无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (5): 66-.

• 论文 • 上一篇    下一篇

过氧化氢生产中失活氧化铝的再生及其理化性能

郭子添1,阮 恒1,王富丽1,黄世勇1,黄 媚2,黄青则1,王秋萍2   

  1. 1.广西壮族自治区化工研究院,广西南宁 530001;2.广西新晶科技有限公司
  • 出版日期:2016-05-10 发布日期:2016-05-16

Regeneration and physical-chemical properties of inactivated alumina in production of hydrogen peroxide

Guo Zitian1,Ruan Heng1,Wang Fuli1,Huang Shiyong1,Huang Mei2,Huang Qingze1,Wang Qiuping2   

  1. 1.Guangxi Research Institute of Chemical Industry,Nanning 530001,China;2.Guangxi Xinjing Technology Co.,Ltd.
  • Published:2016-05-10 Online:2016-05-16

摘要: 蒽醌法制备过氧化氢工艺中使用的活性氧化铝球催化剂经一段时间后会失去活性,需要定期更换。对失活氧化铝球做了再生处理,制备了再生条形氧化铝催化剂。结果表明,再生条形氧化铝催化剂比原活性氧化铝球具有更优良的性能,其比表面积、孔容、平均孔径、压碎强度分别比原活性氧化铝球增大23.1%、24.3%、22.3%、3.3%。产品经工作液浸泡60 d后,上述4项理化指标仅分别下降了29.3%、13.4%、16.3%、7.2%,而原活性氧化铝球则分别下降了47.7%、40.5%、16.7%、59.8%。再生条形氧化铝催化剂的使用寿命比原活性氧化铝提高1倍以上。

关键词: 蒽醌法, 过氧化氢, 活性氧化铝, 催化剂, 再生

Abstract: The catalyst of spherical activated alumina which applied in hydrogen peroxide production with anthraquinone method will lose its catalytic activity after used for a period of time,so it has to be regularly replaced.The regenerated bar-like alumina catalyst was prepared with inactivated alumina.Results showed that the regenerated bar-like alumina had more superior performance compared to the spherical activated alumina,the specific surface area,pore volume,average pore size,and compressive strength increased by 23.1%,24.3%,22.3%,and 3.3%,respectively.After soaking in working liquid for 60 d, these four physical-chemical properties only decreased by 29.3%,13.4%,16.3%,and 7.2% for regenerated bar-like alumina, while the spherical activated alumina fell 47.7%,40.5%,16.7%,and 59.8%,respectively.As a result,the service life of regenerated bar-like alumina increased by 1 time than that of original activated alumina.

Key words: anthraquinone method, hydrogen peroxide, activated alumina, catalyst, regeneration

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