无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (5): 58-.

• 论文 • 上一篇    下一篇

碳硫分析仪测定碳酸锶中总硫含量

杨占寿1,赵鹏兴2,龙光明1,祁米香1,王舒娅1,邹兴武1,李加升1   

  1. 1.中国科学院青海盐湖研究所,青海西宁 810008;2.金瑞矿业发展股份有限公司
  • 发布日期:2011-05-12

Determination of total sulfur content in strontium carbonate by carbon sulfur analyzer

Yang Zhanshou1,Zhao Pengxing2,Long Guangming2,Qi Mixiang1,Wang Shuya1,Zou Xingwu1,Li Jiasheng1    

  1. 1.Qinghai Institute of Salt Lakes,Chinese Academy of Sciences,Xining 810008, China;2.Qinghai Jinrui Mineral Development Co.,Ltd.
  • Online:2011-05-12

摘要: 介绍了碳硫分析仪测定碳酸锶总硫含量的分析方法。在特制硅钼粉、锡粒、纯铁助熔剂和氧气存在的条件下,试样中各价态的硫在电弧燃烧炉中经自动引弧高温氧化为二氧化硫,经吸收液吸收生成亚硫酸,用碘-淀粉标准溶液光控自动滴定亚硫酸根,根据其消耗量计算出总硫含量。该测定方法的相对标准偏差小于0.5%,加标回收率大于95%,该方法简便快速、重现性好、精密度高,适合快速分析的要求。

关键词: 碳酸锶, 硫, 电弧燃烧

Abstract: Determination method of total sulfur content in strontium carbonate by carbon and sulfur analyzer was introduced.Sulfurs of each valence state in the sample were all oxidized to SO2 by high-temperature automatic arc striking in an electric arc induction furnace in the presence of flux (special silicon molybdenum powder,tin grains and pure iron) and oxygen.SO2 would be absorbed by absorption liquid to form H2SO3,and then light-controlled automatic titration of SO32- with iodine-starch standard solution was carried out,and finally total sulfur content could be calculated according to the consumption of standard solution.This method has advantages of convenience,simplicity,good repeatability,and high precision,whose relative standard deviation is less than 0.5% and standard sample recovery rate is more than 95%. 

Key words: strontium carbonate, sulfur, electric arc induction combustion

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