石墨烯防腐涂层研究进展

doi:10.19964/j.issn.1006-4990.2020-0633

Abstract

Abstract:

Graphene is currently known as a new type of carbon materials with two-dimensional layered structure with thin thickness,high hardness and strength.It has excellent chemical inertness,antioxidant capacity and barrier performance.Aim-ing at the application of graphene in the field of marine organic anti-corrosion coatings,the anti-corrosion mechanism of grapheme was summarized,mainly including shielding,corrosion inhibition,reinforcement and cathodic protection.The problems of graphene in coating application,such as easy agglomeration,difficult alignment and defects in its structure were pointed out.The corresponding modification methods were proposed and the improvement effect had been evaluated.Finally,the development directions for anti-corrosive graphene coatings in multi-function,intelligent and environmental friendly were prospected.

Key words: graphene, anti-corrosion, coating, metal corrosion

CLC Number:

TQ127.1

SUN Yaoyao,SONG Jiale,ZHENG Bin,LI Weiguang. Research progress of graphene anticorrosive coating[J]. Inorganic Chemicals Industry, 2021, 53(11): 30-35.

Figures/Tables 2

References 43

[1]	吴敢敢. 石墨烯（石墨纳米片）/环氧树脂船用涂料防腐性能的研究[D]. 哈尔滨:哈尔滨工业大学, 2015.
[2]	王博, 魏世丞, 黄威, 等. 海洋防腐蚀涂料的发展现状及进展简述[J]. 材料保护, 2019, 52(11):132-138.
[3]	叶春波. 金属腐蚀严重,水性环氧防腐涂料成趋势[J]. 石油化工腐蚀与防护, 2017, 34(1):29.
[4]	SHENG Q, SILVERIRA K C D, TIAN W, et al. Simultaneous hydrate and corrosion inhibition with modified poly(vinyl caprolactam) po-lymers[J]. Energy & Fuels, 2017, 31(7):6724-6731. doi: 10.1021/acs.energyfuels.7b00525
[5]	崔明君, 任思明, 王永刚, 等. 石墨烯基防腐涂层研究进展[J]. 表面技术, 2019, 48(6):46-55.
[6]	CHEN S, BROWN L, LEVENDORF M, et al. Oxidation resistance of graphene-coated Cu and Cu/Ni alloy[J]. ACS Nano, 2011, 5(2):1321-1327. doi: 10.1021/nn103028d
[7]	吕心顶. 改性二氧化锆/环氧树脂复合涂层的制备与防腐性能研究[D]. 北京:北京化工大学, 2019.
[8]	SUN W, WANG L, WU T, et al. Inhibited corrosion-promotion acti-vity of graphene encapsulated in nanosized silicon oxide[J]. Journal of materials chemistry.A:Materials for energy and sustainability, 2015, 3(32):16843-16848.
[9]	QIU S H, CHEN C, ZHENG W R, et al. Long-term corrosion protec-tion of mild steel by epoxy coating containing self-doped polyaniline nanofiber[J]. Synthetic Metals, 2017, 229:39-46. doi: 10.1016/j.synthmet.2017.05.004
[10]	LI X, BANDYOPADHYAY P, GUO M, et al. Enhanced gas barrier and anticorrosion performance of boric acid induced cross-linked poly(vinyl alcohol-co-ethylene)/graphene oxide film[J]. Carbon, 2018, 133:150-161. doi: 10.1016/j.carbon.2018.03.036
[11]	关迎东, 候晓燕, 孙春龙. 石墨烯——锌粉长效防腐涂料的研制[J]. 电镀与涂饰, 2017, 36(14):725-730.
[12]	SCHRIVER M, REGAN W, GANNETT W J, et al. Graphene as a long-term metal oxidation barrier:Worse than nothing[J]. ACS Nano, 2013, 7(7):5763-5768. doi: 10.1021/nn4014356
[13]	RAJITHA K, MOHANA K N S. Synjournal of graphene oxide-based nanofillers and their influence on the anticorrosion performance of epoxy coating in saline medium[J]. Diamond and Related Materi-ials, 2020, 108.Doi: 10.1016/j.diamond.2020.107974. doi: 10.1016/j.diamond.2020.107974
[14]	LIN Y T, DON T M, WONG C J, et al. Improvement of mechanical properties and anticorrosion performance of epoxy coatings by the introduction of polyaniline/graphene composite[J]. Surface and Coatings Technology, 2019, 374:1128-1138. doi: 10.1016/j.surfcoat.2018.01.050
[15]	CHEN C, QIU S H, CUI M J, et al. Achieving high performance co-rrosion and wear resistant epoxy coatings via incorporation of no-ncovalent functionalized graphene[J]. Carbon, 2017, 114:356-366. doi: 10.1016/j.carbon.2016.12.044
[16]	陶俊杰, 王凌云, 董佳豪, 等. 植酸改性石墨烯的制备及其在防腐涂层中的应用[J]. 涂料工业, 2020, 50(2):14-21.
[17]	RAMEZANZADEH B, ATTAR M M. An evaluation of the corrosion resistance and adhesion properties of an epoxy-nanocomposite on a hot-dip galvanized steel(HDG) treated by different kinds of co-nversion coatings[J]. Surface and Coatings Technology, 2011, 205(19):4649-4657. doi: 10.1016/j.surfcoat.2011.04.001
[18]	ALINEJAD S, NADERI R, MAHDAVIAN M. The effect of zinc ca-tion on the anticorrosion behavior of an eco-friendly silane sol-gel coating applied on mild steel[J]. Progress in Organic Coatings, 2016, 101:142-148. doi: 10.1016/j.porgcoat.2016.08.005
[19]	PARHIZKAR N, SHAHRRABI T, RAMEZANZADEH B. A new approach for enhancement of the corrosion protection properties and interfacial adhesion bonds between the epoxy coating and steel substrate through surface treatment by covalently modified amino functionalized graphene oxide film[J]. Corrosion Science, 2017, 123:55-75. doi: 10.1016/j.corsci.2017.04.011
[20]	朱相苗, 倪忠斌, 刘士荣, 等. 石墨烯富锌涂料的制备及其防腐蚀性能[J]. 材料保护, 2019, 52(1):78-82.
[21]	刘茜, 金少波, 王震宇, 等. 石墨烯改性涂层防护性能研究[J]. 涂料工业, 2020, 50(4):14-18.
[22]	LIU S, GU L, ZHAO H, et al. Corrosion resistance of graphene-rein-forced waterborne epoxy coatings[J]. Journal of Materials Science & Technology, 2016, 32(5):425-431.
[23]	DONG R, LIU L. Preparation and properties of acrylic resin coating modified by functional graphene oxide[J]. Applied Surface Scien-ce, 2016, 368(15):378-387.
[24]	WANG H H, HE Y, FEI G Q, et al. Functionalizing graphene with titanate coupling agents as reinforcement for one-component water-borne poly(urethane-acrylate) anticorrosion coatings[J]. Chemical Engineering Journal, 2019, 359:331-343. doi: 10.1016/j.cej.2018.11.133
[25]	YU Z X, DI H H, MA Y, et al. Fabrication of graphene oxide-alumi-na hybrids to reinforce the anti-corrosion performance of composite epoxy coatings[J]. Applied Surface Science, 2015, 351:986-996. doi: 10.1016/j.apsusc.2015.06.026
[26]	YE Y W, ZHANG D W, LIU T, et al. Improvement of anticorrosion ability of epoxy matrix in simulate marine environment by filled with superhydrophobic POSS-GO nanosheets[J]. Journal of Hazardous Materials, 2019, 364(15):244-255. doi: 10.1016/j.jhazmat.2018.10.040
[27]	ZHU G Y, CUI X K, ZHANG Y, et al. Poly (vinyl butyral)/Graphe-ne oxide/poly(methylhydrosiloxane) nanocomposite coating for improved aluminum alloy anticorrosion[J]. Polymer, 2019, 172:415-422. doi: 10.1016/j.polymer.2019.03.056
[28]	李爽, 张双红, 杨波, 等. 石墨烯在复合防腐涂层中的应用研究进展[J]. 中国塑料, 2018, 32(12):1-9.
[29]	丁锐, 陈思, 吕静, 等. 石墨烯在有机防腐涂层中的分散性、定向化、功能化和导电性研究与现实问题[J]. 涂料工业, 2019, 49(9):66-80.
[30]	DING R, CHEN S, LV J, et al. Study on graphene modified organic anti-corrosion coatings:A comprehensive review[J]. Journal of Al-loys and Compounds, 2019, 806:611-635.
[31]	ZHOU J, WANG Q, SUN Q, et al. Ferromagnetism in semihydro-genated graphene sheet[J]. Nano Lett, 2009, 9(11):3867-3870. doi: 10.1021/nl9020733
[32]	WEI T, WEN X, WU D, et al. One-step hydrothermal synjournal of magnetic nitrogen-doped graphene for magnetic solid-phase extrac tion of nonsteroidal anti-inflammatory drugs in environmental water samples[J]. Journal of Separation Science, 2020, 43(15):3110-3119. doi: 10.1002/jssc.v43.15
[33]	LANGER R, BLONSKI P, HOFER C, et al. Tailoring electronic and magnetic properties of graphene by phosphorus doping[J]. ACS Applied Materials & Interfaces, 2020, 12(30):34074-34085.
[34]	安浩然. 氟掺杂石墨烯的制备及其电化学性能研究[D]. 天津:天津大学, 2017.
[35]	HAN T W, LUO Y, WANG C Y. Effects of SI,N and B doping on the mechanical properties of graphene sheets[J]. Acta Mechanica Solida Sinica, 2015, 28(6):618-625. doi: 10.1016/S0894-9166(16)30003-9
[36]	REN S M, CUI M J, LI W S, et al. N-doping of graphene:Toward long-term corrosion protection of Cu[J]. Journal of materials chemi-stry A, 2018, 6(47) :24136-24148.
[37]	DING J H, ZHAO H R, JI D, et al. Achieving long-term anticorro-sion via the inhibition of graphene′s electrical activity[J]. Journal of materials chemistry A, 2019, 7(6):2864-2874. doi: 10.1039/C8TA10337B
[38]	RENTERIA J, LEGEDZA S, SALGADO R, et al. Magnetically-func-tionalized self-aligning graphene fillers for high-efficiency thermal management applications[J]. Materials & Design, 2015, 88(25):214-221.
[39]	CHHETRI S, GHOSH S, SAMANTA P, et al. Effect of Fe₃O₄-deco-rated N-doped reduced graphene oxide nanohybrid on the antico-rrosion performance of epoxy composite coating[J]. Chemistry Se-lect(Weinheim), 2019, 4(46):13446-13454.
[40]	ZHANG D, CUI X F, JIN G, et al. Preparation,deposited behavior and hydrophobic property of modified graphene oxide reinforced Ni composite coatings by magnetic field assisted electro-brush plating[J]. Surface and Coatings Technology, 2020, 403.Doi: 10.1016/j.surfcoat.2020.126363. doi: 10.1016/j.surfcoat.2020.126363
[41]	QI K, SUN Y M, DUAN H W, et al. A corrosion-protective coating based on a solution-processable polymer-grafted graphene oxide nanocomposite[J]. Corrosion Science, 2015, 98:500-506. doi: 10.1016/j.corsci.2015.05.056
[42]	SHEN L, LI Y, ZHAO W J, et al. Tuning F-doped degree of rGO:Restraining corrosion-promotion activity of EP/rGO nanocompos-ite coating[J]. Journal of Materials Science & Technology, 2020, 44(9):123-134.
[43]	王军, 姜天明. 石墨烯防腐涂料的特点及在海洋防腐领域的应用前景[J]. 现代涂料与涂装, 2019, 22(4):17-20.

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Research progress of graphene anticorrosive coating

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