自清洁膜材料研究进展

doi:10.19964/j.issn.1006-4990.2021-0514

Abstract

Abstract:

Taking the application of self-cleaning materials in the photovoltaic industry as an example,the application development process,principles and main problems of nano-SiO₂ and nano-TiO₂ were summarized,which were commonly used as film materials for self-cleaning of solar cell glasses.And the main reason for the difficulty in commercial application of nanoTiO₂ self-cleaning film materials was analyzed.Combined with the author′s relevant research work,the research and development progress on nano-graphene self-cleaning anti-reflection film materials was introduced,and it was recommended to strengthen the self-cleaning film materials of nano-graphene in photovoltaic,textile,sewage treatment and other industries.It was believed that nano-graphene was the black material that promoted the upgrading of self-cleaning technology.With the continuous updating of preparation methods and technologies of nano-graphene composite materials,nano-graphene would be more widely used in the field of self-cleaning.

Key words: nano-SiO₂, nano-TiO₂, graphene, self-cleaning film

CLC Number:

TQ127.11

ZHANG Farong,FAN Tiantian,GUO Yanyun,LI Lu,LIU Bingguang,LI Jiansheng. Research progress on self-cleaning film materials[J]. Inorganic Chemicals Industry, 2022, 54(4): 74-80.

Figures/Tables 3

References 50

[1]	GREEN M A, BREMNER S P. Energy conversion approaches and materials for high-efficiency photovoltaics[J]. Nature Material, 2017, 16(1):23-34. doi: 10.1038/nmat4676
[2]	林昇华, 张景, 艾玲, 等. 光伏玻璃减反射膜的研究进展[J]. 材料导报, 2019, 33(11):3588-3595.
[3]	官燕玲, 张豪, 闫旭洲, 等. 灰尘覆盖对光伏组件性能影响的原位实验研究[J]. 太阳能学报, 2016, 37(8):1944-1950.
[4]	ABASS K I, AL-ZUBAIDI D S M, AL-WAELI A A K. Effect of pollution and dust on PV performance[J]. International Journal of Civil,Mechanical and Energy Science(IJCMES), 2017, 3(4):181-185.
[5]	ME P, JAYAMADHURI T. Effects of dust on the performance of solar panel and improving the performance by using arm controller and gear motor based cleaning method[J]. International Journal of Innovative Science,Engineering & Technology, 2015, 2(9):329-334.
[6]	赵明智, 张旭, 苗一鸣, 等. 沙漠环境沙尘覆盖下的光伏组件输出特性研究[J]. 太阳能学报, 2018, 39(3):744-748.
[7]	SAYYAH A, HORENSTEIN M N, MAZUMDER M K. Energy yield loss caused by dust deposition on photovoltaic panels[J]. Solar Energy, 2014, 107:576-604. doi: 10.1016/j.solener.2014.05.030
[8]	VERMA L K, SAKHUJA M, SON J, et al. Self-cleaning and antireflective packaging glass for solar modules[J]. Renewable Energy, 2011, 36(9):2489-2493. doi: 10.1016/j.renene.2011.02.017
[9]	LIN Y, HE J. Recent progress in antireflection and self-cleaning technology-from surface engineering to functional surfaces[J]. Progress in Materials Science, 2014, 61:94-143. doi: 10.1016/j.pmatsci.2013.12.003
[10]	李建生, 刘炳光, 董学通. 用于提高太阳能电池效率的无机纳米材料的研究进展[J]. 无机盐工业, 2014, 46(9):1-6.
[11]	MOZUMDER M S, MOURAD A H I, PERVEZ H, et al. Recent developments in multifunctional coatings for solar panel applications:A review[J]. Solar Energy Materials and Solar Cells, 2019, 189(11):75-102. doi: 10.1016/j.solmat.2018.09.015
[12]	潘胜. 光伏玻璃防尘性能研究[J]. 太阳能, 2020(4):23-28.
[13]	BAHATTAB M A, ALHOMOUDI I A, ALHUSSAINI M I, et al. Anti-soiling surfaces for PV applications prepared by sol-gel processing:Comparison of laboratory testing and outdoor exposure[J]. Solar Energy Materials and Solae Cells, 2016, 157:422-428.
[14]	HAGER P J, SCHLECHTE J S. Silica coating for enhanced hydrophilicity：US,20130071649[P]. 2013-03-21.
[15]	AZANI A, HALIN D S C, RAZAK K A, et al. Recent graphene oxide/TiO₂ thin film based on self-cleaning application[J]. IOP Conference Series:Materials Science and Engineering, 2019, 572.Doi: 10.1088/1757-899X/572/1/012079. doi: 10.1088/1757-899X/572/1/012079
[16]	李建生, 刘炳光, 王韬, 等. 棒状纳米二氧化硅水溶胶制备和镀膜研究[J]. 无机盐工业, 2016, 48(3):34-38.
[17]	GANGULY P, BYRNE C, BREEN A, et al. Antimicrobial activity of photocatalysts:Fundamentals,mechanisms[J]. Applied Catalysis B:Environmental, 2018, 225:51-75. doi: 10.1016/j.apcatb.2017.11.018
[18]	黄宇, 张静, 刘燕, 等. 光催化薄膜的亲水性及其应用[J]. 地球环境学报, 2018, 9(5):415-433.
[19]	李建生, 刘炳光, 王少杰, 等. 玻璃负载纳米TiO₂/SiO₂ 膜的制备和光催化性能[J]. 工业水处理, 2016, 36(5):60-63.
[20]	李建生, 韩璐, 张发荣, 等. 一种可见光催化的自清洁材料的制备方法:中国,2021109447256[P]. 2021-08-17.
[21]	GARLISI C, TREPCI E, LI X, et al. Multilayer thin film structures for multifunctional glass:Self-cleaning,antireflective and energysaving properties[J]. Applied Energy, 2020, 264.Doi: 10.1016/j.apenergy.2020.114697. doi: 10.1016/j.apenergy.2020.114697
[22]	张发荣, 李建生, 尹浩男, 等. 一种太阳电池玻璃低效减反射膜的增效方法:中国,108110064B[P]. 2019-11-08.
[23]	赵琪, 孙赫阳, 胡子文, 等. 二氧化钛基复合光催化材料的制备及应用进展[J]. 功能材料与器件学报, 2020, 26(2):83-88.
[24]	HIGASHINO S, MIYAKE M, IKENOUE T. Formation of a photocatalytic WO₃ surface layer on electrodeposited Al-W alloy coatings by selective dissolution and heat treatment[J]. Scientific Reports, 2019, 9.Doi: 10.1038/s41598-019-52178-6. doi: 10.1038/s41598-019-52178-6
[25]	SIMON S M, CHANDRAN A, GEORGE G, et al. Development of thick superhydrophilic TiO₂-ZrO₂ transparent coatings realized through the inclusion of poly(methyl methacrylate) and pluronic-F127[J]. ACS Omega, 2018, 3:14924-14932. doi: 10.1021/acsomega.8b01940
[26]	MADKOUR M, SAGHEER F A. Au/ZnS and Ag/ZnS nanoheterostructures as regenerated nanophotocatalysts for photocatalytic degradation of organic dyes[J]. Optical Materials Express, 2017, 7(1):158-169. doi: 10.1364/OME.7.000158
[27]	TALINUNGSANG, UPADHAYA D, KUMAR P, et al. Superhydrophilicity of photocatalytic ZnO/SnO₂ heterostructure for self-cleaning applications[J]. Journal of Sol-Gel Science and Technology, 2019, 92:575-584. doi: 10.1007/s10971-019-05127-8
[28]	RAMADHANI J P, WAHYUNINGSIH S, RAMELAN A H. Improving method of TiO₂-Fe₂O₃ composite materials for self-cleaning glass preparation[J]. Materials Science and Engineering, 2019, 578.Doi: 10.1088/1757-899X/578/1/012029. doi: 10.1088/1757-899X/578/1/012029
[29]	LATTHE S S, SUDHAGAR P, RAVIDHAS C, et al. Self-cleaning and superhydrophobic CuO coating by jet-nebulizer spray pyrolysis technique[J]. CrystEngComm, 2015, 17:2624-2628. doi: 10.1039/C5CE00177C
[30]	GAO X, LIU X X, ZHU Z M, et al. Enhanced visible light photocatalytic performance of CdS sensitized TiO₂ nanorod arrays decorated with Au nanoparticles as electron sinks[J]. Scientific Reports, 2017, 7.Doi: 10.1038/s41598-017-01124-5. doi: 10.1038/s41598-017-01124-5
[31]	NAKAYAMA K, HIRAGA T, ZHU C Y, et al. Facile preparation of self-healing superhydrophobic CeO₂ surface by electrochemical processes[J]. Applied Surface Science, 2017, 423:968-976. doi: 10.1016/j.apsusc.2017.07.012
[32]	BARRECA D, GRI F, GASPAROTTO A, et al. Multi-functional MnO₂ nanomaterials for photoactivated applications by a plasmaassisted fabrication route[J]. Nanoscale, 2019, 11:98-108. doi: 10.1039/C8NR06468G
[33]	HANAEI H, ASSADI M K, SAIDUR R. Highly efficient antireflective and self-cleaning coatings that incorporate carbon nanotubes(CNTs) into solar cells:A review[J]. Renewable and Sustainable Energy Reviews, 2016, 59:620-635. doi: 10.1016/j.rser.2016.01.017
[34]	李建生, 于韶梅, 王欣, 等. 石墨烯制备中的无机氧化剂和无机还原剂[J]. 无机盐工业, 2020, 52(8):6-10.
[35]	李鹏. 技术创新推动光伏行业变革[J]. 太阳能, 2018(4):73-74.
[36]	王子韩. 一种高效自清洁石墨烯涂层太阳能光伏组件及制造方法:中国,104916711B[P]. 2017-07-28.
[37]	孙立涛, 毕恒昌, 万树. 一种制备超疏水、耐磨、导电且具有自清洁功能膜的方法:中国,105482136B[P]. 2017-12-22.
[38]	杨欣, 崔淑杰, 王玉琪, 等. 一种光伏玻璃用功能涂层的制备方法:中国,112374767A[P]. 2021-02-19.
[39]	祖晓冬, 李青超, 李建生, 等. 一种石墨烯掺杂自清洁玻璃镀膜液的制备方法：中国,109385122A[P]2019-02-26.
[40]	王欣, 李仕增, 李建生, 等. 一种石墨烯掺杂玻璃镀膜液及其制备方法：中国,109206017A[P]2019-01-15.
[41]	凡甜甜, 郭燕云, 张发荣, 等. 一种石墨烯改性太阳能电池自清洁减反射玻璃:中国,202110764584X[P]. 2021-07-07.
[42]	祖晓冬, 张发荣, 郭燕云, 等. 一种石墨烯基超疏水自清洁玻璃的制备方法:中国,2021109507505[P]. 2021-08-18.
[43]	POSA V R, ANNAVARAM V, KODURU J R, et al. Preparation of graphene-TiO₂ nanocomposite and photocatalytic degradation of Rhodamine-B under solar light irradiation[J]. J.Exp.Nanosci., 2016, 11:722-736.
[44]	ZABIHI F, YAZDI M R A, ESLAMIAN M. Photocatalytic grapheneTiO₂ thin films fabricated by low-temperature ultrasonic vibrationassisted spin and spray coating in a sol-gel process[J]. Catalysts, 2017, 7.Doi: 10.3390/catal7050136. doi: 10.3390/catal7050136
[45]	VALLEJO W, RUEDA A, URIBE C D. Photocatalytic activity of graphene oxide-TiO₂ thin films sensitized by natural dyes extracted from bactris guineensis[J]. Royal Society Open Science, 2019, 3. Doi: 10.1098/rsos.181824. doi: 10.1098/rsos.181824
[46]	NGUYEN D K V, NGUYEN K D V. Magnetite nanoparticles-TiO₂ nanoparticles-graphene oxide nanocomposite:Synjournal,characterization and photocatalytic degradation for Rhodamine-B dye[J]. AIMS Materials Science, 2020, 7(3):288-301. doi: 10.3934/matersci.2020.3.288
[47]	TIMOUMI A. Reduction band gap energy of TiO₂ assembled with graphene oxide nanosheets[J]. Graphene, 2018, 7:31-38. doi: 10.4236/graphene.2018.74004
[48]	PARK J. Photocatalytic performance of graphene-TiO₂ hybrid nanomaterials under visible light[J]. Korean Inst.Electr.Electron.Mater.Eng.March, 2019, 32(2):161-164.
[49]	DIAA M, HASSABO A G. Self-cleaning properties of cellulosic fabrics:A review[J]. Biointerface Research in Applied Chemistry, 2022, 12(2):1847-1855. doi: 10.33263/BRIAC122.18471855
[50]	WANG P, YAO T, SUN B, et al. A cost-effective method for preparing mechanically stable anti-corrosive superhydrophobic coating based on electrochemically exfoliated graphene[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2017.Doi: 10.1016/j.colsurfa.2016.11.002. doi: 10.1016/j.colsurfa.2016.11.002

材料	制备方法	禁带宽度/eV	自清洁机制	应用
WO₃^[24]	电沉积Al-W合金,化学溶解铝,表面热处理形成WO₃膜层	2.7	光催化	降解有机物
TiO₂/ZrO₂^[25]	溶胶-凝胶法	ZrO₂：5.0	光催化、亲水性	降解有机物、防尘
ZnS^[26]	自发明方法：一锅法	3.6	光催化	降解有机物
ZnO/SnO₂^[27]	溶胶-凝胶法	SnO₂：3.5	光催化、超亲水性	降解有机物、防尘、防雾
TiO₂/Fe₂O₃^[28]	溶胶-凝胶法	Fe₂O₃：2.2	光催化、亲水性	降解有机物、防尘
CuO^[29]	喷雾热解技术	1.7	超疏水性	防尘
TiO₂/CdS/Au^[30]	—	CdS：2.4	光催化	降解有机物
CeO₂^[31]	溶胶-凝胶法	2.94	超疏水性、亲油性	油水分离
MnO₂^[32]	等离子体增强化学气相沉积	0.25	光致亲水、固相光催化	防雾、自清洁及水净化

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Research progress on self-cleaning film materials

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 3

References 50

Related Articles 15

Metrics

Comments

Recommended 0

[1]	LI Bo, LIAO Bihai. Preparation of functionalized graphene oxide and its application in portland cement [J]. Inorganic Chemicals Industry, 2023, 55(6): 57-62.
[2]	DENG Changhong. Preparation of nano silica microemulsion and its water control performance [J]. Inorganic Chemicals Industry, 2023, 55(5): 71-77.
[3]	ZHAO Liping, WANG Fei. Effect of amine-functionalized graphene oxide on mechanical properties of cement composites [J]. Inorganic Chemicals Industry, 2023, 55(3): 66-70.
[4]	CUI Xiangmei, PAN Tongtong, LUO Qinglong, BIAN Fuxuan, YE Xiushen. Preparation of amino alcohol modified GO/CNTs composite aerogel and boron adsorption from salt lake brines [J]. Inorganic Chemicals Industry, 2023, 55(12): 59-65.
[5]	DU Changqing, WANG Zhangxuan, TONG Teng, LIU Xiaofan, LIU Liang. Study on dispersion of silica fume/graphene oxide in hardened cement paste [J]. Inorganic Chemicals Industry, 2023, 55(11): 115-120.
[6]	MA Caifu,YUAN Chuanlai,ZHAO Xueqi. Effect of ball milling time on electrochemical properties of graphene composites [J]. Inorganic Chemicals Industry, 2022, 54(12): 68-73.
[7]	Su Chi,Zhang Chenglei. Research progress of graphene and derived oil removal materials [J]. Inorganic Chemicals Industry, 2021, 53(7): 30-35.
[8]	SUN Yaoyao,SONG Jiale,ZHENG Bin,LI Weiguang. Research progress of graphene anticorrosive coating [J]. Inorganic Chemicals Industry, 2021, 53(11): 30-35.
[9]	Bai Lu,Wang Min,Yang Hongjun,Peng Zhengjun,Zhao Youjing,Li Zhilu. Research progress of graphene oxide modified polyamide membrane [J]. Inorganic Chemicals Industry, 2021, 53(10): 15-21.
[10]	Guo Xin,Yi Hualei,Yuan Weiliang,Hao Yun,Duan Cuijia,Chen Zan. Study on preparation of GO-TSC/polyimide mixed matrix membrane and its gas separation performance [J]. Inorganic Chemicals Industry, 2021, 53(10): 74-80.
[11]	Li Jiansheng,Yu Shaomei,Wang Xin,Zu Xiaodong,Liu Bingguang. Inorganic oxidizer and reducing agent used in preparation of graphene [J]. Inorganic Chemicals Industry, 2020, 52(8): 6-10.
[12]	Huang Zhenxu,He Huanhuan,Jia Panpan,Chen Tiwei,Wei Shiqian. Synthesis of graphene by hydrothermal method and its electrocatalytic property on ascorbic acid [J]. Inorganic Chemicals Industry, 2020, 52(11): 29-32.
[13]	Du Miao,Zhang Xin. Progress in application research of two-dimensional nanomaterials in water treatment [J]. Inorganic Chemicals Industry, 2020, 52(1): 17-21.
[14]	Du Miao,Zhang Guangrong. Progress in preparation and application of graphene [J]. Inorganic Chemicals Industry, 2019, 51(3): 12-15.
[15]	Li Shuwen，Zhou Yan，Wang Tielin. Study on preparation and photocatalysis reduction for CO2 of BiVO4/rGO composite [J]. Inorganic Chemicals Industry, 2019, 51(11): 82-87.