无机盐工业 ›› 2024, Vol. 56 ›› Issue (7): 1-10.doi: 10.19964/j.issn.1006-4990.2023-0600
• 综述与专论 • 下一篇
收稿日期:
2023-12-13
出版日期:
2024-07-10
发布日期:
2024-08-01
通讯作者:
毛庆(1979— ),男,博士,副教授,主要研究方向为燃料电池、SPE水电解及CO2电还原领域技术研究开发;E-mail:maoqing@dlut.edu.cn。作者简介:
王挺(1980— ),男,硕士,高级工程师,主要研究方向为焊接、材料加工工程、固废资源化利用研究;E-mail:twang800410@126.com。
基金资助:
WANG Ting1(), ZHANG Wenwen1, MAO Qing2(), LÜ Li3, LIU Changzhen
Received:
2023-12-13
Published:
2024-07-10
Online:
2024-08-01
摘要:
利用二氧化碳电催化还原(CO2RR)技术可将CO2直接转化为燃料或高附加值化学品,是当前缓解资源、环境等问题的有效途径之一。在CO2RR产物中,乙醇具有相对较高的能量密度和经济附加值,但由于基元过程复杂且易受传质与副产析氢的影响,该过程常常伴随高过电位、低反应速率等系列问题。为此,重点介绍利用体系耦合的“过程串联”,活性位点耦合的“反应串联”,以及凸显“电子效应”、“应变效应”和“限域效应”的“反应协同”进行CO2RR制乙醇催化体系的设计思路及相关电催化材料的研究进展。最后,指出“串联催化”和“协同催化”是当前电催化体系设计的两种主要策略;在不同的电催化策略下,基于机理的催化材料设计是CO2RR制乙醇过程活性提升的关键。
中图分类号:
王挺, 章文文, 毛庆, 吕丽, 刘长珍. 二氧化碳电还原制乙醇催化体系与材料研究进展[J]. 无机盐工业, 2024, 56(7): 1-10.
WANG Ting, ZHANG Wenwen, MAO Qing, LÜ Li, LIU Changzhen. Research progress of catalytic system and materials for electrocatalytic reduction of carbon dioxide to ethanol[J]. Inorganic Chemicals Industry, 2024, 56(7): 1-10.
表1
不同电催化剂性能比较
电催化剂 | 过电位/ (V vs.RHE) | 乙醇法拉第 效率/% | 电流密度/ (mA∙cm-2) |
---|---|---|---|
Cu(Ag-20)20-M[ | -1.10 | 14.1 | 2.70 |
OD-Ag15Cu85[ | -1.00 | 33.7 | 8.67 |
Au/Cu[ | -0.90 | — | — |
AuCu/Cu-SCA[ | -1.00 | 29±4 | — |
Cu4Zn[ | -1.05 | 29.1 | 8.20 |
Ag-G-NCF[ | -0.6~-0.7 | 82.0~85.2 | — |
BND[ | -1.00 | 93.2 | — |
RuPC/NPC[ | -0.87~-1.07 | 21.0~27.5 | — |
MC-CNT/Co[ | -0.32 | 60.1 | 5.10 |
Ag-Co[ | -0.80 | 72.3 | 7.40 |
Cu2S@Cu(V) [ | -0.95 | 23.1 | — |
Cu(N-C/Cu) [ | -0.68 | 52±1 | 156±13 |
Au@Cu2O[ | -0.30 | 52.3 | — |
SnS2/Sn1-O3G[ | -0.90 | 97.0 | 17.80 |
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