无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (1): 49-.

• 论文 • 上一篇    下一篇

镁法脱硫系统脱硫液中重金属的去除研究

张亚斌   

  1. 山西大学工程学院,山西太原 030013
  • 出版日期:2014-01-10 发布日期:2014-01-13

Removing of heavy metals in desulfurization solution by Mg(OH)2

 ZHANG  Ya-Bin   

  1. School of Engineering,Shanxi University,Taiyuan 030013,China
  • Published:2014-01-10 Online:2014-01-13

摘要: 为了去除脱硫废液中危害较大的重金属(铬、镉、铅、锰),采用向硫酸镁溶液中加入氢氧化镁吸附剂对其进行化学吸附。应用电感耦合等离子体原子发射光谱仪(ICP-AES)检测了氢氧化镁对铬、镉、铅、锰4种重金属的去除效果。结果发现,氢氧化镁对铬、铅的去除效果在95%以上,对镉、锰的处理效果在40%左右;使用过的氢氧化镁进行3次轻烧后得到的氧化镁仍可使铅的去除率保持在90%以上;pH=5时氢氧化镁对镉的去除率降低最多,对其他3种重金属的处理效果影响较小。因此,对于镁法脱硫来说,利用氢氧化镁这种绿色水处理剂可以在没有其他杂质引入溶液的情况下达到很好的脱除重金属的效果。

关键词: 氢氧化镁, 重金属, 脱硫液

Abstract: In order to remove the dangerous heavy metals(chromium,cadmium,lead,and manganese) in the FGD waste solutions,magnesium hydroxide sorbent was added into the magnesium sulfate solution for chemical adsorption.Removing effects of chromium,cadmium, lead,and manganese were detected by ICP-AES.It was found that the removing effects for chromium and lead were more than 95%,respectively;the removing effects for cadmium and manganese were about 40%;the used magnesium hydroxide could be transformed into the magnesium oxide after three times′ light sintering,which could also keep the removing rate of lead more than 90%;and when pH=5 the magnesium hydroxide′s removing effect for cadmium reduced the most,however,it had less effect on the other heavy metals.Therefore,with regard to the magnesium desulfurization,the use of magnesium hydroxide which was a green water treatment agent could obtain good results in the removal of heavy metals without other impurities induced into the solution.

Key words: magnesium hydroxide, heavy metals, desulfurization solution

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