无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (1): 52-.

• 论文 • 上一篇    下一篇

固化铬渣的解毒研究

宋 玄,李 裕,张 茹,王冬琴   

  1. 中北大学化工与环境学院,山西太原 030051
  • 出版日期:2014-01-10 发布日期:2014-01-13

Study on the detoxification of solid chromium slag

 SONG   Xuan, LI   Yu, ZHANG   Ru, WANG  Dong-Qin   

  1. School of Chemical Engineering and Environment,North University of China,Tianyuan 030051,China
  • Published:2014-01-10 Online:2014-01-13

摘要: 为了处理某含有较低毒性的固化铬渣,首先通过超声破解的方法浸出固化铬渣中的六价铬,再利用水合肼对浸出液中的六价铬进行还原处理,并探讨多种因素对六价铬还原的影响。结果表明:超声处理5 h可以使大部分的六价铬从固化铬渣中浸出;在碱性范围内,投料比、反应温度、反应时间及pH对六价铬的还原影响显著。反应的最佳实验条件为:反应温度为60 ℃、浸出液的pH为8.5、n(水合肼)∶ n(六价铬)=130∶1、反应时间为30 min。在最佳实验条件下,六价铬的去除率达到了98.6%,六价铬的最终质量浓度为0.09 mg/L。

关键词: 铬渣, 水合肼, Cr(Ⅵ), 超声

Abstract: The purpose of the experiment is to dispose the solid chromium slag with a low toxicity.Firstly,Cr(Ⅵ) from solid chromium slag  was leached by using ultrasonic treatment.Then Cr(Ⅵ) in the leaching liquid was reduced by hydrazine hydrate.Various factors affected the reduction of Cr (Ⅵ)were discussed.Results indicated that ultrasonic treatment could leach most of the Cr(Ⅵ) from solid chromium slag in 5 h;in the alkaline range,the factors,such as amount-of-substance ratio of reactants,reaction temperature,reaction time,and pH all had obvious affection on the reduction of Cr(Ⅵ).The optimum experimental conditions were as follows:reaction temperature was 60 ℃,pH=8.5,amount-of-substance ratio of hydrazine hydrate to Cr(Ⅵ) was 130 ∶1,and reaction time was 30 min.Under those conditions,the removal rate and final mass concentra- tion of Cr(Ⅵ) could reach 98.6% and  0.09 mg/L,respectively.

Key words: chromium slag, hydrazine hydrate, Cr(Ⅵ), ultrasonic

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