冶炼废渣吸附脱除硫化氢的研究进展

doi:10.19964/j.issn.1006-4990.2021-0095

Abstract

Abstract:

Hydrogen sulfide（H₂S） is a kind of highly toxic pollutant which seriously endangers atmospheric environment and human health.H₂S widely exists in nature and many production processes.Dry desulfurization is widely used in the removal of H₂S-containing exhaust gas due to its advantages such as easy operation,strong stability and high desulfurization efficiency.Adsorption is the most common method of dry desulfurization.However,the adsorbent is consumed in large quantities during the adsorbing process,which restricts the desulfurization effect and increases the cost.Smelting waste slag is a potential desulfurizer,which has the characteristics of wide sources,large quantity and excellent surface physicochemical properties.The research progress of H₂S removal by different adsorbents of smelting waste slags was summarized,its advantages and disadvantages were analyzed,and factors of affecting adsorption and regeneration of adsorbent were discussed.Finally,in view of the existing problems such as single research scheme and few modification methods of adsorbent,future research directions were proposed,including setting up multi-component dynamic breakthrough adsorption test and exploring a variety of modification methods.

Key words: hydrogen sulfide, adsorbent, regeneration, smelting waste slag

CLC Number:

TQ125.12

JIANG Qi,HE Yongmei,WU Yonglin,JIANG Ming. Research progress of adsorption removal of hydrogen sulfide by smelting waste slag[J]. Inorganic Chemicals Industry, 2021, 53(11): 36-41.

Figures/Tables 4

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Table 2

References 40

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吸附材料	粒径大小	吸附条件	H₂S浓度	H₂S最高去除能力
LD 钢渣^[21]	<212 μm; 212~500 μm	固定床;室温（25 ℃±2 ℃）	1×10^-3 （体积分数）	180 mg/kg
BOF 钢渣^[22]	<1 mm; 1~6 mm	间歇式反应器,300 r/min搅拌;室温（20 ℃）	20% （体积分数）	119 g/kg
BOF 钢渣^[23]	<0.106 mm; 0.106~4.75 mm	固定床	20% （体积分数）	38 g/kg
钢渣^[24]	<0.15 mm; 0.15~0.85 mm	固定床;50 ℃	911 mg/m³	98.86%

分类	吸附剂	再生方式	再生次数	再生效率/%
矿渣^[27]	30%粒化高炉矿渣改性土壤	自然通风1 h	3	82.0
氨浸渣^[30]	大洋锰结核氨浸渣	热空气氧化再生	9	97.9
氨浸渣^[32]	氨浸渣煅烧产物	常温空气氧化再生	4	62.8
赤泥^[37]	赤泥脱硫剂	常温空气氧化再生	4	62.7

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Research progress of adsorption removal of hydrogen sulfide by smelting waste slag

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