半固态储能电池的研究进展

doi:10.19964/j.issn.1006-4990.2021-0294

Abstract

Abstract:

The semi-solid energy storage batteries combine the advantages of high energy density of rechargeable batteries with the flexible design of flow batteries.It is a new type of electrochemical energy storage technology that has attracted widespread at-tention.The research progress on semi-solid batteries in the fields of lithium-ion batteries,lithium-sulfur batteries,zinc batter-ies,air batteries,organic batteries and other different types of energy storage batteries were reviewed.And the influence of active materials,conductive additives,electrolytes in the semi-solid electrodes and battery structure on the performance of semi-solid batteries were explored.Then problems in the development of semi-solid electrodes were further analyzed and sum-marized,and it was found that the performance of semi-solid batteries could be effectively improved by developing new mate-rials and new chemical systems.Finally,it was put forward that the research focus of semi-solid batteries in the future was to improve energy density and cycle stability,and reduce slurry viscosity,etc.

Key words: energy storage batteries, semi-solid electrodes, flowable batteries, new system

CLC Number:

TQ131.11

BAI Xiaojie,CAO Defu,WANG Junhui,LIU Hao,LIAO Libing. Research progress on semi-solid energy storage batteries[J]. Inorganic Chemicals Industry, 2022, 54(2): 6-15.

Figures/Tables 7

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References 57

[1]	DUNN B, KAMATH H, TARASCON J M. Electrical energy storage for the grid:A battery of choices[J]. Science, 2011, 334(6058):928-935. doi: 10.1126/science.1212741
[2]	WANG W, LUO Q T, LI B, et al. Recent progress in redox flow ba-ttery research and development[J]. Advanced Functional Materials, 2013, 23(8):970-986. doi: 10.1002/adfm.v23.8
[3]	DUDUTA M, HO B, WOOD V C, et al. Semi-solid lithium rechar-geable flow battery[J]. Advanced Energy Materials, 2011, 1(4):511-516. doi: 10.1002/aenm.201100152
[4]	任雅琨, 陈永翀, 冯彩梅, 等. 锂离子液流电池电极悬浮液的电子导电性建模及仿真[J]. 现代科学仪器, 2014(3):84-89.
[5]	CHAYAMBUKA K, FRANSAER J, DOMINGUEZ-BENETTON X. Modeling and design of semi-solid flow batteries[J]. Journal of Po-wer Sources, 2019, 434.Doi: 10.1016/j.jpowsour.2019.226740. doi: 10.1016/j.jpowsour.2019.226740
[6]	SHUKLA G, FRANCO A A. Handling complexity of semisolid redox flow battery operation principles through mechanistic simulations[J]. The Journal of Physical Chemistry C:Nanomaterials and Interfaces, 2018, 122(42):23867-23877. doi: 10.1021/acs.jpcc.8b06642
[7]	LACROIX R, BIENDICHO J J, MULDER G, et al. Modelling the rheology and electrochemical performance of Li₄Ti₅O₁₂ and LiNi_1/3Co_1/3Mn_1/3O₂ based suspensions for semi-solid flow batteries[J]. Electrochimica Acta, 2019, 304:146-157. doi: 10.1016/j.electacta.2019.02.107
[8]	SEN S, CHOW C M, MOAZZEN E, et al. Electroactive nanofluids with high solid loading and low viscosity for rechargeable redox flow batteries[J]. Journal of Applied Electrochemistry, 2017, 47(5):593-605. doi: 10.1007/s10800-017-1063-4
[9]	KURATANI K, ISHIBASHI K, KOMODA Y, et al. Controlling of di-spersion state of particles in slurry and electrochemical properties of electrodes[J]. Journal of the Electrochemical Society, 2019, 166(4):A501-A506. doi: 10.1149/2.0111904jes
[10]	冯彩梅, 张晓虎, 陈永翀, 等. 新型电化学储能技术:半固态锂电池[J]. 科技通报, 2017, 33(8):19-26,179.
[11]	陈永翀, 武明晓, 任雅琨, 等. 锂离子液流电池的研究进展[J]. 电工电能新技术, 2012, 31(3):81-85.
[12]	CHEN H N, LAI N C, LU Y C. Silicon-carbon nanocomposite semi-solid negolyte and its application in redox flow batteries[J]. Che-mistry of Materials, 2017, 29(17):7533-7542.
[13]	WU Y Y, CAO D F, BAI X J, et al. Effects of non-ionic surfactants on the rheological,electrical and electrochemical properties of highly loaded silicon suspension electrodes for semi-solid flow ba-tteries[J]. ChemElectroChem, 2020, 7(17):3623-3631. doi: 10.1002/celc.v7.17
[14]	VENTOSA E, SKOUMAL M, VAZQUEZ F J, et al. Electron bottl-eneck in the charge/discharge mechanism of lithium titanates for batteries[J]. ChemSusChem, 2015, 8(10):1737-1744. doi: 10.1002/cssc.201500349
[15]	MADEC L, YOUSSRY M, CERBELAUD M, et al. Electronic vs io-nic limitations to electrochemical performance in Li₄Ti₅O₁₂-based organic suspensions for lithium-redox flow batteries[J]. Journal of the Electrochemical Society, 2014, 161(5):A693-A699. doi: 10.1149/2.035405jes
[16]	QI Z X, KOENIG G M. A carbon-free lithium-ion solid dispersion redox couple with low viscosity for redox flow batteries[J]. Journal of Power Sources, 2016, 323:97-106. doi: 10.1016/j.jpowsour.2016.05.033
[17]	VENTOSA E, ZAMPARDI G, FLOX C, et al. Solid electrolyte in-terphase in semi-solid flow batteries:A wolf in sheep′s clothing[J]. Chemical Communications, 2015, 51(81):14973-14976. doi: 10.1039/C5CC04767F
[18]	QI Z X, LIU A L, KOENIG G M. Carbon-free solid dispersion LiCoO₂ redox couple characterization and electrochemical evalua-tion for all solid dispersion redox flow batteries[J]. Electrochimica Acta, 2017, 228:91-99. doi: 10.1016/j.electacta.2017.01.061
[19]	WEI T S, FAN F Y, HELAL A, et al. Biphasic electrode suspensions for Li-ion semi-solid flow cells with high energy density,fast charge transport,and low-dissipation flow[J]. Advanced Energy Materi-als, 2015, 5(15).Doi: 10.1002/aenm.201500535. doi: 10.1002/aenm.201500535
[20]	DANIEL R G, ZAHILIA C H, SERGI S R, et al. Battery and super-capacitor materials in flow cells.Electrochemical energy storage in a LiFePO₄/reduced graphene oxide aqueous nanofluid[J]. Elec-trochimica Acta, 2018, 281(5):594-600.
[21]	LI Z, SMITH K C, DONG Y J, et al. Aqueous semi-solid flow cell:Demonstration and analysis[J]. Physical Chemistry Chemical Phy-sics, 2013, 15(38).Doi: 10.1039/c3cp53428f. doi: 10.1039/c3cp53428f
[22]	FENG C M, CHEN Y C, LIU D D, et al. Conductivity and electro-chemical performance of LiFePO₄ slurry in the lithium slurry ba-ttery[J]. IOP Conference Series:Materials Science and Engineer-ing, 2017, 207(1).Doi: 10.1088/1757-899X/207/1/012076. doi: 10.1088/1757-899X/207/1/012076
[23]	高静, 陈剑, 衣宝廉. 半固态LiFePO₄液流电池的研究与制备[J]. 电源技术, 2018, 42(11):1690-1693.
[24]	QI C L, MA X L, NING G Q, et al. Aqueous slurry of S-doped car-bon nanotubes as conductive additive for lithium ion batteries[J]. Carbon, 2015, 92:245-253. doi: 10.1016/j.carbon.2015.04.028
[25]	TIAN X Q, FENG C M, JIANG H, et al. Surface modification of po-sitive current collector for lithium slurry battery[J]. Advanced Te-chnology of Electrical Engineering and Energy, 2019, 38(9):59-66.
[26]	BIENDICHO J J, FLOX C, SANZ L, et al. Static and dynamic stu-dies on LiNi_1/3Co_1/3Mn_1/3O₂-based suspensions for semi-solid flow batteries[J]. ChemSusChem, 2016, 9(15):1938-1944. doi: 10.1002/cssc.v9.15
[27]	ZHENG Q, NIU Z H, YE J, et al. High voltage,transition metal complex enables efficient electrochemical energy storage in a Li-ion battery full cell[J]. Advanced Functional Materials, 2017, 27(4).Doi: 10.1002/adfm.201604299. doi: 10.1002/adfm.201604299
[28]	SONG Z P, ZHOU H S. Towards sustainable and versatile energy storage devices:An overview of organic electrode materials[J]. Energy & Environmental Science, 2013, 6(8):2280-2301.
[29]	PENG H J, HUANG J Q, CHENG X B, et al. Review on high-load-ing and high-energy lithium-sulfur batteries[J]. Advanced Energy Materials, 2017, 7(24).Doi: 10.1002/aenm.201700260. doi: 10.1002/aenm.201700260
[30]	XU S, CHENG Y Y, ZHANG L, et al. An effective polysulfides brid-gebuilder to enable long-life lithium-sulfur flow batteries[J]. Nano Energy, 2018, 51:113-121. doi: 10.1016/j.nanoen.2018.06.044
[31]	CHEN H N, ZOU Q L, LIANG Z J, et al. Sulphur-impregnated flow cathode to enable high-energy-density lithium flow batteries[J]. Nature Communications, 2015, 6.Doi: 10.1038/ncomms6877. doi: 10.1038/ncomms6877
[32]	CHEN H N, LU Y C. A high-energy-density multiple redox semi- solid-liquid flow battery[J]. Advanced Energy Materials, 2016, 6(8).Doi: 10.1002/aenm.201502183. doi: 10.1002/aenm.201502183
[33]	XU S, ZHANG L, ZHANG X P, et al. A self-stabilized suspension catholyte to enable long-term stable Li-S flow batteries[J]. Journal of Materials Chemistry A, 2017, 5(25):12904-12913. doi: 10.1039/C7TA02110K
[34]	DONG K, WANG S P, YU J X. A lithium/polysulfide semi-solid rechargeable flow battery with high output performance[J]. RSC Advances, 2014, 4(88):47517-47520. doi: 10.1039/C4RA08413F
[35]	FAN F Y, WOODFORD W H, LI Z, et al. Polysulfide flow batteries enabled by percolating nanoscale conductor networks[J]. Nano Letters, 2014, 14(4):2210-2218. doi: 10.1021/nl500740t
[36]	SOLOMON B R, CHEN X W, RAPOPORT L, et al. Enhancing the performance of viscous electrode-based flow batteries using lubri-cant-impregnated surfaces[J]. ACS Applied Energy Materials, 2018, 1(8):3614-3621. doi: 10.1021/acsaem.8b00241
[37]	ZHOU Y C, CONG G T, CHEN H N, et al. A self-mediating redox flow battery:High-capacity polychalcogenide-based redox flow ba-ttery mediated by inherently present redox shuttles[J]. ACS Energy Letters, 2020, 5(6):1732-1740. doi: 10.1021/acsenergylett.0c00611
[38]	GU S, HUANG X, WANG Q, et al. A hybrid electrolyte for long-life semi-solid-state lithium sulfur batteries[J]. Journal of Materials Chemistry A, 2017, 5(27):13971-13975. doi: 10.1039/C7TA04017B
[39]	方飞, 张文魁, 施媛媛, 等. 可充电锌电极的研究现状和进展[J]. 浙江化工, 2004, 35(7):23-25.
[40]	VENTOSA E, AMEDU O, SCHUHMANN W. Aqueous mixed-cation semi-solid hybrid-flow batteries[J]. ACS Applied Energy Materi-als, 2018, 1(10):5158-5162.
[41]	XIE C X, LI T Y, DENG C Z, et al. A highly reversible neutral zinc/manganese battery for stationary energy storage[J]. Energy & En- vironmental Science, 2020, 13(1):135-143.
[42]	MUBEEN S, JUN Y S, LEE J, et al. Solid suspension flow batteries using earth abundant materials[J]. ACS Applied Materials & In-terfaces, 2016, 8(3):1759-1765.
[43]	LIU J, WANG Y. Preliminary study of high energy density Zn/Ni flow batteries[J]. Journal of Power Sources, 2015, 294:574-579. doi: 10.1016/j.jpowsour.2015.06.110
[44]	ZHU Y G, NARAYANAN T M, TULODZIECKI M, et al. High-en-ergy and high-power Zn-Ni flow batteries with semi-solid electro-des[J]. Sustainable Energy & Fuels, 2020, 4:4076-4085.
[45]	SOAVI F, RUGGERI I, ARBIZZANI C. Design study of a novel,semi-solid Li/O₂ redox flow battery[J]. ECS Transactions, 2016, 72(9):1-9.
[46]	RUGGERI I, ARBIZZANI C, SOAVI F. A novel concept of semi-solid,Li redox flow air(O₂) battery,a breakthrough towards high energy and power batteries[J]. Electrochimica Acta, 2016, 206:291-300. doi: 10.1016/j.electacta.2016.04.139
[47]	RUGGERI I, ARBIZZANI C, SOAVI F. Carbonaceous catholyte for high energy density semi-solid Li/O₂ flow battery[J]. Carbon, 2018, 130:749-757. doi: 10.1016/j.carbon.2018.01.056
[48]	MORI R. Semi-solid-state aluminium-air batteries with electrolytes composed of aluminium chloride hydroxide with various hydropho-bic additives[J]. Physical Chemistry Chemical Physics, 2018, 20(47):29983-29988. doi: 10.1039/C8CP03997F
[49]	KUPSCH C, WEIK D, FEIERABEND L, et al. Vector flow imaging of a highly-laden suspension in a zinc-air flow battery model[J]. IEEE Transactions on Ultrasonics,Ferroelectrics,and Frequency Control, 2019, 66(4):761-771. doi: 10.1109/TUFFC.58
[50]	ZHAO Y F, SI S H, WANG L, et al. Electrochemical study on poly-pyrrole microparticle suspension as flowing anode for manganese dioxide rechargeable flow battery[J]. Journal of Power Sources, 2014, 248:962-968. doi: 10.1016/j.jpowsour.2013.10.008
[51]	CHEN H N, ZHOU Y C, LU Y C. Lithium-organic nanocomposite suspension for high-energy-density redox flow batteries[J]. ACS Energy Letters, 2018, 3(8):1991-1997. doi: 10.1021/acsenergylett.8b01257
[52]	ZHANG X F, ZHANG P Y, CHEN H N. Organic multiple redox se-mi-solid-liquid suspension for Li-based hybrid flow battery[J]. ChemSusChem, 2021, 14:1-9. doi: 10.1002/cssc.v14.1
[53]	XING X Q, LIU Q H, LI J, et al. A nonaqueous all organic semisolid flow battery[J]. Chemical Communications, 2019, 55(94):14214-14217. doi: 10.1039/C9CC07937H
[54]	YAN W, WANG C X, TIAN J Q, et al. All-polymer particulate sl-urry batteries[J]. Nature Communications, 2019, 10(1).Doi: 10.1038/s41467-019-10607-0. doi: 10.1038/s41467-019-10607-0
[55]	CAO H J, SI S H, XU X B, et al. Electrochemical study of a three-dimensional Zn-Mn alloy//Mn-doped polyaniline suspension flow battery with enhanced electrochemical performance[J]. Interna-tional Journal of Electrochemical Science, 2020, 15:4188-4202.
[56]	MUNOZ-TORRERO D, PALMA J, MARCILLA R, et al. Al-ion battery based on semisolid electrodes for higher specific energy and lower cost[J]. ACS Applied Energy Materials, 2020, 3(3):2285-2289. doi: 10.1021/acsaem.9b02253
[57]	PETEK T J, HOYT N C, SAVINELL R F, et al. Slurry electrodes for iron plating in an all-iron flow battery[J]. Journal of Power So-urces, 2015, 294:620-626.

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Research progress on semi-solid energy storage batteries

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