atomically dispersed iron as efficient oxygen electroreduction nanoreactor［J］.Advanced Materials，2023，35（5）：2208942.
57	HE Jing， ZHENG Tianlong， WU Duojie，et al.Insights into the determining effect of carbon support properties on anchoring active sites in Fe-N-C catalysts toward the oxygen reduction reaction［J］.ACS Catalysis，2022，12（3）：1601-1613.
58	ARIF KHAN M， SUN Congli， CAI Jian，et al.Potassium-ion activating formation of Fe-N-C moiety as efficient oxygen electrocatalyst for Zn-air batteries［J］.ChemElectroChem，2021，8（7）：1298-1306.
59	JAFARI M， GHARIBI H， PARNIAN M J，et al.Iron-nanoparticle-loaded nitrogen-doped carbon nanotube/carbon sheet composites derived from MOF as electrocatalysts for an oxygen reduction reaction［J］.ACS Applied Nano Materials，2021，4（1）：459-477.
60	SUO Yange， ZHANG Zihan， ZHANG Zhiguo，et al.Cobalt and nitrogen-doped carbon with enlarged pore size derived from ZIF-67 by a NaCl-assisted pyrolysis strategy towards oxygen reduction reaction［J］.Ionics，2021，27（1）：289-303.
61	KONG Fantao， FAN Xiaohong， KONG Aiguo，et al.Covalent phenanthroline framework derived FeS@Fe₃C composite nanoparticles embedding in N-S-codoped carbons as highly efficient trifunctional electrocatalysts［J］.Advanced Functional Materials，2018，28（51）：1803973.
62	NIU Huajie， ZHANG Lu， FENG Jiuju，et al.Graphene-encapsulated cobalt nanoparticles embedded in porous nitrogen-doped graphitic carbon nanosheets as efficient electrocatalysts for oxygen reduction reaction［J］.Journal of Colloid and Interface Science，2019，552：744-751.
63	CHENITZ R， KRAMM U I， LEFÈVRE M，et al.A specific demetalation of Fe-N₄ catalytic sites in the micropores of NC-Ar +NH₃ is at the origin of the initial activity loss of the highly active Fe/N/C catalyst used for the reduction of oxygen in PEM fuel cells［J］.Energy & Environmental Science，2018，11（2）：365-382.
64	FU Kailin， ZENG Liuli， LIU Jiaming，et al.Magnetron sputtering a high-performance catalyst for ultra-low-Pt loading PEMFCs［J］.Journal of Alloys and Compounds，2020，815：152374.
65	BORUP R， MEYERS J， PIVOVAR B，et al.Scientific aspects of polymer electrolyte fuel cell durability and degradation［J］.Che- mical Reviews，2007，107（10）：3904-3951.
66	LIU Gang， LI Xuguang， LEE J W，et al.A review of the development of nitrogen-modified carbon-based catalysts for oxygen reduction at USC［J］.Catalysis Science & Technology，2011，1（2）：207-217.
67	ZHANG Gaixia， CHENITZ R， LEFÈVRE M，et al.Is iron involved in the lack of stability of Fe/N/C electrocatalysts used to reduce oxygen at the cathode of PEM fuel cells？［J］.Nano Energy，2016，29：111-125.
68	SHAO Yuyan， DODELET J P， WU Gang，et al.PGM-free cathode catalysts for PEM fuel cells：A mini-review on stability challenges［J］.Advanced Materials，2019，31（31）：1807615.
69	CHOI C H， BALDIZZONE C， GROTE J P，et al.Stability of Fe-N-C catalysts in acidic medium studied by operando spectroscopy［J］.Angewandte Chemie，2015，54（43）：12753-12757.
70	FERRANDON M， WANG Xiaoping， KROPF A J，et al.Stability of iron species in heat-treated polyaniline-iron-carbon polymer electrolyte fuel cell cathode catalysts［J］.Electrochimica Acta，2013，110：282-291.
71	CHEN Junren， YAN Xiaohui， FU Cehuang，et al.Insight into the rapid degradation behavior of nonprecious metal Fe-N-C electrocatalyst-based proton exchange membrane fuel cells［J］.ACS Applied Materials & Interfaces，2019，11（41）：37779-37786.
72	CHOI C H， LIM H K， CHUNG M W，et al.The Achilles' heel of iron-based catalysts during oxygen reduction in an acidic medium［J］.Energy & Environmental Science，2018，11（11）：3176-3182.
73	DU Lei， PRABHAKARAN V， XIE Xiaohong，et al.Low-PGM and PGM-free catalysts for proton exchange membrane fuel cells：Stability challenges and material solutions［J］.Advanced Materials，2021，33（6）：1908232.
74	XIAO Meiling， GAO Liqin， WANG Ying，et al.Engineering energy level of metal center：Ru single-atom site for efficient and durable oxygen reduction catalysis［J］.Journal of the American Chemical Society，2019，141（50）：19800-19806.
75	YOON K R， LEE K A，JO S，et al.Mussel-inspired polydopamine-treated reinforced composite membranes with self-supported CeO _x radical scavengers for highly stable PEM fuel cells［J］.Advanced Functional Materials，2019，29（3）：1806929.

催化剂类型	催化剂	电解液	E_1/2/ （V vs.RHE）	塔菲尔斜率/ （mV·dec^-1）	参考文献
非金属元素掺杂碳基催化剂	N-GRW	1 mol/L KOH	0.84	53	［11］
	NPCS-900	0.1 mol/L KOH	0.87	—	［12］
	NPG-1000	0.1 mol/L KOH	0.84	71.2	［14］
	NPS-HC	0.1 mol/L KOH	0.862	57	［16］
	NCN-1000-5	0.1 mol/L KOH	0.82	86	［46］
	N-doped CDs	0.1 mol/L KOH	0.78	60.9	［47］
	Me-CFZ-900	0.1 mol/L KOH	0.86	—	［48］
	NGS4-900	0.1 mol/L KOH	0.859	72	［49］
	N-G-1000	0.1 mol/L KOH	0.862	—	［50］
	NFLGDY-900c	0.1 mol/L KOH	0.87	60.0	［51］
碳基非贵金属单原子催化剂	Fe/N/C-HP	0.1 mol/L KOH	0.90	57.5	［24］
	FeN _x /NC-S	0.1 mol/L KOH	0.92	61.3	［25］
	Cu-SAs/N-C	0.1 mol/L KOH	0.895	63	［26］
	MnNC-700	0.1 mol/L KOH	0.87	—	［29］
	Zn-NC	0.1 mol/L KOH	0.86	97.8	［30］
	（Fe，Co）/CNT	0.1 mol/L KOH	0.954	—	［31］
	Ni-N₄/GHSs/Fe-N₄	0.1 mol/L KOH	0.83	55	［33］
	Fe-N-Si-CNFs	0.1 mol/L KOH	0.86	65	［52］
	NR-CNT@FeNPC-800	0.1 mol/L KOH	0.88	51	［53］
	MoSACs/N-C	0.1 mol/L KOH	0.83	—	［54］
	Fe/PNC@HCF	0.1 mol/L KOH	0.93	77.5	［55］
	Cu-SAs@N-CNS	0.1 mol/L KOH	0.91	62.47	［56］
	Fe，CoSAs-PNCF	0.1 mol/L KOH	0.93	77	［57］
	GO-Fe-N	0.1 mol/L KOH	0.87	66.2	［58］
碳基非贵金属纳米颗粒催化剂	Fe-bNCNT/NC-900	0.1 mol/L KOH	0.884	57	［59］
	Co@NCNTs-800	0.1 mol/L KOH	0.88	63	［37］
	N-Co@C/CNT	0.1 mol/L KOH	0.83	75.2	［38］
	CoNC_-1NaCl_-800	0.1 mol/L KOH	0.84	—	［60］
	Co@N-C（DM）	0.1 mol/L KOH	0.83	—	［39］
	Fe₃C/C-800	0.1 mol/L KOH	0.83	—	［40］
	Fe₃C@MHNFs	0.1 mol/L KOH	0.90	—	［42］
	3D-FePDC	0.1 mol/L KOH	0.84	81	［43］
	FeS/Fe₃C@N-S-C-800	0.1 mol/L KOH	0.87	—	［61］
	PFeC-900	0.1 mol/L KOH	0.88	53	［44］
	FeP@PGL	0.1 mol/L KOH	0.90	64	［45］
	Co@G/N-GCNs	0.1 mol/L KOH	0.86	69.66	［62］

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