g-C3N5纳米棒光电性能分析及对Cr（Ⅵ）和亚甲基蓝去除的研究

doi:10.19964/j.issn.1006-4990.2024-0011

Abstract

Abstract:

In order to achieve green and efficient degradation of Cr（Ⅵ） and dye wastewater，one⁃dimensional nitrogen⁃rich graphite phase carbon nitride nanorods（1D g-C₃N₅） with excellent photocatalytic activity were prepared by KBr-induced method.The crystal structure，group，morphology，photochemical properties and electrochemical properties of 1D g-C₃N₅ were characterized by XRD，FT-IR，TEM，UV-vis DRS，PL，TPC and EIS.The photocatalytic removal of Cr（Ⅵ） and degradation of methylene blue（MB） under visible light were evaluated.The results showed that the specific surface area of the material was increased by the KBr-induced morphology control method，the spectral absorption range was broadened，the visible light absorption and conversion ability was improved，and the separation of photogenerated carriers was effectively promoted，showing a lower surface/interface resistance value.The photocatalytic activity of 1D g-C₃N₅ was significantly improved compared with bulk g-C₃N₅.After visible light irradiation for 60 min，the removal rate of Cr（Ⅵ） and the degradation rate of MB by 1D g-C₃N₅ reached 97.6% and 98.8%，respectively.Moreover，1D g-C₃N₅ still had good stability after 5 cycles.The results of the active groups showed that the main active groups of the photocatalytic system were ·O₂^- and h⁺，the removal of Cr（Ⅵ） benefited from the effect of e^-.The photocatalytic mechanism of 1D g-C₃N₅ photocatalytic reduction of Cr（Ⅵ） and removal of MB was proposed by band structure calculation.

Key words: KBr induction, 1D g-C₃N₅, photocatalysis, Cr（Ⅵ）, methylene blue

CLC Number:

TQ136.11

CUI Xiangdong, LIU Sile. Study on photoelectric performance analysis of g-C₃N₅ nanorods and removal of Cr（Ⅵ） and methylene blue[J]. Inorganic Chemicals Industry, 2024, 56(10): 159-168.

Figures/Tables 13

Fig.1

Fig.2

Fig.3

Fig.4

Fig.5

Fig.6

Fig.7

Fig.8

Fig.9

Fig.10

Fig.11

Fig.12

Fig.13

References 29

1	刘思乐，卜义夫，洪雯雯，等.ZnO/g-C₃N₄复合光催化剂的制备及对罗丹明B的降解［J］.印染，2023，49（3）：53-57.
	LIU Sile， BU Yifu， HONG Wenwen，et al.Preparation of ZnO/g-C₃N₄ composite photocatalyst and its degradation of RhodamineB［J］.China Dyeing & Finishing，2023，49（3）：53-57.
2	余家国，张留洋.光催化材料［J］.硅酸盐学报，2023，51（1）：1-3.
	YU Jiaguo， ZHANG Liuyang.Photocatalytic materials［J］.Journal of the Chinese Ceramic Society，2023，51（1）：1-3.
3	艾兵，何海南，邓璇，等.Ni-P@g-C₃N₄复合材料的合成与可见光催化性能［J］.化学研究与应用，2023，35（7）：1534-1540.
	AI Bing， HE Hainan， DENG Xuan，et al.Preparation and visible⁃light photocatalytic properties of Ni-P@g-C₃N₄ composites［J］.Chemical Research and Application，2023，35（7）：1534-1540.
4	汪益林，高博，张留科，等.g-C₃N₄/介孔TiO₂的制备及可见光下光催化还原Cr（Ⅵ）试验研究［J］.湿法冶金，2023，42（3）：282- 290.
	WANG Yilin， GAO Bo， ZHANG Liuke，et al.Preparation of g-C₃N₄/mesoporous TiO₂ and visible⁃light⁃driven photocatalytic reduction of Cr（Ⅵ）［J］.Hydrometallurgy of China，2023，42（3）：282-290.
5	苏荣军，姜灏，魏澜，等.g-C₃N₄基光催化剂的改性制备及在废水处理中的应用［J］.中国给水排水，2023，39（10）：55-61.
	SU Rongjun， JIANG Hao， WEI Lan，et al.Preparation and modification of g-C₃N₄-based photocatalyst and its application in wastewater treatment［J］.China Water & Wastewater，2023，39（10）：55-61.
6	LUO Suyue， LI Shaopeng， ZHANG Shuo，et al.Visible⁃light⁃driven Z-scheme protonated g-C₃N₄/wood flour biochar/BiVO₄ photocatalyst with biochar as charge⁃transfer channel for enhanced RhB degradation and Cr（Ⅵ） reduction［J］.Science of the Total Environment，2022，806：150662.
7	LAKSHMI PRABAVATHI S， SARAVANAKUMAR K， MAMBA G，et al.1D/2D MnWO₄ nanorods anchored on g-C₃N₄ nanosheets for enhanced photocatalytic degradation ofloxacin under visible light irradiation［J］.Colloids and Surfaces A：Physicochemical and Engineering Aspects，2019，581：123845.
8	李静霄，解玉龙.g-C₃N₄纳米片的改性及光催化降解应用［J］.印染，2023，49（8）：82-87.
	LI Jingxiao， XIE Yulong.Modification and photocatalytic degradation application of g-C₃N₄ nanosheets［J］.China Dyeing & Finishing，2023，49（8）：82-87.
9	谭栋玉，黄斐，张武.g-C₃N₄的微观调控在环境治理中的应用［J］.化工新型材料，2023，51（5）：270-276.
	TAN Dongyu， HUANG Fei， ZHANG Wu.Application of micro⁃control of g-C₃N₄ in environmental governance［J］.New Chemical Materials，2023，51（5）：270-276.
10	WUDIL Y S， AHMAD U F， GONDAL M A，et al.Tuning of graphitic carbon nitride（g-C₃N₄） for photocatalysis：A critical review［J］.Arabian Journal of Chemistry，2023，16（3）：104542.
11	MEENA P L， POSWAL K， SURELA A K，et al.Synthesis of graphitic carbon nitride/zinc oxide （g-C₃N₄/ZnO） hybrid nanostructures and investigation of the effect of ZnO on the photodegradation activity of g-C₃N₄ against the brilliant cresyl blue（BCB） dye under visible light irradiation［J］.Advanced Composites and Hybrid Materials，2022，6（1）：16.
12	RAJENDRAN S， CHELLAPANDI T， USHAVIPINACHANDRAN V，et al.Sustainable 2D Bi₂WO₆/g-C₃N₅ heterostructure as visible light⁃triggered abatement of colorless endocrine disruptors in wastewater［J］.Applied Surface Science，2022，577：151809.
13	VADIVEL S， FUJII M， RAJENDRAN S.Novel S-scheme 2D/2D Bi₄O₅Br₂ nanoplatelets/g-C₃N₅ heterojunctions with enhanced photocatalytic activity towards organic pollutants removal［J］.Environmental Research，2022，213：113736.
14	ZHANG Hongda， ZHAO Yunzhe， XU Guanghui，et al.Photocatalytic activation of sodium percarbonate by C₃N₅/C₂N₃ homojunction for rapid water purification：Efficient electron transfer of built⁃in electric field［J］.Chemical Engineering Journal，2024，491：151885.
15	TIAN Chuan， LIU Sile， SHAO Mengsha，et al.Preparation of g-C₃N₅ composites for butyl xanthate photocatalytic degradation［J］.Inorganic Chemistry Communications，2024，159：111726.
16	LIAO Wenning， YANG Zhiquan， WANG Ying，et al.Novel Z-scheme Nb₂O₅/C₃N₅ photocatalyst for boosted degradation of tetracycline antibiotics by visible light⁃assisted activation of persulfate system［J］.Chemical Engineering Journal，2023，478：147346.
17	THARUMAN S， BALAKUMAR V， VINODHINI J，et al.Visible light driven photocatalytic performance of 3D TiO₂/g-C₃N₅ nanocomposite via Z-scheme charge transfer promotion for water purification［J］.Journal of Molecular Liquids，2023，371：121101.
18	KUMAR P， VAHIDZADEH E， THAKUR U K，et al.C₃N₅：A low bandgap semiconductor containing an azo⁃linked carbon nitride framework for photocatalytic，photovoltaic and adsorbent applications［J］.Journal of the American Chemical Society，2019，141（13）：5415-5436.
19	吴一帆，蔡彪，王顺，等.光催化剂V₂O₅/CdS/g-C₃N₄的制备、表征及降解苄基苯基醚性能［J］.应用化工，2023，52（4）：1109-1114，1120.
	WU Yifan， CAI Biao， WANG Shun，et al.Preparation，characterization and degradation of benzyl phenyl ether of photocatalyst V₂O₅/CdS/g-C₃N₄ ［J］.Applied Chemical Industry，2023，52（4）：1109-1114，1120.
20	粟阳藩，吴林珍，李依林，等.Ⅱ型TiO₂/g-C₃N₄异质结的构筑促进高效光催化U（Ⅵ）还原［J］.无机化学学报，2023，39（4）：689-698.
	SU Yangfan， WU Linzhen， LI Yilin，et al.Construction of type⁃Ⅱ TiO₂/g-C₃N₄ heterojunction promoting efficient photocatalytic reduction of U（Ⅵ）［J］.Chinese Journal of Inorganic Chemistry，2023，39（4）：689-698.
21	VATANPOUR V， MOUSAVI KHADEM S S， DEHQAN A，et al.Application of g-C₃N₄/ZnO nanocomposites for fabrication of an⁃ti⁃fouling polymer membranes with dye and protein rejection superiority［J］.Journal of Membrane Science，2022，660：120893.
22	CAI Zhengqing， HUANG Yining， JI Haodong，et al.Type-Ⅱ surface heterojunction of bismuth⁃rich Bi₄O₅Br₂ on nitrogen⁃rich g-C₃N₅ nanosheets for efficient photocatalytic degradation of antibiotics［J］.Separation and Purification Technology，2022，280：119772.
23	王彦欣，刘亚靖，陶然，等.K/Cl掺杂g-C₃N₄的制备及其光催化性能研究［J］.分子催化，2022，36（6）：561-570.
	WANG Yanxin， LIU Yajing， TAO Ran，et al.Preparation and photocatalytic properties of K/Cl doped g-C₃N₄ ［J］.Journal of Molecular Catalysis （China），2022，36（6）：561-570.
24	谭凤训，陈永凯，王榕，等.g-C₃N₄/PDS光催化降解阿特拉津的效能及机理研究［J］.中国给水排水，2023，39（1）：91-98.
	TAN Fengxun， CHEN Yongkai， WANG Rong，et al.Performance and mechanism of g-C₃N₄/PDS for photocatalytic degradation of atrazine［J］.China Water & Wastewater，2023，39（1）：91-98.
25	GHATTAVI S， NEZAMZADEH-EJHIEH A.A double-Z-scheme ZnO/AgI/WO₃ photocatalyst with high visible light activity：Experimental design and mechanism pathway in the degradation of methylene blue［J］.Journal of Molecular Liquids，2021，322：114563.
26	伍林，胡明蕾，王丽萍，等.TiHAP@g-C₃N₄异质结的制备及光催化降解甲基橙［J］.无机材料学报，2023，38（5）：503-512.
	WU Lin， HU Minglei， WANG Liping，et al.Preparation of TiHAP@g-C₃N₄ heterojunction and photocatalytic degradation of methyl orange［J］.Journal of Inorganic Materials，2023，38（5）：503-512.
27	熊翠蓉，李玮宁，胡浩，等.Z型异质结Au/CoWO₄/g-C₃N₄的制备及其光催化降解性能［J］.无机化学学报，2022，38（11）：2222-2230.
	XIONG Cuirong， LI Weining， HU Hao，et al.Preparation of Au/CoWO₄/g-C₃N₄ Z-scheme heterojunction photocatalyst with efficient photodegradation activity［J］.Chinese Journal of Inorganic Chemistry，2022，38（11）：2222-2230.
28	马占强，张凯悦，郭葳，等.g-C₃N₅纳米片光催化还原Cr（Ⅵ）和抗菌性能研究［J］.化工新型材料，2023，51（6）：191-198.
	MA Zhanqiang， ZHANG Kaiyue， GUO Wei，et al.Study on photocatalytic reduction of Cr（Ⅵ）and antibacterial activities of g-C₃N₅ nanosheets［J］.New Chemical Materials，2023，51（6）：191-198.
29	兰蓥华，陈艳梅，马瑞霄，等.铈钛氧化物-凹凸棒土的制备及其光催化性能［J］.无机盐工业，2023，55（4）：133-140.
	LAN Yinghua， CHEN Yanmei， MA Ruixiao，et al.Preparation and photocatalytic performance of Ce-Ti oxide⁃attapulgite composites［J］.Inorganic Chemicals Industry，2023，55（4）：133-140.

[1]	SHI Wangfang, ZHANG Yongsheng. Study on NO _x degradation performance of concrete-based non-metallic boron doped nitrogen-rich carbon nitride [J]. Inorganic Chemicals Industry, 2025, 57(3): 116-123.
[2]	LI Zihan, ZHANG Jiaqi, LI Shizhuo, LI Xinyu, LIU Shaozhuo, WANG Yihao, HAO Yucui, LIU Jian, LI Yanhua. Study on synthesis and catalytic mechanism of CdS/g-C₃N₄composite photocatalyst [J]. Inorganic Chemicals Industry, 2025, 57(3): 124-132.
[3]	SHEN Xiaoqian, ZHOU Fei, LIU Wanchen, XU Lu, WU Junshu. Study on synthesis of FeS modified calcium silicate hydrate composites and their total Cr removal performance [J]. Inorganic Chemicals Industry, 2025, 57(2): 57-67.
[4]	SUN Qinghao, LI Keyan, GUO Xinwen. Study on photocatalytic benzyl alcohol oxidation coupled with hydrogen production over Pd/ZnIn₂S₄ nanosheets [J]. Inorganic Chemicals Industry, 2025, 57(1): 113-119.
[5]	LIU Guangming. Study on photocatalytic and mechanical properties of C₃N₅/NH₂-MIL-125（Ti） modified concrete mortar [J]. Inorganic Chemicals Industry, 2025, 57(1): 120-128.
[6]	ZHANG Feigang, LIU Zhongli. Study on application of CuO/g-C₃N₄ composites in organic dye degradation and supercapacitors [J]. Inorganic Chemicals Industry, 2025, 57(1): 129-136.
[7]	WEN Huizi, XI Luyao, HE Shuyu, TAN Shanyi, ZHANG Liwen, CHEN Shaohua, DU Yaguang. Research on Na₂CO₃ enhanced food additive wastewater hydrothermal wet reduction and detoxification of chromite ore processing residue [J]. Inorganic Chemicals Industry, 2025, 57(1): 83-89.
[8]	WANG Ping, XU Rongsheng, SUN Dong, SHI Xiaohong, XU Wei, LI Mei. Study on preparation of nitrogen-doped biochar and its adsorption properties for methylene blue [J]. Inorganic Chemicals Industry, 2024, 56(9): 117-127.
[9]	ZHANG Guoqiang, RONG Xilin, XIAO Zhenfang, XUE Ziran, CHENG Hao, FENG Jun, LIU Quan, LU Yao, HUANG Wenyi. Study on preparation and photocatalytic properties of bagasse carbon aerogels loaded with zinc oxide nanoparticles [J]. Inorganic Chemicals Industry, 2024, 56(8): 131-138.
[10]	ZHANG Bangcheng, WANG Li. Preparation and adsorption properties of waste polyester⁃based activated carbon activated by ZnCl₂ [J]. Inorganic Chemicals Industry, 2024, 56(7): 126-134.
[11]	WANG Yawen, WANG Fangfang, GENG Siyu, JU Jia, CHEN Lei, CHEN Changdong. Study on preparation and photocatalytic performance of SrTiO₃-SrWO₄ [J]. Inorganic Chemicals Industry, 2024, 56(7): 143-149.
[12]	LIU Min, HUANG Xiu, ZHANG Liyuan. Research progress of S-type heterojunction photocatalysts [J]. Inorganic Chemicals Industry, 2024, 56(7): 18-27.
[13]	LI Jiangpeng, ZHANG Huibin. Synergistic degradation of methylene blue by photo-Fenton and photocatalytic with 3D porous LaFeO₃/CeO₂/SrTiO₃ [J]. Inorganic Chemicals Industry, 2024, 56(5): 141-148.
[14]	TANG Bei. Preparation of ZnO/g-C₃N₄ heterojunction photocatalytic material and its degradation of pyridine [J]. Inorganic Chemicals Industry, 2024, 56(4): 133-142.
[15]	LI Qiaoyun, HUANG Xiuxing, WEI Wenye, CHEN Zhen. Study on adsorption of methylene blue by activated carbon with acid/alkali synergistically modified fly ash [J]. Inorganic Chemicals Industry, 2024, 56(3): 131-136.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on photoelectric performance analysis of g-C₃N₅ nanorods and removal of Cr（Ⅵ） and methylene blue

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 13

References 29

Related Articles 15

Metrics

Comments

Recommended 0

Study on photoelectric performance analysis of g-C3N5 nanorods and removal of Cr（Ⅵ） and methylene blue