铋基双金属光催化剂合成及降解有机污染物研究进展

doi:10.19964/j.issn.1006-4990.2021-0615

摘要/Abstract

摘要：

铋基双金属光催化剂包括铋基双金属氧化物、铋基双金属配合物及铋酸盐。综述了铋基双金属光催化剂分类、制备方法及其在光催化降解水中有机污染物的研究进展。系统介绍了铋基双金属材料制备方法,包括水热法、溶剂热法、化学溶液分解法、熔盐法、沉淀法、高温固相法等。同时重点阐述了铋基双金属光催化剂掺杂和复合改性,并对铋基双金属光催化剂的研究方向进行了展望,目的是为开发高性能的铋基双金属光催化剂提供实用指南。

关键词: 铋基双金属, 光催化, 有机污染物, 掺杂

Abstract:

Bismuth based bimetal photocatalysts（Bbbps） include bismuth based bimetal oxides,bismuth based bimetal coordination complexes and bismuth salts.The classification,preparation methods of Bbbps and their research advances in photocatalytic degradation of organic pollutants in water were reviewed.The synthesis methods of bismuth bimetallic materials were systematically introduced,including hydrothermal method,solvothermal method,chemical solution decomposition method,molten salt method,precipitation method,high temperature solid phase method,etc.At the same time,the doping and compound modification of Bbbps were emphasized,and the research direction of Bbbps was prospected.The aim was to provide a practical guide for the development of Bbbps with high performance.

Key words: bismuth based bimetal, photocatalysis, organic pollutant, doping

中图分类号:

TQ135.32

梁芳,史发年. 铋基双金属光催化剂合成及降解有机污染物研究进展[J]. 无机盐工业, 2022, 54(4): 61-68.

LIANG Fang,SHI Fanian. Research progress on synthesis of bismuth based bimetallic photocatalyst and degradation of organic pollutants[J]. Inorganic Chemicals Industry, 2022, 54(4): 61-68.

图/表 2

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催化剂	制备方法	禁带宽度/eV	污染物及浓度	光催化效率
CuBi-MOO/Gr^[11]	水热法	2.67	5 mg/L罗丹明B	10 min降解完全
BiCo-MCP^[12]	水热法	1.65	10 mg/L吡虫啉农药	5 h降解81%
BiVO₄^[20]	水热法	2.34	10 mg/L亚甲基蓝	2 h降解95%
BiVO₄^[21]	水热法	2.30	5×10^-5 mol/L罗丹明B	45 min降解90%
β-BiMo₂O₉^[24]	固相法	3.10	5 mg/L罗丹明B	403 min降解50%
			30 mg/L靛蓝胭脂红	295 min降解50%
			15 mg/L茜素红	282 min降解50%
			10 mg/L罗丹明B	90 min降解完全
			10 mg/L双酚A	150 min降解完全
AgBiO₃^[28]	水热法	0.75	20 mg/L 4-硝基苯酚	5 h降解90%
Bi₂WO₆^[30]	水热法	2.95	5 μg/L罗丹明B	50 min降解98%
Bi₁₂TiO₂₀^[31]	溶剂热法	—	25 mg/L酸性品红	3 h降解92%
Bi₂Ti₂O₇^[37]	化学溶液分解法	2.95	10 mg/L甲基橙	7.5 min脱色50%
Bi₄Ti₃O₁₂^[38]	化学溶液分解法	3.08	10 mg/L甲基橙	2.6 h脱色50%
Bi₄Ti₃O₁₂^[40]	熔盐法	—	20 mg/L亚甲基蓝	2 h降解完全
Bi₄Ti₃O₁₂^[42]	氧化剂过氧化物法	2.63	10 mg/L罗丹明B	3 h降解98%
Bi₁₂TiO₂₀^[42]	氧化剂过氧化物法	2.66	10 mg/L罗丹明B	3 h降解98%

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