二氧化碳逆水煤气变换的研究进展

doi:10.19964/j.issn.1006-4990.2024-0445

Abstract

Abstract:

The Reverse Water-Gas Shift（RWGS） reaction，facilitated by the catalytic reaction between carbon dioxide and hydrogen，has become a crucial step in the production of high-value chemicals and fuels such as methanol，low-carbon olefins，aromatics，and gasoline.This review presents an in-depth analysis of the two primary mechanisms of the RWGS reaction：the redox mechanism and the intermediate mechanism.Additionally，recent advancements in RWGS research were comprehensively reviewed，the catalysts employed in this reaction were systematically categorized，analyzed，and summarized.These catalysts encompassed supported metal catalysts，oxide catalysts（including mixed oxides，spinels，and perovskites），and carbide catalysts.Moreover，the industrial applications of the RWGS reaction was analyzed and its future development was prospected.RWGS reaction could serve as an efficient method for integrating technologies like naphtha dehydroaromatization，ethylbenzene dehydrogenation for styrene production，low-carbon alkane dehydrogenation for olefin production，carbon dioxide capture，and synthetic electronic fuel production to realize efficient utilization of CO₂.It not only provided theoretical basis and guidance for developing new RWGS reaction catalysts but also offered feasible ideas and references for the future application scenarios of the RWGS reaction.

Key words: Reverse Water-Gas Shift, catalysts, reaction mechanism, CO₂

CLC Number:

TQ116

HOU Zhanggui, WU Chongchong, ZHANG Siran. Research progress of CO₂ conversion via Reverse Water-Gas Shift reaction[J]. Inorganic Chemicals Industry, 2024, 56(11): 105-115.

Figures/Tables 10

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催化剂	反应温度/℃	n（CO₂）∶ n（H₂）	空速/ ［mL·（g·h）^-1］	CO₂转化率/%	CO选择性/%
Pt/CeO₂^［12］	450	1∶3	43 200	35	98
Pt/TiO₂^［13］	600	1∶3	12 000	56	100
PtW/Al₂O₃^［14］	450	1∶3	34 200	42	78
Cu/CeO₂^［15］	500	1∶3	300 000	41	100
NiCo/SiO₂^［16］	500	1∶4	15 000	50	47
Ni₁₂P₅-SiO₂^［17］	600	1∶4	6 000	44.8	91.8
CuIn/ZrO₂^［18］	600	1∶4	3 000	48	100
NiMo/Al₂O₃^［19］	600	1∶1	30 000	34
Ni/CeO₂^［20］	650	1∶1	6 000	38	94
RuFe/CeO₂^［21］	800	1∶1	6 000	47.5	100
PtCs/TiO₂^［22］	500	1∶4	30 000	44	98
Ni/NiCeZr^［23］	550	1∶3	50 000	48	87.5

催化剂	反应温度/℃	n（CO₂）∶n（H₂）	空速/［mL·（g·h）^-1］	CO₂转化率/%	CO选择性/%
RuNi/Ce_0.5Zr_0.5O₂^［30］	700	1∶4	24 000	72	91
In₂O₃-CeO₂^［31］	500	1∶1	24 000	19.98	100
Ni/Ce-Zr-O^［32］	750	1∶1	30 000	49.66	99.65
Ga₂O₃-CeO₂^［26］	500	1∶1	4 800	15	100
BaZr_0.8Y_0.2O₃^［28］	600	1∶1	2 400	26.7	93
BaZr_0.8Y_0.16Zn_0.04O₃^［28］	600	1∶1	2 400	37.5	97
BaCe_0.7Zr_0.1Y_0.16Zn_0.04O₃^［28］	600	1∶1	2 400	10.8	74
CuAl₂O₄-α^［27］	400	1∶3	9 960	37	100
Co_3-_x Al _x O₄^［33］	500	1∶5	55 000	53	98
K₃CuAlFe^［25］	550	1∶1	1 830	35
CeO₂-CaO^［34］	650		20 000	49	100

催化剂	反应温度/℃	n（CO₂）∶ n（H₂）	空速/［mL·（g·h）^-1］	CO₂转化率/%	CO选择性/%
Cu/β-Mo₂C^［36］	500	1∶2	300 000	28.9	99.0
Cu/β-Mo₂C^［36］	600	1∶2	300 000	40.0	99.2
α-Mo₂C^［37］	400	1∶1	2 000	15.9	99.3
介孔MoC^［35］	400	1∶4	12 000	16	100
Mo₂C/Al₂O₃^［38］	400	1∶3	3 000	24	94.5
Mo₂C/SiO₂^［38］	400	1∶3	3 000	27.5	98.5
Mo₂C/TiO₂^［38］	400	1∶3	3 000	8.5	97
Mo _x C-B^［39］	350	1∶3	3 000	18	~98
α-MoC_1-_x^［40］	600	1∶4	36 000	60	99
β-Mo₂C^［40］	600	1∶4	36 000	60	98

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Research progress of CO₂ conversion via Reverse Water-Gas Shift reaction

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Research progress of CO2 conversion via Reverse Water-Gas Shift reaction