钠离子电池层状过渡金属氧化物正极材料的研究进展

doi:10.19964/j.issn.1006-4990.2023-0296

Abstract

Abstract:

Layered transition metal oxides are considered as one of the most promising cathode materials for sodium-ion batteries（SIBs） due to their high theoretical capacity and ease of synthesis，which have attracted widespread attention.The purpose of this article is to review the research progress on layered transition metal oxides as cathode materials for SIBs.Firstly，a brief overview of the structural characteristics and existing issues of layered transition metal oxide cathode materials was provided.The Na⁺ coordination configurations and diffusion paths in terms of P2 and O3-type layered transition metal oxide cathode materials were also introduced.In addition，considering the issues of irreversible phase transition during charge/discharge process，high air sensitivity，and insufficient electrochemical performance，the recent research results of P2 and O3-type layered transition metal oxides were summarized based on three types of modification methods：component regulation，structural design，and surface coating.Finally，the future industrial development and potential research directions of layered transition metal oxide cathode materials for SIBs were prospected.

Key words: sodium-ion batteries, cathode materials, layered transition metal oxides, O3 phase, P2 phase

CLC Number:

TQ131.12

PENG Chenxi, LIU Jun. Research progress of layered transition metal oxides cathode materials for sodium-ion batteries[J]. Inorganic Chemicals Industry, 2023, 55(10): 1-12.

Figures/Tables 11

Table 1

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材料类型	优点	缺点
O3相	高比容量、高初始库伦效率	结构稳定性差、倍率性能差、多复杂相变
P2相	快速Na⁺传输通道、高结构稳定性	低比容量、空气稳定性差

改性方法	正极材料	截止电压/V	可逆比容量/（mA∙h∙g^-1）	容量保持率/%
成分调控	P2-Na_0.67Co_0.5Mn_0.5O₂^［32］	4.2	147.0 （0.1C）	~100 （1C，100 cycles）
	P2-Na_0.612K_0.056MnO₂^［33］	4.3	240.5 （20 mA/g）	98.2 （50 mA/g，100 cycles）
	Sb-Na_0.67Mn_0.66Ni_0.33O₂^［34］	4.2	130.0 （1C）	86.0 （0.5C，200 cycles）
	P2-Na_2/3Mn_1/2Ni_1/6Co_1/3O₂^［35］	4.5	134.0 （70 mA/g）	87.0 （1 A/g，300 cycles）
	P2-Na_0.6Ni_0.3Mn_0.7O₂^［40］	4.5	111.6 （0.1C）	60.0 （1C，100 cycles）
	P2-Na_0.66Mn_0.54Ni_0.13Co_0.13O₂^［60］	4.7	133.2 （0.1C）	77.9 （1C，100 cycles）
	P2-Na_0.67Ni_0.33MnO₂^［61］	3.57	143.3 （0.1C）	84.7 （0.1C，50 cycles）
结构设计	P2/P3-Na_0.7Li_0.06Mg_0.06Ni_0.22Mn_0.67O₂^［44］	4.4	119.0 （0.2C）	97.2 （0.2C，50 cycles）
	P2/O3-Na_0.8Mn_0.55Ni_0.25Fe_0.1Ti_0.1O₂^［45］	4.3	153.0 （0.1C）	80.2 （0.1C，100 cycles）
	P2/O3-Na_0.67Li_0.11Fe_0.36Mn_0.36Ti_0.17O₂^［46］	4.2	235.0 （0.1C）	85.4 （1C，100 cycles）
	P2-Na_0.4Mn_0.54Co_0.46O₂^［49］	4.2	145.0 （20 mA/g）	65.0 （20 mA/g，65 cycles）
	O3-Na_2/3Li_1/6Fe_1/6Co_1/6Ni_1/6Mn_1/3O₂^［52］	4.5	172.0 （0.1C）	63.7 （1C，300 cycles）
	P2-Na_0.76Cu_0.22Fe_0.30Mn_0.48O₂^［62］	4.0	154.1 （0.1C）	79.0 （2C，300 cycles）
表面包覆	TiO₂-NaMn_0.33Fe_0.33Ni_0.33O₂^［55］	4.2	160.9 （0.1C）	71.0 （1C，100 cycles）
	Na₃PO₄-Na（Ni_0.3Fe_0.4Mn_0.3）O₂^［57］	4.0	122.0 （0.2C）	75.0 （0.2C，100 cycles）
	Na_0.67Fe_0.5Mn_0.5O₂^［59］	4.2	192.0 （0.5C）	36.8 （0.5C，500 cycles）
	NTP-Na_0.65Mn_0.70Ni_0.16Co_0.14O₂^［63］	4.3	105.1 （5C）	84.3 （5C，500 cycles）

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Research progress of layered transition metal oxides cathode materials for sodium-ion batteries

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