羟基磷灰石复合腐植酸及其对Mn（Ⅱ）的去除

doi:10.19964/j.issn.1006-4990.2023-0335

Abstract

Abstract:

Hydroxyapatite（HAP） was successfully synthesized by chemical precipitation method using calcium nitrate and ammonium hydrogen phosphate as raw materials，and HAP-HA composite adsorbent was prepared by combining HAP with humic acid（HA）.The samples were characterized by Fourier transform infrared spectroscopy（FT-IR），specific surface area and pore size analysis，differential thermal-thermogravimetric analysis（TG-DSC） and scanning electron microscopy（SEM）.The results showed that humic acid was successfully loaded onto hydroxyapatite.The pore size of HAP-HA was mainly distributed in 3~5 nm，the specific surface area was large，and it had good stability.The surface of HAP-HA was rough and porous，which increased the specific surface area and provided a large number of active sites for heavy metal ions.Taking Mn（Ⅱ） as the target pollutant and the removal rate of Mn（Ⅱ） as the index，the adsorption performance of HAP-HA on pollutants was investigated by adsorption experiments.The results showed that the removal rate of Mn（Ⅱ） by HAP-HA was the highest at room temperature，pH of 8.0，dosage of 0.15 g and adsorption time of 150 min，which could reach more than 99.0%.The adsorption process conformed to the Freundlich isothermal adsorption model.At the same time，the desorption and regeneration adsorption experiments were carried out on the adsorbent after the adsorption experiment.The NaOH solution was used as the eluent to obtain better desorption effect，and the desorption efficiency could reach 78.1%.HAP-HA still had good adsorption performance after 6 regeneration cycles.

Key words: hydroxyapatite, humic acid, adsorbent, Mn（Ⅱ）

CLC Number:

O647.33

PEI Xiaogang, ZHANG Peng, DONG Shanshan, GE Shanshan, ZHAO Yuelong. Hydroxyapatite composite humic acid and its removal of Mn（Ⅱ）[J]. Inorganic Chemicals Industry, 2024, 56(5): 70-77.

Figures/Tables 14

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Table 1

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References 21

1	DEY S， TRIPATHY B， KUMAR M S，et al.Ecotoxicological consequences of manganese mining pollutants and their biological remediation［J］.Environmental Chemistry and Ecotoxicology，2023，5：55-61.
2	JIANG Shuxian， RAO Peng， HUANG Huaguan，et al.Performance of a ceramsite-enhanced gravity-driven ceramic membrane（GDCM） for simultaneous manganese ion and ammonia removal［J］.Journal of Cleaner Production，2023，389：136082.
3	陈远其，陈章，李志贤，等.锰污染土壤修复研究现状与展望［J］.生态环境学报，2017，26（8）：1451-1456.
	CHEN Yuanqi， CHEN Zhang， LI Zhixian，et al.A review and perspective on remediation of manganese contaminated soil research［J］.Ecology and Environmental Sciences，2017，26（8）：1451-1456.
4	张鹏，赵文麟，廖为雄，等.聚丙烯酰胺-谷胱甘肽-聚合硫酸铝铁去除Mn（Ⅱ）和溶解性有机物的研究［J］.环境污染与防治，2019，41（12）：1403-1407，1412.
	ZHANG Peng， ZHAO Wenlin， LIAO Weixiong，et al.Removal of Mn（Ⅱ） and dissolved organic matter by polyacrylamide-glutath-ione-polymeric aluminum ferric sulfate［J］.Environmental Pollution & Control，2019，41（12）：1403-1407，1412.
5	NECULITA C M， ROSA E.A review of the implications and challenges of manganese removal from mine drainage［J］.Chemosp- here，2019，214：491-510.
6	SALEH T A， MUSTAQEEM M， KHALED M.Water treatment technologies in removing heavy metal ions from wastewater：A review［J］.Environmental Nanotechnology，Monitoring & Management，2022，17：100617.
7	安强，朱胜，缪乐，等.碱改柚子皮生物炭对水体中Mn（Ⅱ）的动态吸附研究［J］.重庆大学学报，2021，44（6）：96-108，126.
	AN Qiang， ZHU Sheng， MIAO Yue，et al.The dynamic adsorption of Mn（Ⅱ） in water by alkali modified pomelo peel biochar［J］.Journal of Chongqing University，2021，44（6）：96-108，126.
8	MEHTA D， MAZUMDAR S， SINGH S K.Magnetic adsorbents for the treatment of water/wastewater：A review［J］.Journal of Water Process Engineering，2015，7：244-265.
9	张茜，刘方，杨爱江，等.Mg-HAp对煤矸石中Mn²⁺的吸附特性及固定效果［J］.工业水处理，2021，41（1）：61-66.
	ZHANG Qian， LIU Fang， YANG Aijiang，et al.Adsorption characteristics and fixation effect of Mg-HAp on Mn²⁺ in coal gangue［J］.Industrial Water Treatment，2021，41（1）：61-66.
10	张鹏，王雨露，丁文杰，等.新型巯基絮凝剂PAM-GSH的合成及除Mn（Ⅱ）性能研究［J］.化工学报，2019，70（5）：1932-1941，1656.
	ZHANG Peng， WANG Yulu， DING Wenjie，et al.Synthesis of new sulfhydryl flocculant PAM-GSH and its performance in removing Mn（Ⅱ）［J］.CIESC Journal，2019，70（5）：1932-1941，1656.
11	周爱玲，贾爱忠，赵新强，等.污水重金属离子选择性吸附的研究进展［J］.材料导报，2023，37（9）：50-59.
	ZHOU Ailing， JIA Aizhong， ZHAO Xinqiang，et al.Research progress on selective adsorption of heavy metal ions in sewage［J］.Materials Reports，2023，37（9）：50-59.
12	CHEN Zhenzhen， LIU Yiling， MAO Lianzhen，et al.Effect of cation doping on the structure of hydroxyapatite and the mechanism of defluoridation［J］.Ceramics International，2018，44（6）：6002-6009.
13	钱程，张卫民.纳米HAP复合型材料吸附水中镍离子性能［J］.无机盐工业，2019，51（2）：45-49.
	QIAN Cheng， ZHANG Weimin.Capacity of nano HAP composite for adsorption of Ni²⁺ in water［J］.Inorganic Chemicals Industry，2019，51（2）：45-49.
14	刘诗婷，么强，陈芳，等.腐殖酸联合铁氧化物去除水体中重金属的研究进展［J］.工业水处理，2020，40（5）：7-11.
	LIU Shiting， YAO Qiang， CHEN Fang，et al.Research progress on removal of heavy metals from water by humic acid combined with iron oxide［J］.Industrial Water Treatment，2020，40（5）：7-11.
15	XIAO Jiang， HU Rui， CHEN Guangcai，et al.Facile synthesis of multifunctional bone biochar composites decorated with Fe/Mn oxide micro-nanoparticles：Physicochemical properties，heavy metals sorption behavior and mechanism［J］.Journal of Hazardous Materials，2020，399：123067.
16	胡冬雪，张飞杰，周燕，等.腐殖酸负载羟基磷灰石对废水中Cd²⁺吸附性能的影响［J］.环境科学学报，2019，39（12）：4022-4030.
	HU Dongxue， ZHANG Feijie， ZHOU Yan，et al.Effect of humic acid load hydroxyapatite on the adsorption of Cd²⁺ in wastewater［J］.Acta Scientiae Circumstantiae，2019，39（12）：4022-4030.
17	宋海燕，程旭.水分对土壤近红外光谱检测影响的二维相关光谱解析［J］.光谱学与光谱分析，2014，34（5）：1240.
	SONG Haiyan， CHENG Xu.Analysis of the effect of moisture on soil spectra detection by using two-dimensional correlation near infrared spectroscopy［J］.Spectroscopy and Spectral Analysis，2014，34（5）：1240.
18	SUN Lingmin， WU Junshu， WANG Jinshu，et al.Fabricating hydroxyapatite functionalized biochar composite using steel slag and Hami melon peel for Pb（Ⅱ） and Cd（Ⅱ） removal［J］.Colloids and Surfaces A：Physicochemical and Engineering Aspects，2023，666：131310.
19	袁秋华，石鑫，吴文珊，等.羟基磷灰石-氧化石墨烯复合微球的制备及性能［J］.深圳大学学报（理工版），2022，39（4）：447-455.
	YUAN Qiuhua， SHI Xin， WU Wenshan，et al.Preparation and performance of hydroxyapatite-graphene oxide composite microspheres［J］.Journal of Shenzhen University（Science and Engineering），2022，39（4）：447-455.
20	覃海富，张卫民.pH及离子强度对石英砂负载羟基磷灰石吸附锰的影响［J］.有色金属（冶炼部分），2018（6）：71-75.
	QIN Haifu， ZHANG Weimin.Effect of pH value and ionic strength on manganese adsorption on hydroxyapatite coated quartz sands［J］.Nonferrous Metals（Extractive Metallurgy），2018（6）：71- 75.
21	LI Wanlu， CAI Gege， LUO Kun，et al.Synthesis of magnesium-modified ceramsite from iron tailings as efficient adsorbent for phosphorus removal［J］.Separation and Purification Technology，2023，326：124817.

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Hydroxyapatite composite humic acid and its removal of Mn（Ⅱ）

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