无机盐工业 ›› 2023, Vol. 55 ›› Issue (10): 13-23.doi: 10.19964/j.issn.1006-4990.2023-0038
收稿日期:
2023-01-16
出版日期:
2023-10-10
发布日期:
2023-10-16
通讯作者:
于海斌(1970— ),男,教授级高工;E-mail:yuhaibin9227@163.com。作者简介:
武鲁明(1990— ),女,博士,主要研究方向为催化材料的制备及其催化机理研究;E-mail:wuluming8363@163.com。
WU Luming1,2(), YU Haibin2(
), WANG Yaquan1
Received:
2023-01-16
Published:
2023-10-10
Online:
2023-10-16
摘要:
氧还原反应电催化剂在能量储存和转换中的应用受到了广泛关注,铂基贵金属催化剂因成本高、资源稀缺等缺点限制了其规模化应用。碳基非贵金属催化剂因价格低廉、反应活性好和抗甲醇渗透能力强等优点有望成为铂基催化剂的替代品。目前,文献报道的碳基催化剂主要通过调控活性位点的电子结构、增加活性位点密度与可接近性及调控碳/金属复合材料界面结构等策略提升其氧还原活性。从非金属元素掺杂碳基催化剂、碳基非贵金属单原子催化剂和碳基非贵金属纳米颗粒催化剂3个方面综述了碳基氧还原催化剂的研究进展,总结和指出了碳基催化剂面临的问题及挑战,并对催化剂的发展前景进行了展望。
中图分类号:
武鲁明, 于海斌, 王亚权. 多孔碳基非贵金属氧还原电催化剂研究进展[J]. 无机盐工业, 2023, 55(10): 13-23.
WU Luming, YU Haibin, WANG Yaquan. Research progress of porous carbon-based non noble metal electrocatalysts for oxygen reduction[J]. Inorganic Chemicals Industry, 2023, 55(10): 13-23.
表1
碳基非贵金属催化剂的ORR性能对比
催化剂类型 | 催化剂 | 电解液 | E1/2/ (V vs.RHE) | 塔菲尔斜率/ (mV·dec-1) | 参考文献 |
---|---|---|---|---|---|
非金属元素掺杂碳基催化剂 | N-GRW | 1 mol/L KOH | 0.84 | 53 | [ |
NPCS-900 | 0.1 mol/L KOH | 0.87 | — | [ | |
NPG-1000 | 0.1 mol/L KOH | 0.84 | 71.2 | [ | |
NPS-HC | 0.1 mol/L KOH | 0.862 | 57 | [ | |
NCN-1000-5 | 0.1 mol/L KOH | 0.82 | 86 | [ | |
N-doped CDs | 0.1 mol/L KOH | 0.78 | 60.9 | [ | |
Me-CFZ-900 | 0.1 mol/L KOH | 0.86 | — | [ | |
NGS4-900 | 0.1 mol/L KOH | 0.859 | 72 | [ | |
N-G-1000 | 0.1 mol/L KOH | 0.862 | — | [ | |
NFLGDY-900c | 0.1 mol/L KOH | 0.87 | 60.0 | [ | |
碳基非贵金属单原子催化剂 | Fe/N/C-HP | 0.1 mol/L KOH | 0.90 | 57.5 | [ |
FeN x /NC-S | 0.1 mol/L KOH | 0.92 | 61.3 | [ | |
Cu-SAs/N-C | 0.1 mol/L KOH | 0.895 | 63 | [ | |
MnNC-700 | 0.1 mol/L KOH | 0.87 | — | [ | |
Zn-NC | 0.1 mol/L KOH | 0.86 | 97.8 | [ | |
(Fe,Co)/CNT | 0.1 mol/L KOH | 0.954 | — | [ | |
Ni-N4/GHSs/Fe-N4 | 0.1 mol/L KOH | 0.83 | 55 | [ | |
Fe-N-Si-CNFs | 0.1 mol/L KOH | 0.86 | 65 | [ | |
NR-CNT@FeNPC-800 | 0.1 mol/L KOH | 0.88 | 51 | [ | |
MoSACs/N-C | 0.1 mol/L KOH | 0.83 | — | [ | |
Fe/PNC@HCF | 0.1 mol/L KOH | 0.93 | 77.5 | [ | |
Cu-SAs@N-CNS | 0.1 mol/L KOH | 0.91 | 62.47 | [ | |
Fe,CoSAs-PNCF | 0.1 mol/L KOH | 0.93 | 77 | [ | |
GO-Fe-N | 0.1 mol/L KOH | 0.87 | 66.2 | [ | |
碳基非贵金属纳米颗粒催化剂 | Fe-bNCNT/NC-900 | 0.1 mol/L KOH | 0.884 | 57 | [ |
Co@NCNTs-800 | 0.1 mol/L KOH | 0.88 | 63 | [ | |
N-Co@C/CNT | 0.1 mol/L KOH | 0.83 | 75.2 | [ | |
CoNC-1NaCl-800 | 0.1 mol/L KOH | 0.84 | — | [ | |
Co@N-C(DM) | 0.1 mol/L KOH | 0.83 | — | [ | |
Fe3C/C-800 | 0.1 mol/L KOH | 0.83 | — | [ | |
Fe3C@MHNFs | 0.1 mol/L KOH | 0.90 | — | [ | |
3D-FePDC | 0.1 mol/L KOH | 0.84 | 81 | [ | |
FeS/Fe3C@N-S-C-800 | 0.1 mol/L KOH | 0.87 | — | [ | |
PFeC-900 | 0.1 mol/L KOH | 0.88 | 53 | [ | |
FeP@PGL | 0.1 mol/L KOH | 0.90 | 64 | [ | |
Co@G/N-GCNs | 0.1 mol/L KOH | 0.86 | 69.66 | [ |
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