自清洁膜材料研究进展

doi:10.19964/j.issn.1006-4990.2021-0514

摘要/Abstract

摘要：

以自清洁材料在光伏行业应用为例,综述了太阳能电池玻璃自清洁常用膜材料纳米二氧化硅和纳米二氧化钛应用发展历程、原理及存在的主要问题;分析了纳米二氧化钛自清洁膜材料难以商业化应用的主要原因;结合笔者相关研究工作,介绍了纳米石墨烯自清洁材料研究开发进展,建议加强纳米石墨烯在光伏、纺织、污水处理等行业的自清洁膜材料的应用研究;认为纳米石墨烯是促进自清洁技术升级换代的黑材料,随着纳米石墨烯复合材料的制备方法和技术不断更新,纳米石墨烯必将被更广泛地应用到自清洁领域中。

关键词: 纳米SiO₂, 纳米TiO₂, 石墨烯, 自清洁膜

Abstract:

Taking the application of self-cleaning materials in the photovoltaic industry as an example,the application development process,principles and main problems of nano-SiO₂ and nano-TiO₂ were summarized,which were commonly used as film materials for self-cleaning of solar cell glasses.And the main reason for the difficulty in commercial application of nanoTiO₂ self-cleaning film materials was analyzed.Combined with the author′s relevant research work,the research and development progress on nano-graphene self-cleaning anti-reflection film materials was introduced,and it was recommended to strengthen the self-cleaning film materials of nano-graphene in photovoltaic,textile,sewage treatment and other industries.It was believed that nano-graphene was the black material that promoted the upgrading of self-cleaning technology.With the continuous updating of preparation methods and technologies of nano-graphene composite materials,nano-graphene would be more widely used in the field of self-cleaning.

Key words: nano-SiO₂, nano-TiO₂, graphene, self-cleaning film

中图分类号:

TQ127.11

张发荣,凡甜甜,郭燕云,李璐,刘炳光,李建生. 自清洁膜材料研究进展[J]. 无机盐工业, 2022, 54(4): 74-80.

ZHANG Farong,FAN Tiantian,GUO Yanyun,LI Lu,LIU Bingguang,LI Jiansheng. Research progress on self-cleaning film materials[J]. Inorganic Chemicals Industry, 2022, 54(4): 74-80.

图/表 3

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材料	制备方法	禁带宽度/eV	自清洁机制	应用
WO₃^[24]	电沉积Al-W合金,化学溶解铝,表面热处理形成WO₃膜层	2.7	光催化	降解有机物
TiO₂/ZrO₂^[25]	溶胶-凝胶法	ZrO₂：5.0	光催化、亲水性	降解有机物、防尘
ZnS^[26]	自发明方法：一锅法	3.6	光催化	降解有机物
ZnO/SnO₂^[27]	溶胶-凝胶法	SnO₂：3.5	光催化、超亲水性	降解有机物、防尘、防雾
TiO₂/Fe₂O₃^[28]	溶胶-凝胶法	Fe₂O₃：2.2	光催化、亲水性	降解有机物、防尘
CuO^[29]	喷雾热解技术	1.7	超疏水性	防尘
TiO₂/CdS/Au^[30]	—	CdS：2.4	光催化	降解有机物
CeO₂^[31]	溶胶-凝胶法	2.94	超疏水性、亲油性	油水分离
MnO₂^[32]	等离子体增强化学气相沉积	0.25	光致亲水、固相光催化	防雾、自清洁及水净化

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