非贵金属催化剂用于丙烷脱氢的研究进展

doi:10.19964/j.issn.1006-4990.2023-0274

Abstract

Abstract:

Propylene is an important industrial raw material mainly used in the production of polypropylene，acrylonitrile，isopropyl alcohol，acetone and propylene oxide.With the increasing demand for propylene，the technology of propane dehydrogenation has been widely used in the industrial production of propylene.Although platinum-based and chromium-based catalysts have high activity in propane dehydrogenation，they are also prone to poisoning and deactivation.Metal oxides have attracted widespread attention as alternative non-precious metal catalysts.Firstly，the reaction pathway and deactivation mechanism of propane dehydrogenation catalyzed by metal oxides were introduced.It was pointed out that enhancing the C—H activation ability，alleviating the reconstruction and reduction of active components were the key to improving the propane dehydrogenation performance of metal oxide catalysts.Then，several representative metal oxide catalysts were reviewed in detail，the mechanism of action and active species of various catalysts were summarized，and the existing problems of corresponding catalysts were analyzed and discussed.Finally，key research directions for future propane dehydrogenation catalysts were proposed，which was expected to provide new ideas for the direct production of chemicals through the activation of low-carbon alkanes.

Key words: propane dehydrogenation, metal oxides, active site, reaction pathway, stability, non-precious metal catalysts

CLC Number:

TQ138

WANG Yansu, LIU Guozhu, YU Haibin. Research progress of non-precious metal catalysts for propane dehydrogenation[J]. Inorganic Chemicals Industry, 2023, 55(12): 1-11.

Figures/Tables 11

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催化剂	反应温度/℃	反应原料比	丙烷初始转化率/%	丙烯选择性/%	失活速率K_d/h^-1
VO _x /ZrO₂^［13］	550	φ（C₃H₈）∶φ（H₂）∶φ（N₂）=7∶36∶7	25	85	0.549
VO _x /Al₂O₃^［14］	600	φ（C₃H₈）∶φ（H₂）∶φ（N₂）=7∶7∶11	32	约94	0.245
Mo－V－O^［15］	550	φ（C₃H₈）∶φ（N₂）=19∶81	36	89
Ga₈Al₂O₁₅^［16］	500	φ（C₃H₈）∶φ（N₂）=1∶39	49.7	91.7	0.086
［Fe］ZSM-5（MFI）^［17］	530		约7.2	约78
Sn-HMS^［18］	600	φ（C₃H₈）∶φ（N₂）=5∶95	约40	约90
SnO₂/SiO₂^［19］	600	φ（C₃H₈）∶φ（N₂）=5∶95	约30	约85
Fe_Ⅱ/SiO₂^［9］	650	φ（C₃H₈）∶φ（Ar）=3∶97	4.9	>99
Co-Al₂O₃-HT^［20］	590	φ（C₃H₈）∶φ（H₂）∶φ（N₂）=1∶0.8∶3.2	23	约97	0.06
VO _x /meso-Al₂O₃^［21］	510	φ（C₃H₈）∶φ（N₂）=4∶1	70	约85	0.169
GaO _x /SiO₂^［22］	580	φ（C₃H₈）∶φ（N₂）=1∶10	65	约90	0.136
Co–Al₂O₃–IMP^［20］	590	φ（C₃H₈）∶φ（H₂）∶φ（N₂）=1：0.8：3.2	21.2	94.6	0.16
Co（II）/SiO₂^［23］	550	φ（C₃H₈）∶φ（Ar）=20∶80	710	72	0.07
Co/SiO₂^［24］	550	φ（C₃H₈）∶φ（He）=3∶97	3.5	92	0.008 5
0.5CoSiBeta^［25］	600	φ（C₃H₈）∶φ（N₂）=5∶95	19	98.2	0.04
Co-Zr/SiO₂^［24］	550	φ（C₃H₈）∶φ（He）=3∶97	8.7	96	0.011 5
ZnO/Beta^［26］	600	φ（C₃H₈）∶φ（N₂）=5∶95	52	约93	0.095

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