ZnCl2活化废旧涤纶基活性炭的制备及吸附性能

doi:10.19964/j.issn.1006-4990.2023-0526

Abstract

Abstract:

In order to realize the resource utilization of waste polyester fabrics，waste polyester⁃based activated carbon（WPT-AC） was prepared by ZnCl₂ activation⁃high temperature pyrolysis method.The crystal phase，characteristic groups and specific surface area pore structure of WPT-AC were characterized by XRD，FT-IR and BET.The optimal process for preparing WPT-AC was determined by orthogonal experiment.The adsorption performance of WPT-AC for methylene blue（MB） was evaluated and the adsorption mechanism was analyzed.The results showed that the specific surface area of WPT-AC prepared under the optimal process conditions of 45% ZnCl₂ solution，pyrolysis temperature of 900 ℃，heating rate of 5 ℃/min and pyrolysis time of 90 min was as high as 1 089.72 m²/g，and the yield was 58.45%.The abundant pore structure was beneficial to improve the adsorption of pollutants.The removal rate of MB by WPT-AC was 97.49% under the conditions of WPT-AC dosage of 2.0 g/L，initial concentration of MB of 500 mg/L，adsorption temperature of 40 ℃ and adsorption time of 80 min.WPT-AC also had a good adsorption effect on oxytetracycline（CIP），and the presence of electrostatic attraction was beneficial to the improvement of adsorption performance under the condition of Ni（Ⅱ） coexistence.The quasi⁃second⁃order kinetic model and Langmuir isothermal adsorption model of WPT-AC were more suitable for fitting the MB adsorption process of WPT-AC.

Key words: waste polyester?based activated carbon, adsorption, methylene blue, zinc chloride activation, high temperature pyrolysis

CLC Number:

TQ424.1

ZHANG Bangcheng, WANG Li. Preparation and adsorption properties of waste polyester⁃based activated carbon activated by ZnCl₂[J]. Inorganic Chemicals Industry, 2024, 56(7): 126-134.

Figures/Tables 17

Fig.1

Fig.2

Fig.3

Table 1

Table 2

Table 3

Fig.4

Fig.5

Fig.6

Fig.7

Fig.8

Fig.9

Table 4

Fig.10

Table 5

Fig.11

Fig.12

References 22

1	陈龙，周哲，张军，等.废旧棉与涤纶纺织品化学法循环再生利用的研究进展［J］.纺织学报，2022，43（5）：43-48.
	CHEN Long， ZHOU Zhe， ZHANG Jun，et al.Research progress in chemical recycling of waste cotton and polyester textiles［J］.Journal of Textile Research，2022，43（5）：43-48.
2	SINGHAL S， AGARWAL S， SINGHAL N.Chemical recycling of waste clothes：A smarter approach to sustainable development［J］.Environmental Science and Pollution Research International，2023，30（19）：54448-54469.
3	缪星宇，石振，许迪，等.废旧涤纶纺织品制备纤维增强复合材料的研究现状［J］.毛纺科技，2023，51（2）：129-134.
	MIAO Xingyu， SHI Zhen， XU Di，et al.Research status of fiber reinforced composites prepared from waste polyester textiles［J］.Wool Textile Journal，2023，51（2）：129-134.
4	SUN Y Y， XIA Z P， YANG A P，et al.Nanocellulose extracted from waste polyester/cotton fabric by chemical⁃mechanical separation technology［J］.Journal of Physics：Conference Series，2021，1790（1）：012074.
5	薛江鹏，莫治新，李有文，等.阳离子表面活性剂改性生物质炭对染料废水的吸附性能［J］.印染，2023，49（7）：60-63，68.
	XUE Jiangpeng， MO Zhixin， LI Youwen，et al.Adsorption performance of cationic surfactant modified biochar on dye wastewat⁃er［J］.China Dyeing & Finishing，2023，49（7）：60-63，68.
6	卜义夫，刘思乐，杜文娟，等.二硫化钼/石墨相氮化碳光催化降解印染废水研究［J］.皮革科学与工程，2023，33（3）：12-18.
	BU Yifu， LIU Sile， DU Wenjuan，et al.Study on photocatalytic degradation of printing and dyeing wastewater by molybdenum disulfide/graphite carbon nitride［J］.Leather Science and Engineering，2023，33（3）：12-18.
7	刘立华，贾俊芳，关俊霞.稻壳吸附染料废水中亚甲基蓝的动力学研究［J］.南开大学学报（自然科学版），2023，56（3）：85-91.
	LIU Lihua， JIA Junfang， GUAN Junxia.Kinetics study on the adsorption of methylene blue dye wastewater by rice husks［J］.Acta Scientiarum Naturalium Universitatis Nankaiensis，2023，56（3）：85-91.
8	金青青，梁晓怿，张佳楠，等.改性球形活性炭对氨气吸附性能的研究［J］.无机盐工业，2021，53（4）：61-66.
	JIN Qingqing， LIANG Xiaoyi， ZHANG Jia′nan，et al.Study on adsorption performance of modified spherical activated carbon for ammonia［J］.Inorganic Chemicals Industry，2021，53（4）：61-66.
9	郭晋杰，王晓龙，张聚华，等.活性炭吸附活性黄3RS染料的研究［J］.毛纺科技，2019，47（5）：30-34.
	GUO Jinjie， WANG Xiaolong， ZHANG Juhua，et al.Study on adsorption of reactive yellow 3RS dye on activated carbon［J］.Wool Textile Journal，2019，47（5）：30-34.
10	周林，杨瑛，郑文轩.棉秆基活性炭对印染废水中常见有机污染物的吸附效果［J］.印染，2019，45（16）：20-26.
	ZHOU Lin， YANG Ying， ZHENG Wenxuan.The adsorption effect of cotton straw based activated carbon on organic pollutants in printing and dyeing wastewater［J］.Dyeing & Finishing，2019，45（16）：20-26.
11	徐茹婷，马名哲，应浩，等.竹热解气化副产物改性制备高性能成型活性炭及其表征［J］.林产化学与工业，2023，43（4）：1-8.
	XU Ruting， MA Mingzhe， YING Hao，et al.Preparation and characterization of high performance formed activated carbon by modification of by⁃products from bamboo gasification［J］.Chemistry and Industry of Forest Products，2023，43（4）：1-8.
12	TIAN Danqi， XU Zhihua， ZHANG Daofang，et al.Multifaceted roles of FeCl₂ on pore formation of polyester fabric wastes⁃based activated carbon［J］.Colloids and Surfaces A：Physicochemical and Engineering Aspects，2020，598：124756.
13	卜义夫，刘思乐，宋丹丹，等.废旧涤纶基活性炭负载g-C₃N₄光催化剂的制备及其对亚甲基蓝的光催化降解［J］.毛纺科技，2023，51（2）：40-48.
	BU Yifu， LIU Sile， SONG Dandan，et al.Preparation of waste polyester⁃based activated carbon loaded g-C₃N₄ photocatalyst and its photocatalytic degradation of methylene blue［J］.Wool Textile Journal，2023，51（2）：40-48.
14	蒋仁杰，司艳晓，张文静，等.响应曲面法优化菌渣活性炭吸附水中亚甲基蓝［J］.科学技术与工程，2023，23（17）：7468-7477.
	JIANG Renjie， SI Yanxiao， ZHANG Wenjing，et al.Response surface methodology for the optimization of the adsorption of methylene blue in water by activated carbon of bacterial residue［J］.Science Technology and Engineering，2023，23（17）：7468-7477.
15	李兆强，王仲宇，孙嘉炜，等.煤矸石-污泥基活性炭对苯酚的吸附［J］.化工环保，2023，43（4）：470-477.
	LI Zhaoqiang， WANG Zhongyu， SUN Jiawei，et al.Adsorption of phenol by ZnCl₂ modified coal gangue⁃sludge based activated carbon［J］.Environmental Protection of Chemical Industry，2023，43（4）：470-477.
16	曹俊雅，张文茜，张婧，等.活性炭对乙黄药的吸附研究［J］.水处理技术，2023，49（6）：52-58.
	CAO Junya， ZHANG Wenxi， ZHANG Jing，et al.Study on adsorption of ethyl xanthate by activated carbon［J］.Technology of Water Treatment，2023，49（6）：52-58.
17	赵鹏，王刚，寇丽红，等.气化灰渣浮选精炭制备活性炭的研究［J］.燃料化学学报（中英文），2023，51（8）：1193-1200.
	ZHAO Peng， WANG Gang， KOU Lihong，et al.Preparation of flotation refined carbon from gasification slag［J］.Journal of Fuel Chemistry and Technology，2023，51（8）：1193-1200.
18	徐荣声，冯倩，孟泽，等.枸杞杆制活性炭对亚甲基蓝的吸附研究［J］.无机盐工业，2022，54（12）：106-112，118.
	XU Rongsheng， FENG Qian， MENG Ze，et al.Study on adsorption of methylene blue by activated carbon prepared by wolfberry stems［J］.Inorganic Chemicals Industry，2022，54（12）：106-112，118.
19	叶结旺，周志丹，金贞福.氮掺杂木质素基活性炭的制备、表征及其吸附性能研究［J］.林产化学与工业，2023，43（1）：127-132.
	YE Jiewang， ZHOU Zhidan， JIN Zhenfu.Preparation，characterization and adsorption properties of nitrogen⁃doped lignin⁃based activated carbon［J］.Chemistry and Industry of Forest Products，2023，43（1）：127-132.
20	冯倩，徐荣声，李梅，等.向日葵制活性炭对亚甲基蓝的吸附研究［J］.无机盐工业，2021，53（12）：122-128.
	FENG Qian， XU Rongsheng， LI Mei，et al.Research on adsorption of methylene blue on activated carbon prepared from sunflower［J］.Inorganic Chemicals Industry，2021，53（12）：122- 128.
21	陈淇，程婷，肖更生，等.榴莲壳和龙眼壳活性炭的制备、表征及其吸附性能研究［J］.食品工业科技，2023，44（15）：46- 54.
	CHEN Qi， CHENG Ting， XIAO Gengsheng，et al.Preparation，characterization and adsorption performance of activated carbon from durian shell and longan shell［J］.Science and Technology of Food Industry，2023，44（15）：46-54.
22	吴婷，姚晨飞，郝仕油，等.纳米羟基铁改性活性炭对亚甲基蓝的吸附性能研究［J］.环境污染与防治，2023，45（8）：1096-1100.
	WU Ting， YAO Chenfei， HAO Shiyou，et al.Adsorption performance of nano⁃hydroxyferric modified activated carbon for methy⁃hylene blue［J］.Environmental Pollution & Control，2023，45（8）：1096-1100.

样品	S_BET/ （m²·g^-1）	V_tot/ （cm³·g^-1）	V_mic/ （cm³·g^-1）	D_p/ nm
WPT-AC（500 ℃）	469.53	0.488	0.176	3.814
WPT-AC（600 ℃）	714.29	0.599	0.281	3.224
WPT-AC（700 ℃）	794.06	0.628	0.274	3.557
WPT-AC（800 ℃）	934.91	0.701	0.343	3.294
WPT-AC（900 ℃）	1 089.72	0.999	0.573	3.370

水平	因素
水平	A ZnCl₂质量分数/%	B热解温度/℃	C升温速率/ （℃·min^-1）	D热解时间/ min
1	35	700	5	60
2	45	800	10	90
3	55	900	15	120

序号	因素				Q_MB/ （mg·g^-1）	产率/ %
序号	A	B	C	D	Q_MB/ （mg·g^-1）	产率/ %
1	1	1	1	1	208.9	46.25
2	1	2	2	2	235.1	47.99
3	1	3	3	3	344.6	48.72
4	2	1	2	3	244.3	50.31
5	2	2	3	1	253.9	52.13
6	2	3	1	2	385.6	58.45
7	3	1	3	2	230.1	46.27
8	3	2	1	3	260.7	46.33
9	3	3	2	1	325.2	46.20
k₁	262.867	227.767	285.067	262.667
k₂	294.600	249.900	268.200	283.600
k₃	272.000	351.800	276.200	283.200
R	31.733	124.033	16.867	20.933
k₁′	47.320	47.277	50.010	47.860
k₂′	53.630	48.817	48.167	50.903
k₃′	46.267	51.123	49.040	48.453
R′	7.363	3.846	1.843	3.043

Langmuir等温吸附方程
线性拟合方程	q_m/（mg·g^-1）	b/（L·mg^-1）	R²
y=0.004 58x+0.040 99	245.431	0.350	0.998 48
Freundlich等温吸附方程
线性拟合方程	K_F/（mg^1-1^/n ·L¹^/n ·g^-1）	1/n	R²
y=0.053 44x+2.278 23	9.631	0.038	0.973 16

[1]	BAI Xingxing, LI Hanfei, TANG Yong, ZHANG Jun, ZHU Guangkai, LI Lishuo, TONG Zhangfa. Study on preparation of cellulose based hydrogel doped with nano-calcium carbonate and its adsorption properties of copper ions [J]. Inorganic Chemicals Industry, 2025, 57(2): 83-91.
[2]	ZHANG Feigang, LIU Zhongli. Study on application of CuO/g-C₃N₄ composites in organic dye degradation and supercapacitors [J]. Inorganic Chemicals Industry, 2025, 57(1): 129-136.
[3]	WANG Ping, XU Rongsheng, SUN Dong, SHI Xiaohong, XU Wei, LI Mei. Study on preparation of nitrogen-doped biochar and its adsorption properties for methylene blue [J]. Inorganic Chemicals Industry, 2024, 56(9): 117-127.
[4]	SONG Zhaoxia, LIU Yongkang, GUO Yaokun, WANG Tengfei. Study on adsorption performance of wheat straw biochar on malachite green [J]. Inorganic Chemicals Industry, 2024, 56(9): 128-135.
[5]	XIONG Chengrong, CHEN Yan, TANG Miao, ZHANG Fengze, ZHOU Tianxiang, OUYANG Ruifeng, DONG Gang, SHI Wei, ZENG Tao, CHEN Yunxia, SU Xiaoli. Research progress on preparation of 2D vermiculite nanosheets and their environmental adsorption of pollutants [J]. Inorganic Chemicals Industry, 2024, 56(8): 19-26.
[6]	ZHANG Lijin, LÜ Qing, CHEN Xiaolang, LI Qingxin, SHI Hongyu, QIN Jun. Preparation of Ca-based LDO composite material and its adsorption performance for phosphate [J]. Inorganic Chemicals Industry, 2024, 56(7): 37-45.
[7]	ZHAO Chuang, ZHANG Boyu, LI Ben, JIN Fengying, LI Bin, SUN Zhenhai, GUO Chunlei. Study on adsorption and separation technology of polycyclic aromatic hydrocarbons by adsorbent [J]. Inorganic Chemicals Industry, 2024, 56(7): 61-68.
[8]	LIU Kailong, ZHU Kongyi, GUO Chunlei, MA Xiaobiao, WANG Yujian, SHENG Qiang, LI Xiang, WANG Yinbin, JIN Fengying. Effects of process condition on performance of diesel aromatic to light aromatic [J]. Inorganic Chemicals Industry, 2024, 56(6): 139-146.
[9]	ZHU Zenghu, WANG Min, PENG Zhengjun, JIA Guofeng, LI Yan. Study on adsorption of potassium ions in lithium chloride solution [J]. Inorganic Chemicals Industry, 2024, 56(6): 61-66.
[10]	XU Mengyao, ZHANG Xin, HE Kunpeng, HE Jian, JIANG Wei. Preparation of yttrium oxide and zirconium phosphate adsorbents from zirconium-yttrium waste and evaluation of their performance [J]. Inorganic Chemicals Industry, 2024, 56(3): 116-124.
[11]	LI Qiaoyun, HUANG Xiuxing, WEI Wenye, CHEN Zhen. Study on adsorption of methylene blue by activated carbon with acid/alkali synergistically modified fly ash [J]. Inorganic Chemicals Industry, 2024, 56(3): 131-136.
[12]	HUANG Jianan, LU Xiaoyu, WANG Mitang. Effect of Ba-La co-doping on degradation of methylene blue dye by TaON [J]. Inorganic Chemicals Industry, 2024, 56(2): 146-151.
[13]	LI Yang, LOU Feijian, SUI Xin, LI Keyan, LIU Fei, GUO Xinwen. Preparation of amine-functionalized fumed SiO₂ materials and their performance for CO₂ adsorption [J]. Inorganic Chemicals Industry, 2024, 56(2): 38-43.
[14]	LIU Fujie, HE Qian, SU Long, JIANG Caiyun. Adsorption properties of methylene blue by surface functionalized magnetic biochar with sodium alginate [J]. Inorganic Chemicals Industry, 2024, 56(2): 65-73.
[15]	ZHANG Li, ZHANG Dan, PAN Hongyan, DONG Yonggang, LI Wenfei, QIN Hong. Study on preparation of low ash activated carbon by phosphoric acid method [J]. Inorganic Chemicals Industry, 2024, 56(2): 95-103.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Preparation and adsorption properties of waste polyester⁃based activated carbon activated by ZnCl₂

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 17

References 22

Related Articles 15

Metrics

Comments

Recommended 0

Preparation and adsorption properties of waste polyester⁃based activated carbon activated by ZnCl2