无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2024, Vol. 56 ›› Issue (8): 54-59.doi: 10.19964/j.issn.1006-4990.2023-0541

• 研究与开发 • 上一篇    下一篇

氧化石墨烯对再生砂超高性能混凝土力学及抗氯离子渗透性能的影响

张瑞君1(), 陈国良2, 宋春草1, 朱亚飞3   

  1. 1.郑州工商学院工学院,河南 郑州 450045
    2.河南豫之筑建设工程有限公司,河南 郑州 450045
    3.合肥工业大学土木与水利工程学院,安徽 合肥 230009
  • 收稿日期:2023-11-13 出版日期:2024-08-10 发布日期:2024-09-26
  • 作者简介:张瑞君(1989— ),女,讲师,主要从事建筑材料分析、桥梁结构抗震分析及结构优化分析研究;E-mail:172294127@qq.com
  • 基金资助:
    河南省重点研发与推广专项(212102110191)

Effects of graphene oxide on mechanical properties and chloride penetration resistance of ultra⁃high performance concrete incorporating recycled sand

ZHANG Ruijun1(), CHEN Guoliang2, SONG Chuncao1, ZHU Yafei3   

  1. 1.School of Engineering,Zhengzhou Technology and business University,Zhengzhou 450045,China
    2.Henan ;Yuzhizhu Construction Engineering Co. ,Ltd. ,Zhengzhou 450045,China
    3.School of Civil and Hydraulic;Engineering,Hefei University of Technology,Hefei 230009,China
  • Received:2023-11-13 Published:2024-08-10 Online:2024-09-26

摘要:

鉴于再生砂(RS)部分取代石英砂(QS)制备再生砂超高性能混凝土(RS-UHPC)的力学性能和耐久性降低的问题,以不同氧化石墨烯(GO)掺量为试验参数,探究GO对UHPC工作性能、力学性能及抗氯离子渗透性能的影响规律,并通过差热-热重分析和扫描电子显微镜等手段揭示其增强机理。结果表明:掺入RS会降低UHPC的流动度、力学性能及UHPC抗氯离子渗透性能;随着GO掺量的增加,RS-UHPC流动度逐渐下降,但其力学性能、抗氯离子渗透性能均显著提升,当GO质量分数为0.06%时,RS-UHPC的28 d抗压强度和抗折强度分别提升11.8%和49.6%,氯离子扩散系数降低31.8%,抗裂韧性显著提升。RS的内养护效应和GO的晶核效应均促进水泥水化、降低基体孔隙率、改善再生砂与基体的界面过渡区,从而提升RS-UHPC的力学性能、抗裂性能和抗氯离子渗透性能。

关键词: 超高性能混凝土, 氧化石墨烯, 再生砂, 力学性能, 界面过渡区

Abstract:

In view of the problems of mechanical properties and durability of recycled sand(RS) partially replacing quartz sand(QS) in the preparation of recycled sand ultra⁃high performance concrete(RS-UHPC),different dosages of graphene oxide(GO) were used as experimental parameters to explore the influence of GO on the working performance,mechanical properties,and chloride ion penetration resistance of UHPC,and to reveal its reinforcement mechanism through TG-DSC and SEM methods.The results showed that the addition of RS could reduce the flowability and mechanical properties of UHPC,as well as its resistance to chloride ion penetration.As the GO content increased,the flowability of RS-UHPC was further decreased,but its mechanical properties and resistance to chloride ion penetration were significantly improved.When the GO content was 0.06%,the 28 d compressive strength and flexural strength of RS-UHPC were increased by 11.8% and 49.6%,respectively.The chloride ion diffusion coefficient was decreased by 31.8%,and the crack toughness was significantly improved.The internal curing effect of RS and the nucleation effect of GO both promoted cement hydration,reduced matrix porosity,improved the interface transition zone between recycled sand and matrix,thereby enhancing the mechanical properties,crack resistance,and chloride ion penetration resistance of RS-UHPC.

Key words: ultra?high performance concrete, graphene oxide, recycled sand, mechanical properties, interface transition zone

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