无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2010, Vol. 0 ›› Issue (12): 46-.

• 论文 • 上一篇    下一篇

碱性活化煤系高岭土吸附生活污水中磷的研究

沈王庆,李道华,卿东红   

  1. 内江师范学院化学与生命科学学院,四川内江 641112
  • 发布日期:2011-04-18

Study on phosphorus in municipal wastewater adsorpted by alkaline-activated coal-based kaolin 

Shen Wangqing,Li Daohua,Qing Donghong   

  1. School of Chemistry and Life Science,Neijiang Normal University,Neijiang 641112,China
  • Online:2011-04-18

摘要: 为了拓宽煤系高岭土的应用途径,同时去除城市生活污水中的磷元素,研究了碳酸钠活化煤系高岭土以及用其吸附城市生活污水中磷的方法。考察了活化煤系高岭土的粒径对污水中磷元素吸附的影响,以及其吸附热力学和吸附等温线,并进一步研究了吸附机理。研究结果表明:当活化煤系高岭土的粒径在106~1 700 μm时,随着粒径的不断减小,其对磷的吸附率不断增大,当粒径减小到150 μm以后,吸附率变化趋缓。碳酸钠活化煤系高岭土对城市生活污水中磷的吸附行为符合Freundlich型,且升高温度有利于吸附,因此其吸附为吸热过程。

关键词: 煤系高岭土, 活化,

Abstract: To amplify applied prospect of coal-based kaolin and solve water body polluted by phosphorus,coal-based kaolin activated by Na2CO3 and the methods it adsorbing phosphorus in municipal wastewater were studied.Effect of partical size of activated coal-based kaolin on the adsorption of phosphorus as well as its adsorption thermodynamics and isotherm was investigated.Then its adsorption mechanism was further studied.Results showed when the partical size of activated coal-based kaolin was at 106~1 700 μm,the phosphorus adsorption rate continued to grow with the partical size declining;when the partical size decreased to 150 μm,the change of adsorption rate tended to be slow.Action that phosphorus in municipal wastewater adsorpted by activated coal-based kaolin accorded with Freundlich,and the higher temperature was good for the adsorption,so the action was an endothermic process.

Key words: coal-based kaolin, activation, phosphorus

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