无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (12): 19-.

• 论文 • 上一篇    下一篇

钛酸钡纳米复合材料制备与性能研究

韩淑芬1,陈伟伟2,于 洁1   

  1. 1.内蒙古机电职业技术学院,内蒙古呼和浩特 010070;2.内蒙古工业大学
  • 出版日期:2016-12-10 发布日期:2016-12-08

Study on synthesis and properties of barium titanate nano-composites

Han Shufen1,Chen Weiwei2,Yu Jie1   

  1. 1.Inner Mongolia Technical College of Mechanics and Electrics,Hohhot 010070,China;
    2.Inner Mongolia University of Technology
  • Published:2016-12-10 Online:2016-12-08

摘要: 对钛酸钡颗粒进行羟基化和巯基官能化处理,将纳米银粒子成功接枝到钛酸钡颗粒表面制备了xAg@BT颗粒(x为银质量分数,BT为钛酸钡),并用溶液共混法制备了Ag@BT/PVDF纳米复合材料(PVDF为聚偏氟乙烯)。结果表明,xAg@BT颗粒为具有草莓结构的纳米颗粒,尺寸为2~16 nm的银粒子成功装饰在钛酸钡颗粒表面;纳米银粒子的引入可以降低复合材料在低频下的介电损耗和电导率,且当纳米银粒子质量分数为1.0%时复合材料的特征击穿强度达到最大值;与传统BT/PVDF纳米复合材料相比,1.0%Ag@BT/PVDF纳米复合材料具有更优良的电性能。

关键词: 钛酸钡, 复合材料, 银, 介电性能

Abstract: Barium titanate particles were hydroxyl and mercapto functionalized,and nano-sized Ag particles successfully grafted onto the surface of barium titanate to prepare xAg@BT(x is the mass fraction of Ag and BT is barium titanate) parti- cles,and Ag@BT/PVDF and BT/PVDF nano composite materials were finally prepared by solution blending method.Results showed that,xAg@BT nano-sized particles had a core-strawberry structure,Ag particles with the size of 2~16 nm was success- fully decorated on the surface of barium titanate particles;dielectric loss and electrical conductivity of the composite were de- creased at low frequency as the introduction of nano-sized Ag particles,and when the mass fraction of Ag nano-sized particles was 1.0%,the composite′s characteristics breakdown strength reached the maximum value.Compared with the traditional composite material nano BT/PVDF,1%Ag@BT/PVDF composite had more excellent electrical properties.

Key words: barium titanate;composite materials;Ag, dielectric properties

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