接力催化CO2制备高附加值化学品中催化剂的研究进展

doi:10.19964/j.issn.1006-4990.2024-0404

Abstract

Abstract:

The rapid development of global industrialization has led to excessive emissions of carbon dioxide（CO₂），which in turn has led to increasingly severe green house effect.The catalytic conversion of CO₂ into high value-added chemicals can achieve the recycling of carbon resources and energy conservation and emission reduction.With the continuous deepening of research on CO₂ thermal catalytic conversion and the construction of relay-catalysis systems，researchers had continuously achieved new scientific research results in the preparation of high value-added chemicals through CO₂ relay catalysis.By summarizing the mechanism and advantages of relay-catalysis reactions，as well as the recent structural characteristics，reaction mechanisms，and catalytic performance characteristics of various catalysts in the relay-catalysis reactions of CO₂ to prepare low-carbon olefins，aromatics，and oxygen-containing hydrocarbons，a detailed analysis was conducted on the role of bifunctional catalysts formed by the combination of various metal compounds and different molecular sieves in the reaction，and the key factors affecting catalytic performance on bifunctional catalysts were discussed.The adjustment measures of the structure，morphology，and binding mode of the active components of bifunctional catalysts in future relay-catalysis reactions were prospected，in order to improve the conversion rate of CO₂ and the selectivity of the target product.

Key words: relay-catalysis, CO₂, high value-added chemicals, metallic oxide, molecular sieves

CLC Number:

TQ116

FENG Qing, WANG Yansu, ZHOU Wei, LIU Yang, SUN Yanmin, NAN Jun. Research progress on catalysts for relay-catalysis of CO₂ to prepare high value-added chemicals[J]. Inorganic Chemicals Industry, 2024, 56(11): 81-94.

Figures/Tables 14

Fig.1

Fig.2

Fig.3

Fig.4

Table 1

Fig.5

Fig.6

Fig.7

Table 2

Fig.8

Table 3

Fig.9

Fig.10

Fig.11

References 56

1	The Global Carbon Budget Office.Global carbon budget 2023［R］.London：Earth System Science Data，2023.
2	李自琴，王康洲，高新华，等.CO₂加氢制高碳α-烯烃Fe基催化剂研究进展［J］.低碳化学与化工，2023，48（3）：11-21.
	LI Ziqin， WANG Kangzhou， GAO Xinhua，et al.Research progress on Fe-based catalysts for CO₂ hydrogenation to high carbon α-olefins［J］.Low-carbon Chemistry and Chemical Engineering，2023，48（3）：11-21.
3	ZHANG Wei， YANG Yu， LI Yunxin，et al.Recent progress on integrated CO₂ capture and electrochemical upgrading［J］.Materials Today Catalysis，2023，2：100006.
4	SU Junjie， LIU Chang， LIU Songlin，et al.High conversion of syngas to ethene and propene on bifunctional catalysts via the tailoring of SAPO zeolite structure［J］.Cell Reports Physical Science，2021，2（1）：100290.
5	邵斌，孙哲毅，章云，等.二氧化碳转化为合成气及高附加值产品的研究进展［J］.化工进展，2022，41（3）：1136-1151.
	SHAO Bin， SUN Zheyi， ZHANG Yun，et al.Recent progresses in CO₂ to syngas and high value-added products［J］.Chemical Industry and Engineering Progress，2022，41（3）：1136-1151.
6	成康，张庆红，康金灿，等.二氧化碳直接制备高值化学品中的接力催化方法［J］.中国科学：化学，2020，50（7）：743-755.
	CHENG Kang， ZHANG Qinghong， KANG Jincan，et al.Relay catalysis in the direct conversion of carbon dioxide to high-value chemicals［J］.Scientia Sinica Chimica，2020，50（7）：743-755.
7	郝金辉，施伟东.过渡金属（Mo，Fe，Co和Ni）基催化剂在电催化还原二氧化碳还原中应用［J］.催化学报，2018，39（7）：1157-1166.
	HAO Jinhui， SHI Weidong.Transition metal（Mo，Fe，Co，and Ni）-based catalysts for electrochemical CO2 reduction［J］.Chinese Journal of Catalysis，2018，39（7）：1157-1166.
8	王挺，章文文，毛庆，等.二氧化碳电还原制乙醇催化体系与材料研究进展［J］.无机盐工业，2024，56（7）：1-10，68.
	WANG Ting， ZHANG Wenwen， MAO Qing，et al.Research progress of catalytic system and materials for electrocatalytic reduction of carbon dioxide to ethanol［J］.Inorganic Chemicals Industry，2024，56（7）：1-10，68.
9	华凯敏，刘晓放，魏百银，等.过渡金属催化CO₂/H₂参与的羰基化研究进展［J］.物理化学学报，2021，37（5）：141-156.
	HUA Kaimin， LIU Xiaofang， WEI Baiyin，et al.Research progress regarding transition metal-catalyzed carbonylations with CO₂/H₂ ［J］.Acta Physico-Chimica Sinica，2021，37（5）：141-156.
10	JIAO Feng， LI Jinjing， PAN Xiulian，et al.Selective conversion of syngas to light olefins［J］.Science，2016，351（6277）：1065-1068.
11	LIU Xiaoliang， WANG Mengheng， ZHOU Cheng，et al.Selective transformation of carbon dioxide into lower olefins with a bifunctional catalyst composed of ZnGa₂O₄ and SAPO-34［J］.Chemical Communications，2018，54（2）：140-143.
12	CHENG Kang， LI Yubing， KANG Jincan，et al.Selectivity control by relay catalysis in CO and CO₂ hydrogenation to multicarbon compounds［J］.Accounts of Chemical Research，2024，57（5）：714-725.
13	MARTÍN N， CIRUJANO F G.Multifunctional heterogeneous catalysts for the tandem CO₂ hydrogenation-Fischer Tropsch synthesis of gasoline［J］.Journal of CO2 Utilization，2022，65：102176.
14	WANG Shunwu， WU Tijun， LIN Jun，et al.FeK on 3D graphene-zeolite tandem catalyst with high efficiency and versatility in direct CO₂ conversion to aromatics［J］.ACS Sustainable Chemistry & Engineering，2019，7（21）：17825-17833.
15	ZHANG Chundong， HU Kehao， CHEN Xixi，et al.Direct hydrogenation of CO₂ into valuable aromatics over K/Fe-Cu-Al @HZSM-5 tandem catalysts：Effects of zeolite surface acidity on aromatics formation［J］.Fuel Processing Technology，2023，248：107824.
16	BURK M J， LEE J R， MARTINEZ J P.A versatile tandem catalysis procedure for the preparation of novel amino acids and peptides［J］.Journal of the American Chemical Society，1994，116（23）：10847-10848.
17	BALEMA V P， HEY-HAWKINS E.Die CuCl-katalysierte reaktion von trimethylsilyl（t-butyl）chlorphosphan mit dimethylzirconocen：Ein beispiel der tandem-katalyse［J］.Zeitschrift Für Anorganische und Allgemeine Chemie，1996，622（12）：2053- 2056.
18	李永恒，吴冲冲，王文波，等.CO₂催化制备高附加值多碳含氧化合物的研究进展［J］.燃料化学学报（中英文），2024，52（4）：496-511.
	LI Yongheng， WU Chongchong， WANG Wenbo，et al.Research progress on CO₂ catalytic conversion to value-added oxygenates［J］.Journal of Fuel Chemistry and Technology，2024，52（4）：496-511.
19	王晓星，段永鸿，张俊峰，等.串联催化剂上CO₂催化转化制备高附加值烃类研究进展［J］.燃料化学学报，2022，50（5）：538-563.
	WANG Xiaoxing， DUAN Yonghong， ZHANG Junfeng，et al.Catalytic conversion of CO₂ into high value-added hydrocarbons over tandem catalyst［J］.Journal of Fuel Chemistry and Technology，2022，50（5）：538-563.
20	PODROJKOVÁ N， SANS V， ORIŇAK A，et al.Recent developments in the modelling of heterogeneous catalysts for CO₂ conversion to chemicals［J］.ChemCatChem，2020，12（7）：1802-1825.
21	SHARMA P， SEBASTIAN J， GHOSH S，et al.Recent advances in hydrogenation of CO₂ into hydrocarbons via methanol intermediate over heterogeneous catalysts［J］.Catalysis Science & Technology，2021，11（5）：1665-1697.
22	CHIU H H， YU B Y.Synthesis of green light olefins from direct hydrogenation of CO₂.PartⅡ：Detailed process design and optimization［J］.Journal of the Taiwan Institute of Chemical Engineers，2024，155：105287.
23	BARRIOS A J， PERON D V， CHAKKINGAL A，et al.Efficient promoters and reaction paths in the CO₂ hydrogenation to light olefins over zirconia-supported iron catalysts［J］.ACS Catalysis，2022，12（5）：3211-3225.
24	CHERNYAK S A， CORDA M， MARINOVA M，et al.Decisive influence of SAPO-34 zeolite on light olefin selectivity in methanol-meditated CO₂ hydrogenation over metal oxide-zeolite catalysts［J］.ACS Catalysis，2023，13（22）：14627-14638.
25	LI Jian， YU Tie， MIAO Dengyun，et al.Carbon dioxide hydrogenation to light olefins over ZnO-Y₂O₃ and SAPO-34 bifunctional catalysts［J］.Catalysis Communications，2019，129：105711.
26	LIU Xiaoliang， WANG Mengheng， YIN Haoren，et al.Tandem catalysis for hydrogenation of CO and CO₂ to lower olefins with bifunctional catalysts composed of spinel oxide and SAPO-34［J］.ACS Catalysis，2020，10（15）：8303-8314.
27	ZHANG Peng， MA Lixuan， MENG Fanhui，et al.Boosting CO₂ hydrogenation performance for light olefin synthesis over GaZrO _x combined with SAPO-34［J］.Applied Catalysis B：Environmental，2022，305：121042.
28	KIM S， JHAVERI C A， SASMAZ E.Impact of yttria-stabilized zirconia on direct CO₂ hydrogenation to light olefins over a tandem catalyst composed of In₂O₃/YSZ and SAPO-34［J］.Energy & Fuels，2023，37（10）：7361-7371.
29	GAO Peng， DANG Shanshan， LI Shenggang，et al.Direct production of lower olefins from CO₂ conversion via bifunctional cataly- sis［J］.ACS Catalysis，2018，8（1）：571-578.
30	WANG Sen， WANG Pengfei， QIN Zhangfeng，et al.Enhancement of light olefin production in CO₂ hydrogenation over In₂O₃-based oxide and SAPO-34 composite［J］.Journal of Catalysis，2020，391：459-470.
31	WANG Sen， ZHANG Li， ZHANG Wenyu，et al.Selective conversion of CO₂ into propene and butene［J］.Chem，2020，6（12）：3344-3363.
32	杨浪浪，孟凡会，张鹏，等.ZrCdO _x /SAPO-18双功能催化剂催化CO₂加氢合成低碳烯烃性能［J］.无机化学学报，2021，37（3）：448-456.
	YANG Langlang， MENG Fanhui， ZHANG Peng，et al.Catalytic performance for CO₂ hydrogenation to light olefins over ZrCdO _x /SAPO-18 bifunctional catalyst［J］.Chinese Journal of Inorganic Chemistry，2021，37（3）：448-456.
33	陈思宇，王集杰，李灿.ZnZrO _x /SAPO-18催化剂上CO₂加氢制低碳烯烃［J］.石油化工，2023，52（8）：1031-1038.
	CHEN Siyu， WANG Jijie， LI Can.Hydrogenation of CO₂ to light olefins on ZnZrO _x /SAPO-18 catalyst［J］.Petrochemical Technology，2023，52（8）：1031-1038.
34	SHI Y， GAO W， WANG G，et al.Direct conversion of CO₂ to ethylene by bifunctional ZnCr₂O₄-ZSM-22 catalyst［J］.Materials Today Chemistry，2023，32：101654.
35	DANG Shanshan， LI Shenggang， YANG Chengguang，et al.Selective transformation of CO₂ and H₂ into lower olefins over In₂O₃-ZnZrO _x /SAPO-34 bifunctional catalysts［J］.ChemSusChem，2019，12（15）：3582-3591.
36	PORTILLO A， PARRA O， EREÑA J，et al.Effect of water and methanol concentration in the feed on the deactivation of In₂O₃-ZrO₂/SAPO-34 catalyst in the conversion of CO₂/CO to olefins by hydrogenation［J］.Fuel，2023，346：128298.
37	PORTILLO A， PARRA O， AGUAYO A T，et al.Kinetic model for the direct conversion of CO₂/CO into light olefins over an In₂O₃-ZrO₂/SAPO-34 tandem catalyst［J］.ACS Sustainable Chemistry & Engineering，2024，12（4）：1616-1624.
38	ZHANG Xinbao， ZHANG Anfeng， JIANG Xiao，et al.Utilization of CO₂ for aromatics production over ZnO/ZrO₂-ZSM-5 tandem catalyst［J］.Journal of CO2 Utilization，2019，29：140-145.
39	TIAN Haifeng， JIAO Jiapeng， ZHA Fei，et al.Hydrogenation of CO₂ into aromatics over ZnZrO-Zn/HZSM-5 composite catalysts derived from ZIF-8［J］.Catalysis Science & Technology，2022，12（3）：799-811.
40	WANG Yang， TAN Li， TAN Minghui，et al.Rationally designing bifunctional catalysts as an efficient strategy to boost CO₂ hydrogenation producing value-added aromatics［J］.ACS Catalysis，2019，9（2）：895-901.
41	TIAN Haifeng， HE Huanhuan， JIAO Jiapeng，et al.Tandem catalysts composed of different morphology HZSM-5 and metal oxides for CO₂ hydrogenation to aromatics［J］.Fuel，2022，314：123119.
42	ZHOU Cheng， SHI Jiaqing， ZHOU Wei，et al.Highly active ZnO-ZrO₂ aerogels integrated with H-ZSM-5 for aromatics synthesis from carbon dioxide［J］.ACS Catalysis，2020，10（1）：302-310.
43	ZHANG Lijun， GAO Weizhe， WANG Fan，et al.Highly selective synthesis of light aromatics from CO₂ by chromium-doped ZrO₂ aerogels in tandem with HZSM-5@SiO₂ catalyst［J］.Applied Catalysis B：Environmental，2023，328：122535.
44	WANG Wenhang， HE Ruosong， WANG Yang，et al.Boosting methanol-mediated CO₂ hydrogenation into aromatics by synergistically tailoring oxygen vacancy and acid site properties of multifunctional catalyst［J］.Chemistry-A European Journal，2023，29（40）：2301135.
45	HE Yiming， MÜLLER F H， PALKOVITS R，et al.Tandem catalysis for CO₂ conversion to higher alcohols：A review［J］.Applied Catalysis B：Environment and Energy，2024，345：123663.
46	张广宇，赵健，孙峰，等.CO₂催化转化制碳酸丙烯酯研究进展：催化剂设计、性能与反应机理［J］.化工进展，2022，41（S1）：177-189.
	ZHANG Guangyu， ZHAO Jian， SUN Feng，et al.Recent advances on catalytic conversion of CO₂ into propylene carbonate：Catalyst design，performance and reaction mechanism［J］.Chemical Industry and Engineering Progress，2022，41（S1）：177-189.
47	朱有财，丁欣欣，孙莉，等.CO₂/C₂H₄耦合制备丙烯酸及其衍生物的研究进展［J］.有机化学，2022，42（4）：965-977.
	ZHU Youcai， DING Xinxin， SUN Li，et al.Advances in the production of acrylic acid and its derivatives by CO₂/C₂H₄ coupling［J］.Chinese Journal of Organic Chemistry，2022，42（4）：965-977.
48	金湘元，张礼兵，孙晓甫，等.单原子催化剂在电催化还原CO₂领域的应用［J］.高等学校化学学报，2022，43（5）：5-24.
	JIN Xiangyuan， ZHANG Libing， SUN Xiaofu，et al.Electrocatalytic CO₂ reduction over single-atom catalysts［J］.Chemical Journal of Chinese Universities，2022，43（5）：5-24.
49	ZHANG Fuyong， ZHOU Wei， XIONG Xuewei，et al.Selective hydrogenation of CO₂ to ethanol over sodium-modified rhodium nanoparticles embedded in zeolite silicalite-1［J］.The Journal of Physical Chemistry C，2021，125（44）：24429-24439.
50	WANG Guishuo， LUO Ran， YANG Chengsheng，et al.Active sites in CO₂ hydrogenation over confined VO _x -Rh catalysts［J］.Science China Chemistry，2019，62（12）：1710-1719.
51	DING Liping， SHI Taotao， GU Jing，et al.CO₂ hydrogenation to ethanol over Cu@Na-beta［J］.Chem，2020，6（10）：2673-2689.
52	FAN Linhui， WANG Yuezhao， ZHAI Xiaohan，et al.Production of oxygenates from CH₄/CO₂ plasma reaction assisted by Ni/HZSM-5 catalyst［J］.Plasma Chemistry and Plasma Processing，2023，43（6）：1979-1998.
53	XIE Zhenhua， XU Yuanguo， XIE Meng，et al.Reactions of CO₂ and ethane enable CO bond insertion for production of C3 oxygenates［J］.Nature Communications，2020，11：1887.
54	XIE Zhenhua， GUO Haoyue， HUANG Erwei，et al.Catalytic tandem CO₂-ethane reactions and hydroformylation for C3 oxygenate production［J］.ACS Catalysis，2022，12（14）：8279-8290.
55	BISWAS A N， XIE Zhenhua， XIA Rong，et al.Tandem electrocatalytic-thermocatalytic reaction scheme for CO₂ conversion to C₃ oxygenates［J］.ACS Energy Letters，2022，7（9）：2904-2910.
56	BISWAS A N， WINTER L R， LOENDERS B，et al.Oxygenate production from plasma-activated reaction of CO₂ and ethane［J］.ACS Energy Letters，2022，7（1）：236-241.

催化剂	CO₂转化率/%	选择性/%						CO选择性/%
催化剂	CO₂转化率/%	CH₄	C₂⁼~C₄⁼	C₂⁰~C₄⁰	C₅⁺	CH₃OH	DME	CO选择性/%
MgAl₂O₄	0.8	12.0	13.0	16.0	9.0	48	2	97
MgGa₂O₄	7.8	0.9	0.1	0.0	0.0	65	34	87
ZnAl₂O₄	12.0	0.6	0.1	0.1	0.0	84	15	69
ZnGa₂O₄	9.8	0.2	0.0	0.0	0.0	98	0	68
MgAl₂O₄/SAPO-34	1.1	9.0	65.0	18.0	8.0	0	0	96
MgGa₂O₄/SAPO-34	8.7	1.9	65.0	25.0	8.3	0	0	82
ZnAl₂O₄/SAPO-34	15.0	0.7	87.0	10.0	2.2	0	0	49
ZnGa₂O₄/SAPO-34	13.0	1.0	86.0	11.0	2.0	0	0	46

催化剂	反应温度/℃	反应压强/MPa	反应空速/（mL· g^-1·h^-1）	CO₂转化率/%	C₂⁼~C₄⁼选择性/%	反应时间/h
Zn_0.5Ce_0.2Zr_1.8O₄/H-RUB-13^［31］	350	1	4 800	10.7	83.4	30
In₂O₃-ZnZrO _x /SAPO-34^［35］	380	3	9 000	17	85	48
In₂O₃/YSZ/SAPO-34^［28］	420	3	4 000	30.3	10.8	45
ZnZrO _x / SAPO-34^［24］	375	2	3 000	23.9	72.4
Zr₈Cd₁O _x /SAPO-18^［32］	370	2.5	5 000	17.8	85.6	50
ZnZrO _x / SAPO-18^［33］	360	2	4 500	8.6	90.6	120
GaZrO _x /SAPO-34^［27］	390	3	3 000	26.7	88.8	100
ZnAl₂O₄/SAPO-34^［26］	370	3	5 400	15	87
ZnCr₂O₄-ZSM-22^［34］	360	5	1 200	21.9	24（乙烯选择性）	60

催化剂	CO₂ 转化率/%	CO 选择性/%	加氢产物的选择性/%
催化剂	CO₂ 转化率/%	CO 选择性/%	C_1~2	C₃	C₄	C₅₊	B^a	T^b	X^c	C₉₊	BTX	Aro^d
ZnZr₇O（500）-片状Z5	17.2	31.4	14.1	18.1	14.6	1.3	0.7	4.9	41.1	5.1	46.7	51.8
ZnZr₇O（500）-空心Z5	14.1	40.3	18.3	17.8	29.1	2.8	0.5	2.5	23.3	5.7	26.3	32.0
ZnZr₇O（500）-球形Z5	10.8	61.6	15.4	13.2	26.6	3.6	0.7	2.4	17.0	21.0	20.1	41.1
ZnZr₇O（500）-链状Z5	13.5	60.5	18.0	14.8	25.7	7.2	0.7	2.0	17.2	14.4	19.9	34.3
In₂O₃-片状Z5	24.9	43.8	30.6	16.2	15.2	6.8	0.6	1.8	14.8	14.0	17.2	31.2
Cu-ZnO-Al₂O₃-片状Z5	34.5	84.3	43.2	10.7	30.1	4.0	0.1	0.3	0.4	6.2	0.8	7.0

[1]	YAN Xin, LIU Hailu, LIU Baolin, LIU Yi, LIU Yanyang. Research on key technologies and mechanisms of green nano calcium carbonate production [J]. Inorganic Chemicals Industry, 2025, 57(1): 71-76.
[2]	ZHAN Sijin, LIU Shike, LIU Fei, YAO Mengqin, CAO Jianxin. Study on preparation and catalytic performance of ZnO-CeO₂ [J]. Inorganic Chemicals Industry, 2024, 56(3): 137-143.
[3]	REN Qixia, YANG Kun, LIU Fei, YAO Mengqin, CAO Jianxin. Effect of promoter on physicochemical properties and catalytic performance of ZnO/ZrO₂ [J]. Inorganic Chemicals Industry, 2024, 56(3): 144-154.
[4]	YANG Kun, REN Qixia, DONG Yonggang, LIU Fei, YAO Mengqin, CAO Jianxin. Effect of calcination temperature on catalytic performance of ZnGaZrO _x /SAPO-34 [J]. Inorganic Chemicals Industry, 2024, 56(2): 136-145.
[5]	LI Yang, LOU Feijian, SUI Xin, LI Keyan, LIU Fei, GUO Xinwen. Preparation of amine-functionalized fumed SiO₂ materials and their performance for CO₂ adsorption [J]. Inorganic Chemicals Industry, 2024, 56(2): 38-43.
[6]	HOU Zhanggui, WU Chongchong, ZHANG Siran. Research progress of CO₂ conversion via Reverse Water-Gas Shift reaction [J]. Inorganic Chemicals Industry, 2024, 56(11): 105-115.
[7]	CHEN Xu, YANG Gang, LI Haitao. Study on preparation of multistage pore nano-SAPO-34 molecular sieves and its methanol to olefin performance [J]. Inorganic Chemicals Industry, 2024, 56(1): 134-140.
[8]	CHANG Chengbing, LIU Shengyu, ZHANG Lei, YANG Zhichao, GUO Jianying, LI Bao. Experimental study on carbon dioxide sequestration by wet carbonation of calcium silicate minerals [J]. Inorganic Chemicals Industry, 2023, 55(9): 57-65.
[9]	ZHAO Yan, HAO Xuewei, SHI Hainan, LI Jiahui, LI Keyan, GUO Xinwen. Study on photocatalytic CO₂reduction performance of Cu-doped TiO₂/PCN heterojunction [J]. Inorganic Chemicals Industry, 2023, 55(8): 21-27.
[10]	SONG Zhijia, WANG Suisui, KUANG Qin. Hollow Cu-doped TiO₂ for enhancing photocatalytic CO₂ reduction performance [J]. Inorganic Chemicals Industry, 2023, 55(8): 45-50.
[11]	GUI Changqing, WANG Yajing, LING Changjian, WANG Huaiyou, TANG Zhongfeng. Research progress of preparation and modification of MgO-based CO₂ adsorbents [J]. Inorganic Chemicals Industry, 2023, 55(8): 77-83.
[12]	WANG Jianfang, YANG Heping, LI Kaibin, CONG Shiqiang, ZHANG Bojie, GUO Shan. Study on preparation of C₃N₄/MnCo₂S₄ composites and their capacitive properties [J]. Inorganic Chemicals Industry, 2023, 55(7): 70-74.
[13]	LI Songhong,ZHOU Songhua,ZHAO Aiming,DONG Wenyan,JIANG Chunyan,CAO Yang,AO Xianquan. Study on catalytic gasification reaction of distillers′grains under H₂O/CO₂ atmosphere [J]. Inorganic Chemicals Industry, 2023, 55(2): 132-140.
[14]	YANG Tinglong,WANG Fuzhong,LIU Fei. Study on sulfur poisoning of zirconium-based bimetallic oxides catalyst [J]. Inorganic Chemicals Industry, 2023, 55(1): 151-158.
[15]	WENG Dingsong,WANG Zhenghao,CHEN Liang,YIN Rentao,XIAO Haibing,LIU Weizao,LIANG Bin,LUO Dongmei. Serpentine coupled with copperas to enrich magnesium solution for simultaneous CO₂ mineralization and nickel recovery [J]. Inorganic Chemicals Industry, 2023, 55(1): 93-99.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Research progress on catalysts for relay-catalysis of CO₂ to prepare high value-added chemicals

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 14

References 56

Related Articles 15

Metrics

Comments

Recommended 0

Research progress on catalysts for relay-catalysis of CO2 to prepare high value-added chemicals