竹茹丝炭负载钌催化剂光催化氨硼烷水解产氢研究

doi:10.19964/j.issn.1006-4990.2023-0039

Abstract

Abstract:

In order to prepare efficient and low-cost catalysts for hydrogen production from ammonia borane，bamboo shavings carbon materials（BSC） derived from bamboo shavings were prepared by direct calcination.The Ru/BSC layered catalyst was finally prepared by impregnation reduction using BSC as carrier to support the Ru metal on the carrier surface.The catalyst structure composition and morphology were analyzed by various characterization methods and the effects of light and non-light，metal loading，catalyst dosage，ammonia borane concentration and temperature on hydrogen production from ammonia borane hydrolysis were investigated.The results showed that there was a metal-support interaction between Ru and BSC.The 1.0%Ru/BSC catalyst catalyzed ammonia borane hydrolysis dehydrogenation under visible light irradiation was significantly better than dark conditions.The rate of hydrogen production was directly proportional to the concentration of Ru/BSC，and the hydrogen production rate of ammonia borane hydrolysis catalyzed by Ru/BSC was independent of the concentration of ammonia borane.The TOF value of the dehydrogenation reaction of ammonia borane catalyzed by 1.0%Ru/BSC at 298 K was 446.4 min^-1 and the activation energy was 64.0 kJ/mol.Therefore，this study provided a new idea for the preparation of efficient and low-cost catalysts.

Key words: ruthenium catalyst, bamboo shavings carbon, photocatalysis, ammonia borane, hydrolytic dehydrogenation

CLC Number:

TQ138.21

QIU Xiaokui, ZHANG Ruofan, WANG Xiaoyan, WANG Hailong, ZHANG Qixue, WAN Chao, XU Lixin. Research on bamboo shavings carbon supported ruthenium catalysts for hydrogen generation from photocatalytic hydrolysis of ammonia borane[J]. Inorganic Chemicals Industry, 2023, 55(10): 153-158.

Figures/Tables 8

Fig.1

Fig.2

Fig.3

Fig.4

Fig.5

Fig.6

Fig.7

Fig.8

References 19

1	孙海杰，刘欣改，陈志浩，等.二氧化硅负载钌催化剂催化氨硼烷水解产氢研究［J］.无机盐工业，2020，52（5）：81-85.
	SUN Haijie， LIU Xingai， CHEN Zhihao，et al.Research on Ru/SiO₂ catalysts for hydrogen generation from catalytic hydrolysis of ammonia borane［J］.Inorganic Chemicals Industry，2020，52（5）：81-85.
2	任壮禾，张欣，高明霞，等.Ti基催化剂改性的NaAlH₄储氢材料研究进展［J］.稀有金属，2021，45（5）：569-582.
	REN Zhuanghe， ZHANG Xin， GAO Mingxia，et al.Research progress in Ti-based catalysts-modified NaAlH₄ hydrogen storage materials［J］.Chinese Journal of Rare Metals，2021，45（5）：569-582.
3	孙海杰，梅洋洋，陈志浩，等.铁、钴、镍、铜和锌催化剂催化氨硼烷水解产氢性能研究［J］.无机盐工业，2021，53（1）：102-106.
	SUN Haijie， MEI Yangyang， CHEN Zhihao，et al.Performance of Fe，Co，Ni，Cu and Zn catalysts for hydrogen generation from catalytic hydrolysis of ammonia borane［J］.Inorganic Chemicals Industry，2021，53（1）：102-106.
4	陈凌霞，王琪，孙海杰，等.膨润土负载钌催化剂制备及其催化氨硼烷水解产氢研究［J］.无机盐工业，2021，53（6）：199-204.
	CHEN Lingxia， WANG Qi， SUN Haijie，et al.Study on preparation of bentonite supported Ru catalysts and their performance for hydrogen generation from catalytic hydrolysis of ammonia borane［J］.Inorganic Chemicals Industry，2021，53（6）：199-204.
5	韩利，李琦，冷国云，等.氢能储存技术最新进展［J］.化工进展，2022，41（S1）：108-117.
	HAN Li， LI Qi， LENG Guoyun，et al.Latest research progress of hydrogen energy storage technology［J］.Chemical Industry and Engineering Progress，2022，41（S1）：108-117.
6	PENG Yumei， HE Yating， WANG Yi，et al.Sustainable one-pot construction of oxygen-rich nitrogen-doped carbon nanosheets stabilized ultrafine Rh nanoparticles for efficient ammonia borane hydrolysis［J］.Journal of Colloid and Interface Science，2021，594：131-140.
7	DEMIRCI U B.Ammonia borane，a material with exceptional properties for chemical hydrogen storage［J］.International Journal of Hydrogen Energy，2017，42（15）：9978-10013.
8	SUN Daohua， MAZUMDER V， METIN Ö，et al.Catalytic hydrolysis of ammonia borane via cobalt palladium nanoparticles［J］.ACS Nano，2011，5（8）：6458-6464.
9	FU Ling， CAI Li.Ru nanoparticles loaded on tannin immobilized collagen fibers for catalytic hydrolysis of ammonia borane［J］.International Journal of Hydrogen Energy，2021，46（18）：10749-10762.
10	FU Wenzhao， HAN Chen， LI Dali，et al.Polyoxometalates-engineered hydrogen generation rate and durability of Pt/CNT catalysts from ammonia borane［J］.Journal of Energy Chemistry，2020，41：142-148.
11	ZHANG Jun， DONG Yana， LIU Quanxing，et al.Hierarchically alloyed Pd-Cu microarchitecture with tunable shapes：Morphological engineering，and catalysis for hydrogen evolution reaction of ammonia borane［J］.International Journal of Hydrogen Energy，2019，44（57）：30226-30236.
12	SHEN Junfeng， YANG Lan， HU Kai，et al.Rh nanoparticles supported on graphene as efficient catalyst for hydrolytic dehydrogenation of amine boranes for chemical hydrogen storage［J］.International Journal of Hydrogen Energy，2015，40（2）：1062-1070.
13	DU Cheng， AO Qiang， CAO Nan，et al.Facile synthesis of monodisperse ruthenium nanoparticles supported on graphene for hydrogen generation from hydrolysis of ammonia borane［J］.International Journal of Hydrogen Energy，2015，40（18）：6180-6187.
14	宁汇，王路海，何盛宝，等.石油沥青基碳材料的电化学应用研究进展［J］.石油炼制与化工，2021，52（10）：38-45.
	NING Hui， WANG Luhai， HE Shengbao，et al.Research process of petroleum pitch-based carbon materials in electrochemical applications［J］.Petroleum Processing and Petrochemicals，2021，52（10）：38-45.
15	NAVLANI-GARCÍA M， MORI K， NOZAKI A，et al.Highly efficient Ru/carbon catalysts prepared by pyrolysis of supported Ru complex towards the hydrogen production from ammonia bora-ne［J］.Applied Catalysis A：General，2016，527：45-52.
16	CHENG Hui， LIU Juan， SUN Yunxiu，et al.A fungus-derived biomass porous carbon-MnO₂ nanocomposite-modified electrode for the voltammetric determination of rutin［J］.RSC Advances，2020，10（69）：42340-42348.
17	董会超，张勇，王力臻，等.微波加热氢氧化钾活化制备多孔结构竹炭的研究［J］.无机盐工业，2010，42（12）：32-34.
	DONG Huichao， ZHANG Yong， WANG Lizhen，et al.Study on preparation of porous bamboo charcoal with KOH activation and microwave heating［J］.Inorganic Chemicals Industry，2010，42（12）：32-34.
18	ZHAO Bing， CHEN Wenlin， TAN Yifeng，et al.Preparation of M/Ce_1- _x Ti _x O₂（M=Pt，Rh，Ru） from sol-gel method and their catalytic oxidation activity for diesel soot［J］.Journal of Rare Earths，2022，40（12）：1849-1859.
19	崔伯洋.钌基催化剂的制备及其催化氨硼烷水解性能研究［D］.桂林：桂林电子科技大学，2022.
	CUI Boyang.Preparation of ruthenium-based catalyst and its catalytic performance toward ammonia-borane hydrolysis［D］.Guilin：Guilin University of Electronic Technology，2022.

[1]	SHI Wangfang, ZHANG Yongsheng. Study on NO _x degradation performance of concrete-based non-metallic boron doped nitrogen-rich carbon nitride [J]. Inorganic Chemicals Industry, 2025, 57(3): 116-123.
[2]	LI Zihan, ZHANG Jiaqi, LI Shizhuo, LI Xinyu, LIU Shaozhuo, WANG Yihao, HAO Yucui, LIU Jian, LI Yanhua. Study on synthesis and catalytic mechanism of CdS/g-C₃N₄composite photocatalyst [J]. Inorganic Chemicals Industry, 2025, 57(3): 124-132.
[3]	SUN Qinghao, LI Keyan, GUO Xinwen. Study on photocatalytic benzyl alcohol oxidation coupled with hydrogen production over Pd/ZnIn₂S₄ nanosheets [J]. Inorganic Chemicals Industry, 2025, 57(1): 113-119.
[4]	LIU Guangming. Study on photocatalytic and mechanical properties of C₃N₅/NH₂-MIL-125（Ti） modified concrete mortar [J]. Inorganic Chemicals Industry, 2025, 57(1): 120-128.
[5]	ZHANG Guoqiang, RONG Xilin, XIAO Zhenfang, XUE Ziran, CHENG Hao, FENG Jun, LIU Quan, LU Yao, HUANG Wenyi. Study on preparation and photocatalytic properties of bagasse carbon aerogels loaded with zinc oxide nanoparticles [J]. Inorganic Chemicals Industry, 2024, 56(8): 131-138.
[6]	WANG Yawen, WANG Fangfang, GENG Siyu, JU Jia, CHEN Lei, CHEN Changdong. Study on preparation and photocatalytic performance of SrTiO₃-SrWO₄ [J]. Inorganic Chemicals Industry, 2024, 56(7): 143-149.
[7]	LIU Min, HUANG Xiu, ZHANG Liyuan. Research progress of S-type heterojunction photocatalysts [J]. Inorganic Chemicals Industry, 2024, 56(7): 18-27.
[8]	LI Jiangpeng, ZHANG Huibin. Synergistic degradation of methylene blue by photo-Fenton and photocatalytic with 3D porous LaFeO₃/CeO₂/SrTiO₃ [J]. Inorganic Chemicals Industry, 2024, 56(5): 141-148.
[9]	TANG Bei. Preparation of ZnO/g-C₃N₄ heterojunction photocatalytic material and its degradation of pyridine [J]. Inorganic Chemicals Industry, 2024, 56(4): 133-142.
[10]	HUANG Jianan, LU Xiaoyu, WANG Mitang. Effect of Ba-La co-doping on degradation of methylene blue dye by TaON [J]. Inorganic Chemicals Industry, 2024, 56(2): 146-151.
[11]	ZUO Guangling, WANG Minghui, PENG Yunying, DU Jia, YE Hongyong. Study on hnoneycomb-like LaVO₄/Bi₂O₃ heterojunction for photocatalytic degradation of tetracycline hydrochloride [J]. Inorganic Chemicals Industry, 2024, 56(11): 158-164.
[12]	CUI Xiangdong, LIU Sile. Study on photoelectric performance analysis of g-C₃N₅ nanorods and removal of Cr（Ⅵ） and methylene blue [J]. Inorganic Chemicals Industry, 2024, 56(10): 159-168.
[13]	YAN Yu, ZHOU Wenyuan, YANG Yunfei, WU Junshu, WANG Jinshu, SUN Lingmin. Study on surface regulation of sodium ferric silicate photocatalyst and its enhanced Cr（Ⅵ） photoreduction properties [J]. Inorganic Chemicals Industry, 2024, 56(10): 141-150.
[14]	MA Yihong, CHEN Xingtao, TANG Lei. Treatment of printing wastewater by chemical coagulation-TiO₂/g-C₃N₅ photocatalytic degradation [J]. Inorganic Chemicals Industry, 2024, 56(10): 151-158.
[15]	YANG Bo, LIANG Zhiyan, LIU Wenyuan, CAO Jiazhen, LIU Xinyue, XING Mingyang. Research progress of application of molybdenum-based catalytic materials for water pollution control [J]. Inorganic Chemicals Industry, 2023, 55(8): 1-12.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Research on bamboo shavings carbon supported ruthenium catalysts for hydrogen generation from photocatalytic hydrolysis of ammonia borane

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 8

References 19

Related Articles 15

Metrics

Comments

Recommended 0