膜法脱除天然气中二氧化碳的工艺技术发展现状

doi:10.19964/j.issn.1006-4990.2022-0030

Abstract

Abstract:

The current development status of membrane technology for CO₂ removal from natural gas was reviewed.Firstly，the technical characteristics and application situations of various processes for removing CO₂ from natural gas were compared.Compared with other separation methods，the membrane separation method has the advantages of less investment，small footprint，and low energy consumption.The principle of membrane separation，membrane materials，development status of membrane modules，and technical units of membrane technology to remove CO₂ from natural gas were introduced.The process technology unit was further divided into pretreatment unit and membrane separation unit：the pretreatment unit was selected to different removal methods to combine according to the components of the produced raw material gas；the raw material gas was entered the membrane separation unit after passing through the pretreatment unit.According to the actual working conditions，considering the hydrocarbon recovery rate，land occupation，energy consumption，investment and other factors，the membrane decarbonization separation process was reasonably designed.Then，the domestic and foreign application cases for the removal of CO₂ from natural gas by membrane methods were introduced.At present，there were many application cases of foreign membrane methods to remove CO₂ from natural gas，while there were few domestic application cases.Therefore，it was necessary to increase the domestic membrane method to remove CO₂from natural gas industrial applications.Finally，the development direction of CO₂ removal technology by natural gas membrane method was prospected.The research and development of membrane materials with independent intellectual property rights and maintaining high performance and long?term stability under actual complex working conditions is the focus of future membrane separation technology development.A coupled integrated combined process was that combining two or more single CO₂ removal technologies，such as membrane separation+chemical absorption，membrane separation+temperature swing adsorption，etc.This coupled integrated combined process would provide new directions for the future decarbonization process technological developments.

Key words: membrane, natural gas, removal, carbon dioxide, process technology

CLC Number:

TQ127.1

YAN Shuo,YU Haibin,CHEN Zan. Technology development status of carbon dioxide removal from natural gas by membrane process[J]. Inorganic Chemicals Industry, 2022, 54(5): 38-46.

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应用场合	公司及产品	膜材料	膜组件类型
CO₂/CH₄、H₂/CH₄、He/CH₄	UOP，Honeywell （Separex?，PolySep?）	醋酸纤维素、其他	螺旋卷式、中空纤维式
CO₂/CH₄	Cameron（Cynara?）	三乙酸纤维素	中空纤维式
CO₂/CH₄、H₂/CH₄、O₂/N₂	Ube	聚酰亚胺	中空纤维式
H₂分离、O₂/N₂	Air Products（PRISM?）	聚砜	中空纤维式
H₂分离、O₂/N₂	Air Liquide（MEDAL?）	聚酰亚胺/芳纶	中空纤维式
O₂/N₂	Generon IGS	四溴聚碳酸酯	中空纤维式
蒸汽/天然气、其他	MTR	硅橡胶、其他	螺旋卷式
蒸汽/天然气、空气脱水	GKSS	硅橡胶	板框式、螺旋卷式
CO₂/CH₄、沼气	Evonik（SEPURAN?，SEPURANNG?）	聚酰亚胺	中空纤维式

地区	处理量/ （1 116.3 Nm³·h^-1）	φ（原料气CO₂）/%	φ（产品气CO₂）/%
墨西哥	120	70	5
泰国	32	50	20
马来西亚	680	44	8
马来西亚	1 840	43	23
泰国	620	40	21
印度尼西亚	254	40	20
马来西亚	3 398	37	19
泰国	1 280	36	16
泰国	680	35	23
印度尼西亚	878	30	15
美国	86	30	10
巴基斯坦	240	12	3
巴基斯坦	510	12	3
美国	84	11	2
埃及	234	9	3
尼日利亚	200	7	2
埃及	218	6.8	3
埃及	107	6.7	3
巴基斯坦	750	6.5	2

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Technology development status of carbon dioxide removal from natural gas by membrane process

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