基于水热/溶剂热法制备不同形貌LiNi0.8Co0.1Mn0.1O2 锂离子电池正极材料

doi:10.19964/j.issn.1006-4990.2021-0234

摘要/Abstract

摘要：

基于水热/溶剂热法制备LiNi_0.8Co_0.1Mn_0.1O₂电极材料,以镍、钴、锰乙酸盐为原料,以六亚甲基四胺为沉淀剂、水或乙醇为溶剂,通过调节溶剂组分控制Ni_0.8Co_0.1Mn_0.1（OH）₂（NCM）的成核与生长速率,从而合成两种形貌不同的Ni_0.8Co_0.1Mn_0.1（OH）₂前驱体,再经过混锂煅烧获得LiNi_0.8Co_0.1Mn_0.1O₂正极材料,研究比较了其电化学性能。以水为溶剂通过水热法合成的前驱体样品呈现出由一次片状颗粒紧密堆积组成的长方体状二次颗粒形貌,经混锂煅烧得到的产物表现出较高的放电比容量,在0.5C倍率下首次放电比容量可达到189.70 mA·h/g,循环200次容量保持率为69.72%。以乙醇为溶剂通过溶剂热法合成得到球形二次颗粒前驱体,最终得到的产物具有多孔球形结构,表现出了优异的循环性能,0.5C首次放电比容量为178.65 mA·h/g,循环200次容量保持率仍高达94.55%。

关键词: 锂离子电池, 高镍正极材料, 水热, 溶剂热

Abstract:

LiNi_0.8Co_0.1Mn_0.1O₂electrode material was prepared by hydrothermal/solvothermal method.Two precursors of Ni_0.8Co_0.1Mn_0.1（OH）₂ with different morphology were synthesized by adjusting the solvent composition and controlling the nu-cleation and growth rate of Ni_0.8Co_0.1Mn_0.1（OH）₂ with nickel,cobalt and manganese acetate as raw materials,hexamethylene tetramine as precipitant and water or ethanol as solvent.LiNi_0.8Co_0.1Mn_0.1O₂ cathode material was obtained by lithium mixed calcination,and its electrochemical property was studied and compared.By using water as the solvent,the prepared precursor composed of rectangular parallelepiped secondary particles was synthesized,which were assembled by plate-like primary particles.The obtained product exhibited a high specific discharge capacity of 189.70 mA·h/g and a capacity retention of 69.72% after 200 cycles at 0.5C.By using ethanol as the solvent,the spherical secondary particle precursor was synthesized.The final product was evolved into porous spherical structure and exhibited excellent cycle performance.It delivered a specific discharge capacity of 178.65 mA·h/g and a high capacity retention of 94.55% after 200 cycles at 0.5C.

Key words: lithium-ion battery, Ni-rich cathode material, hydrothermal, solvothermal

中图分类号:

TQ131.11

吴兆国,曹骏,杨则恒. 基于水热/溶剂热法制备不同形貌LiNi_0.8Co_0.1Mn_0.1O₂ 锂离子电池正极材料[J]. 无机盐工业, 2022, 54(2): 72-77.

WU Zhaoguo,CAO Jun,YANG Zeheng. Preparation of LiNi_0.8Co_0.1Mn_0.1O₂ cathode materials with different morphologies based on hydrothermal/solvothermal method[J]. Inorganic Chemicals Industry, 2022, 54(2): 72-77.

图/表 9

图1

表1

图2

图3

表2

图4

图5

图6

表3

参考文献 17

[1]	MANTHIRAM A, KNIGHT J C, MYUNG S T, et al. Nickel-rich and lithium-rich layered oxide cathodes:Progress and perspectives[J]. Advanced Energy Materials, 2016, 6(1).Doi: 10.1002/aenm.201501010. doi: 10.1002/aenm.201501010
[2]	LARCHER D, TARASCON J M. Towards greener and more sustain-able batteries for electrical energy storage[J]. Nature Chemistry, 2014, 7(1):19-29. doi: 10.1038/nchem.2085
[3]	ANDRE D, KIM S J, LAMP P, et al. Future generations of cathode materials:An automotive industry perspective[J]. Journal of Mate-rials Chemistry A, 2015, 3(13):6709-6732.
[4]	SUN Y K. High-capacity layered cathodes for next-generation elec- tric vehicles[J]. ACS Energy Letters, 2019, 4(5):1042-1044. doi: 10.1021/acsenergylett.9b00652
[5]	LIU W, OH P, LIU X, et al. Nickel-rich layered lithium transition-metal oxide for high-energy lithium-ion batteries[J]. Angewandte Chemie International Ed., 2015, 54(15):4440-4457. doi: 10.1002/anie.201409262
[6]	MANTHIRAM A, SONG B, LI W, et al. A perspective on nickel-rich layered oxide cathodes for lithium-ion batteries[J]. Energy Storage Materials, 2017, 6:125-139. doi: 10.1016/j.ensm.2016.10.007
[7]	PARK K J, JUNG H G, KUO L Y, et al. Improved cycling stability of Li[Ni_0.90Co_0.05Mn_0.05]O₂ through microstructure modification by boron doping for Li-Ion Batteries[J]. Advanced Energy Materials, 2018, 8(25).Doi: 10.1002/aenm.201801202. doi: 10.1002/aenm.201801202
[8]	LI Q, DANG R, CHEN M, et al. Synjournal method for long cycle life lithium-ion cathode material:Nickel-rich core-shell LiNi_0.8Co_0.1Mn_0.1O₂[J]. ACS Applied Materials & Interfaces, 2018, 10(21):17850-17860.
[9]	LI L, CHEN Z, ZHANG Q, et al. A hydrolysis-hydrothermal route for the synjournal of ultrathin LiAlO₂-inlaid LiNi_0.5Co_0.2Mn_0.3O₂ as a high-performance cathode material for lithium-ion batteries[J]. Journal of Materials Chemistry A, 2014, 3(2):894-904. doi: 10.1039/C4TA05902F
[10]	WU F, WANG Z, SU Y, et al. Synjournal and characterization of ho-llow spherical cathode Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ assembled with nano-structured particles via homogeneous precipitation-hydrothermal synjournal[J]. Journal of Power Sources, 2014, 267:337-346. doi: 10.1016/j.jpowsour.2014.05.097
[11]	WU N, WU H, LIU H, et al. Solvothermal coating LiNi_0.8Co_0.15Al_0.05O₂ microspheres with nanoscale Li₂TiO₃ shell for long lifespan Li-ion battery cathode materials[J]. Journal of Alloys & Compounds, 2016, 665:48-56.
[12]	QUAN W, TANG Z, HONG Y, et al. Hydroxyl compensation effects on the cycle stability of nickel-cobalt layered double hydroxides synthesized via solvothermal method[J]. Electrochimica Acta, 2015, 182:445-451. doi: 10.1016/j.electacta.2015.09.118
[13]	PENG L, ZHU Y, KHAKOO U, et al. Self-assembled LiNi_1/3Co_1/3Mn_1/3O₂ nanosheet cathodes with tunable rate capabili-ty[J]. Nano Energy, 2015, 17:36-42. doi: 10.1016/j.nanoen.2015.07.031
[14]	HUANG Z D, LIU X M, OH S W, et al. Microscopically porous,in-terconnected single crystal LiNi_1/3Co_1/3Mn_1/3O₂ cathode material for Lithium-ion batteries[J]. Journal of Materials Chemistry, 2011, 21(29):10777-10784. doi: 10.1039/c1jm00059d
[15]	ZHAO J, WANG Z, WANG J, et al. Anchoring K + in Li + sites of LiNi_0.8Co_0.15Al_0.05O₂ cathode material to suppress its structural de-gradation during high-voltage cycling[J]. Energy Technology, 2018, 6(12):2358-2366. doi: 10.1002/ente.v6.12
[16]	DUAN Y, YANG L, ZHANG M J, et al. Insights into Li/Ni ordering and surface reconstruction during synjournal of Ni-rich layered ox-ides[J]. Journal of Materials Chemistry A, 2019, 7(2):513-519. doi: 10.1039/C8TA10553G
[17]	JOSÉ O L, CARLOS G Y, RIGOBERTO L J. Synjournal of advanced ceramics by hydrothermal crystallization and modified related methods[J]. Journal of Advanced Ceramics, 2012, 1(3):204-220. doi: 10.1007/s40145-012-0022-0

样品编号	a/nm	c/nm	c/a	I_（003）/I_（104）
LNCM-1	0.287 15	1.419 21	4.942 3	1.382 7
LNCM-2	0.286 21	1.414 48	4.942 1	1.378 5
LNCM-3	0.286 51	1.413 53	4.933 6	1.372 6

样品	ρ（Ni）/ （mg·L^-1）	ρ（Co）/ （mg·L^-1）	ρ（Mn）/ （mg·L^-1）	n（Ni）∶n（Co）∶ n（Mn）
LNCM-1	1 652.15	217.08	223.02	77.31∶10.23∶10.51
LNCM-2	1 960.45	264.62	260.86	77.12∶10.41∶10.27
LNCM-3	1 780.40	245.85	248.65	76.17∶10.52∶10.64

样品	D_Li⁺（cm²/s）（锂离子嵌入）	D_Li⁺（cm²/s）（锂离子脱出）
LNCM-1	6.97×10^-11	2.56×10^-11
LNCM-2	2.88×10^-11	1.41×10^-11
LNCM-3	1.18×10^-11	1.19×10^-11

首页

全国无机盐信息中心

中国化工学会

无机酸碱盐专业委员会

基于水热/溶剂热法制备不同形貌LiNi_0.8Co_0.1Mn_0.1O₂ 锂离子电池正极材料

Preparation of LiNi_0.8Co_0.1Mn_0.1O₂ cathode materials with different morphologies based on hydrothermal/solvothermal method

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 9

参考文献 17

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	狄璐, 王卫国, 陈珏先, 吴传淑. 过渡金属负载Silicalite-1分子筛的制备及其催化糠醛加氢性能研究[J]. 无机盐工业, 2024, 56(4): 125-132.
[2]	周海涛, 温承钦, 郑玲, 孙洁. 金属锂电池负极界面氮化硼修饰膜的研究[J]. 无机盐工业, 2024, 56(4): 85-89.
[3]	李亚广, 韩东战, 齐利娟. 废旧锂离子电池预处理及电解液回收技术研究现状[J]. 无机盐工业, 2024, 56(2): 1-10.
[4]	李超, 王丽萍, 戴崟, 高桂梅, 张云峰, 洪雨, 许立军, 崔永杰. 高硅渣碱熔水热合成13X分子筛及吸附铅铜锌离子研究[J]. 无机盐工业, 2023, 55(9): 88-93.
[5]	冯准. B/Al/Zr协同策略改善高镍单晶正极材料高温稳定性[J]. 无机盐工业, 2023, 55(8): 59-64.
[6]	于惠, 王榆彬, 廖折军, 杨云广. 废旧三元锂离子动力电池循环再生利用工艺概述[J]. 无机盐工业, 2023, 55(7): 32-37.
[7]	丁泓宇, 仲剑初, 王洪志, 张爽. 晶种诱导法水热合成滑石[J]. 无机盐工业, 2023, 55(5): 59-65.
[8]	朱志红, 朱永芳. 硅掺杂锰酸锂的自蔓延燃烧制备及其性能研究[J]. 无机盐工业, 2023, 55(5): 66-70.
[9]	陈彰旭, 傅明连, 朱丹琛, 郑炳云. 碳/石墨相氮化碳复合材料制备及其去除亚甲基蓝性能[J]. 无机盐工业, 2023, 55(3): 134-139.
[10]	董雄伟, 韩凤兰, 华炜, 李茂辉, 安长聪, 黄玉才. 硅锰渣基沸石的合成及其表征[J]. 无机盐工业, 2023, 55(12): 128-132.
[11]	田朋, 徐金钢, 徐前进, 刘坤吉, 庞洪昌, 宁桂玲. 纳米氧化铝浆料制备及用于改性锂电池正极材料[J]. 无机盐工业, 2023, 55(12): 43-49.
[12]	蒋德敏, 李顺梅, 李青青, 陈雨欣, 刘代俊. 氢氧化镁与七水硫酸镁水热法合成碱式硫酸镁晶须[J]. 无机盐工业, 2023, 55(12): 74-81.
[13]	彭秋桂, 杨帆, 吕仁亮, 向兰. 预还原对含杂硫酸氧钛溶液水热水解除铁影响[J]. 无机盐工业, 2023, 55(12): 95-101.
[14]	滕家阳, 冯庆革, 张璇, 覃方红, 冯靖航, 胡嘉文, 陈超宏. 铝灰资源化制备拟薄水铝石的研究[J]. 无机盐工业, 2023, 55(11): 130-138.
[15]	唐迪,王俊雄,陈稳,季冠军,马骏,周光敏. 退役锂离子电池正极材料直接回收的研究现状和展望[J]. 无机盐工业, 2023, 55(1): 15-25.

首 页