Inorganic Chemicals Industry ›› 2023, Vol. 55 ›› Issue (7): 32-37.doi: 10.19964/j.issn.1006-4990.2022-0487
• Reviews and Special Topics • Previous Articles Next Articles
YU Hui1(), WANG Yubin1, LIAO Zhejun1,2, YANG Yunguang1,2
Received:
2022-08-17
Online:
2023-07-10
Published:
2023-07-13
CLC Number:
YU Hui, WANG Yubin, LIAO Zhejun, YANG Yunguang. Overview of recycling and utilization process of waste ternary lithium-ion power batteries[J]. Inorganic Chemicals Industry, 2023, 55(7): 32-37.
Table 1
Comparison of cathode materials and their performance"
正极材料 | 主要成分 | 理论能量密度/ (mA·h·g-1) | 实际能量密度/ (mA·h·g-1) | 电压/ V | 循环性能/ 次数 | 资源 | 环保性 | 安全性能 | 适用温度/ ℃ |
---|---|---|---|---|---|---|---|---|---|
镍酸锂 | LiNiO2 | 274 | 190~210 | 2.5~4.1 | 差 | 丰富 | 镍有毒 | 差 | N/A |
钴酸锂 | LiCoO2 | 274 | 135~140 | 3.6 | >300 | 匮乏 | 钴有毒 | 差 | -20~55 |
锰酸锂 | LiMnO2 | 286 | 200 | 3.4~4.3 | 差 | 丰富 | 无毒 | 良好 | 高温不稳定 |
磷酸铁锂 | LiFePO4 | 170 | 130~140 | 3.2~3.7 | >2 000 | 非常丰富 | 无毒 | 好 | -20~75 |
镍钴锰三元材料 | LiNiCoMnO2 | 278 | 155~165 | 3.0~4.5 | >800 | 匮乏 | 镍、钴有毒 | 良好 | -20~55 |
1 | 荆乾坤.典型锂离子电池正极材料的湿法回收与再生基础研究[D].北京:北京科技大学,2021. |
JING Qiankun.Basic research on wet chemical recovery and regeneration of typical cathode materials of lithium-ion batteries[D].Beijing:University of Science and Technology Beijing,2021. | |
2 | 张蕊.新能源车火爆催生千亿市场,电池回收“一天一价”:新注册企业增26倍行业急速扩张,新蓝海还是加速变红海?[N].每日经济新闻,2022-01-11(5). |
3 | 李扬,王军.退役锂离子电池筛选分类方法设计与分析[J].电池,2020,50(4):403-407. |
LI Yang, WANG Jun.Design and analysis of screening and classification methods for retired Li-ion battery[J].Battery Bimonthly,2020,50(4):403-407. | |
4 | 谭震,范茂松,赵光金,等.动力电池梯次利用国家标准体系分析[J].电池,2022,52(4):443-446. |
TAN Zhen, FAN Maosong, ZHAO Guangjin,et al.Analysis of national standard system for power battery echelon utilization[J].Battery Bimonthly,2022,52(4):443-446. | |
5 | 肖武坤,张辉.中国废旧车用锂离子电池回收利用概况[J].电源技术,2020,44(8):1217-1222. |
XIAO Wukun, ZHANG Hui.Recycling status of spent lithium-ion batteries for electric vehicle in China[J].Chinese Journal of Power Sources,2020,44(8):1217-1222. | |
6 | 梁新成,张勉.车载退役锂离子电池回收研究[J].电源学报,2022,20(4):86-91. |
LIANG Xincheng, ZHANG Mian.Study on recycling of ex-service lithium-ion batteries used in electric vehicles[J].Journal of Power Supply,2022,20(4):86-91. | |
7 | 杨健,秦吉涛,李芳成,等.废旧锂离子电池的湿法回收研究进展[J].中南大学学报(自然科学版),2020,51(12):3261-3278. |
YANG Jian, QIN Jitao, LI Fangcheng,et al.Review of hydrometallurgical processes for recycling spent lithium-ion batteries[J].Jo- | |
urnal of Central South University(Science and Technology),2020,51(12):3261-3278. | |
8 | HANISCH C, LOELLHOEFFEL T, DIEKMANN J,et al.Recycling of lithium-ion batteries:A novel method to separate coating and foil of electrodes[J].Journal of Cleaner Production,2015,108:301-311. |
9 | HE Lipo, SUN Shuying, SONG Xingfu,et al.Recovery of cathode materials and Al from spent lithium-ion batteries by ultrasonic cleaning[J].Waste Management,2015,46:523-528. |
10 | 田庆华,邹艾玲,童汇,等.废旧三元锂离子电池正极材料回收技术研究进展[J].材料导报,2021,35(1):1011-1022. |
TIAN Qinghua, ZOU Ailing, TONG Hui,et al.Research progress on recycling technology of cathode materials for spent ternary lithium-ion batteries[J].Materials Reports,2021,35(1):1011-1022. | |
11 | LU Mi, ZHANG Houan, WANG Bingchen,et al.The re-synthesis of LiCoO2 from spent lithium ion batteries separated by vacuum-assisted heat-treating method[J].International Journal of Electrochemical Science,2013,8(6):8201-8209. |
12 | 董仲珍,冯强,李本盛.三元锂离子电池正极材料浸出回收工艺进展[J].中国环境管理干部学院学报,2018,28(6):59-62,70. |
DONG Zhongzhen, FENG Qiang, LI Bensheng.Leaching and reco- | |
very process of cathode materials for ternary lithium ion battery[J].Journal of Environmental Management College of China,2018,28(6):59-62,70. | |
13 | HE Lipo, SUN Shuying, SONG Xingfu,et al.Leaching process for recovering valuable metals from the LiNi1/3Co1/3Mn1/3O2 cathode of lithium-ion batteries[J].Waste Management,2017,64:171- 181. |
14 | 邹超,潘君丽,刘维桥,等.湿法回收锂离子电池三元正极材料的进展[J].电池,2018,48(2):130-134. |
ZOU Chao, PAN Junli, LIU Weiqiao,et al.Progress in hydrometallurgical process for recycling ternary cathode material of Li-ion battery[J].Battery Bimonthly,2018,48(2):130-134. | |
15 | 袁双,卢立峰,张宁远,等.废旧锂离子电池正极材料中钴的回收与高值化利用[J].中国科技论文,2020,15(12):1359-1363. |
YUAN Shuang, LU Lifeng, ZHANG Ningyuan,et al.Recovery and high value utilization of cobalt in cathode materials of spent lithium-ion battery[J].China Sciencepaper,2020,15(12): 1359-1363. | |
16 | ZHAO Jingjing, ZHANG Beilei, XIE Hongwei,et al.Hydrometallurgical recovery of spent cobalt-based lithium-ion battery cathodes using ethanol as the reducing agent[J].Environmental Research,2020,181:108803. |
17 | 赵磊.废旧锂离子电池有机酸浸出回收钴、锂金属研究[D].扬州:扬州大学,2021. |
ZHAO Lei.Study on recovery of cobalt and lithium metals by organic acid leaching of waste lithium ion batteries[D].Yangzhou:Yangzhou University,2021. | |
18 | VIROLAINEN S, FALLAH FINI M, LAITINEN A,et al.Solvent extraction fractionation of Li-ion battery leachate containing Li,Ni,and Co[J].Separation and Purification Technology,2017,179:274-282. |
19 | JOO S H, SHIN D,OH C,et al.Extraction of Manganese by alkyl monocarboxylic acid in a mixed extractant from a leaching solution of spent lithium-ion battery ternary cathodic material[J].Journal of Power Sources,2016,305:175-181. |
20 | JOO S H, SHIN D J,OH C,et al.Selective extraction and separation of nickel from cobalt,manganese and lithium in pre-treated leach liquors of ternary cathode material of spent lithium-ion batteries using synergism caused by Versatic 10 acid and LIX |
84-I[J].Hydrometallurgy,2016,159:65-74. | |
21 | 李本盛.废旧锂离子电池中Li,Ni,Co的湿法工艺回收与利用[D].赣州:江西理工大学,2020. |
LI Bensheng.Recycling and utilization of Li,Ni and Co from spent lithium-ion batteries by wet precess[D].Ganzhou:Jiangxi University of Science and Technology,2020. | |
22 | 张笑笑.废旧锂离子电池的回收处理与资源化利用[D].北京:北京理工大学,2016. |
ZHANG Xiaoxiao.Recycling and resource utilization of spent lithium-ion batteries[D].Beijing:Beijing Institute of Technology,2016. | |
23 | NIE Min, XIA Yunfei, WANG Zhenbo,et al.Effects of precursor particle size on the performance of LiNi0.5Co0.2Mn0.3O2 cathode material[J].Ceramics International,2015,41(10):15185-15192. |
24 | ZHANG Zheming, HE Wenzhi, LI Guangming,et al.Ultrasound-assisted hydrothermal renovation of LiCoO2 from the cathode of spent lithium-ion batteries[J].International Journal of Electrochemical Science,2014,9(7):3691-3700. |
25 | 王珊.高镍正极材料LiNi1- x Mg x O2的制备及改性研究[D].哈尔滨:哈尔滨工业大学,2021. |
WANG Shan.Synthesis and structure optimization of LiNi1- x Mg x O2 high nickel binary cathode material[D].Harbin:Harbin Institute of Technology,2021. | |
26 | 谭燚,缪畅,聂炎,等.废旧锂离子电池三元正极材料的回收与再利用工艺研究进展[J].人工晶体学报,2020,49(10):1944-1951. |
TAN Yi, MIAO Chang, NIE Yan,et al.Review on recycling and utilizing processes of ternary cathode materials in spent lithium-ion batteries[J].Journal of Synthetic Crystals,2020,49(10):1944-1951. | |
27 | 吴小龙,王晨麟,陈曦,等.废旧锂离子电池市场规模及回收利用技术[J].环境科学与技术,2020,43(S2):179-183. |
WU Xiaolong, WANG Chenlin, CHEN Xi,et al.Market scale and recycling technology of waste lithium-ion batteries[J].Environmental Science & Technology,2020,43(S2):179-183. | |
28 | 贺觉渊.工信部:今年新能源车销量料达500万辆[N].证券时报,2022-01-13(A02). |
29 | 祝嫣然.工信部:加快推进动力电池回收利用立法[N].第一财经日报,2021-10-20(A02). |
30 | 杨洁,李嫒嫒.重点行业碳达峰实施方案明确[N].中国证券报,2021-12-04(A05). |
31 | 孙立极,史一棋.建好动力电池回收网[N].人民日报,2021-08-02(7). |
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