非贵金属基催化剂用于甘油电氧化的研究进展

doi:10.19964/j.issn.1006-4990.2024-0412

摘要/Abstract

摘要：

甘油作为生物柴油生产过程中的副产物，价格低廉且储量丰富，将其转化为高附加值精细化学品是缓解当前资源、环境等问题的有效途径之一。电催化甘油氧化反应（GEOR）因无需氧化剂且阴极产生清洁能源H₂等优点而极具应用前景；但贵金属催化剂的高成本和稀缺性限制其商业化应用。因此，亟需开发高效非贵金属催化剂以替代贵金属催化剂。在简单介绍甘油氧化机理的基础上，对近年来过渡金属基GEOR催化剂的研究进展进行综述，并重点梳理了不同催化剂设计策略对甘油氧化性能的提升作用，包括掺杂工程、合金策略、异质结构筑、复合工程和晶相调节等。最后，对过渡金属基催化剂在GEOR中所面临的挑战进行展望。

关键词: 甘油, 氧化, 电催化, 非贵金属

Abstract:

Glycerol is an important by-product in the production process of biodiesel with low prices and abundant reserves.Converting glycerol into high value-added fine chemicals is one of the effective ways to alleviate the current problems of resources and environment.Glycerol electrooxidation reaction（GEOR） has great application prospects due to its advantages of no need for oxidants and generation of clean energy H₂ at the cathode.However，the high cost and scarcity of precious metal catalysts limit their commercial application.Therefore，there is an urgent need to develop efficient non-noble metal catalysts to replace noble metal catalysts.Based on a brief introduction of glycerol oxidation mechanism，recent research on transition metal-based GEOR catalysts and various catalyst design strategies to enhance glycerol oxidation performance were reviewed.These strategies included doping engineering，alloy strategies，heterogeneous structure building，composite engineering and crystal phase adjustment.Finally，the challenges faced by transition metal-based catalysts in GEOR were prospected.

Key words: glycerol, oxidation, electrocatalysis, non-noble metal

中图分类号:

O643.36

白一彤, 宋明洋, 李杰飞. 非贵金属基催化剂用于甘油电氧化的研究进展[J]. 无机盐工业, 2025, 57(4): 1-10.

BAI Yitong, SONG Mingyang, LI Jiefei. Research progress of non-noble metal-based catalysts for electrooxidation of glycerol[J]. Inorganic Chemicals Industry, 2025, 57(4): 1-10.

图/表 6

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