无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2012, Vol. 44 ›› Issue (12): 13-.

• 论文 • 上一篇    下一篇

微波外场中的硫酸钙碳热还原

刘海燕,刘代俊,杨 军,于 洋,邓 林   

  1. 四川大学化工学院,四川成都 610051
  • 发布日期:2012-12-11

Carbonthermal reduction of calcium sulfate in microwave field

 LIU  Hai-Yan, LIU  Dai-Jun, YANG   Jun, YU   Yang, DENG   Lin   

  1. School of Chemical Engineering,Sichuan University,Chengdu 610065,China
  • Online:2012-12-11

摘要: 采用微波加热介质技术,研究了煤粉作为还原剂的硫酸钙碳热还原反应。结果显示,在碳与硫物质的量比为0.6、反应温度为1 200 ℃、反应时间为10 min条件下,硫酸钙的分解率可达98.53%。二氧化硅作为助熔剂,促进了固相反应。试验中掺入石墨粉,降低了反应温度,并进一步缩短了反应时间。微波场中硫酸钙的反应速率高于普通碳热还原反应。

关键词: 微波效应, 碳热还原, 硫酸钙, 石膏, 二氧化硫

Abstract: Carbonthermal reduction of calcium sulfate heated by microwave with pulverized coal as  reductant was studied.Results showed that the decomposition rate of calcium sulfate could reach 98.53% while the amount-of-substance ratio of carbon to sulfur was 0.6,the reaction temperature was 1 200 ℃,and reaction time was 10 min.The fluxing agent silica  enhanced the reaction rate in solid state.Doping graphite powder could not only bring down the reaction temperature,but also reduced the reaction time.It was obvious that the reaction rate of calcium sulfate in microwave field was higher than that in normal situation.

Key words: microwave effect, carbonthermal reduction, calcium sulfate, gypsum, sulfur dioxide

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