无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (9): 29-.

• 论文 • 上一篇    下一篇

氨气法制备多形貌氢氧化镁及 对氧化镁活性的影响*

胡 含,谢佳阳,李 雪, 王怀士, 常 鹏, 刘云义   

  1. 沈阳化工大学化学工程学院,辽宁沈阳 110142
  • 出版日期:2014-09-10 发布日期:2014-09-22

Preparation of Mg(OH)2 with different morphologies by ammonia method and research of their influences on MgO activity

 HU   Han, XIE  Jia-Yang, LI   Xue,   Wang-Huai-Shi,   Chang- Peng,   Liu-Yun-Yi   

  1. College of Chemical Engineering, Shenyang University of Chemical Technology,Shenyang 110142,China
  • Published:2014-09-10 Online:2014-09-22

摘要: 研究了不同镁盐原料对制得的氧化镁晶体形貌的影响。以3种镁盐为原料、氨气为沉淀剂制备了不同形貌的前驱体,通过煅烧热分解法制备氧化镁晶体。采用扫描电镜、X射线衍射、热重(TG)分析和激光粒度分布分析对所得氧化镁产品进行表征,选用柠檬酸法测定氧化镁活性。结果表明,以六水合氯化镁、六水合硝酸镁、硫酸镁为原料制备的氧化镁形貌分别为块状、片状、花球状。通过对不同煅烧条件制备的不同形貌氧化镁活性的研究,得出在升温速率为10 ℃/min条件下升高温度到600 ℃恒温煅烧2 h所得氧化镁活性最高,不同形貌氧化镁在相同煅烧条件下的活性不同:块状>片状>花球状。

关键词: 氧化镁, 活性, 形貌

Abstract: Effect of different magnesium salts on the morphologies of MgO crystals was investigated.The precursors [Mg(OH)2]with different morphologies were synthesized by employing three kinds of magnesium salts as raw materials and NH3(g) as precipitant,and then different morphologies of magnesium oxide(MgO) crystals by calcining the precursors. Scanning electron microscope(SEM),X-ray powder diffraction(XRD),TG analyzer,and laser particle size analyzer were employed to characterize the products,and citrate method was used for determination of magnesium oxide activities.Results indicated that the morphologies of MgO crystals were tetragonal massive,flake,and flower spherical with the raw materials of MgCl2·6H2O,Mg(NO3)·6H2O,and MgSO4,respectively.By means of the study on activities of magnesium oxide with dif- ferent morphologies prepared under different calcined conditions,it was concluded that magnesium oxide activity was  the highest under the heating rate of 10 ℃/min  to 600 ℃ for 2 h.Different morphologies of magnesium oxide under the same calcination condition had different  activities: tetragonal massive>flake>flower spherical.

Key words: MgO, activity, morphology