无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (3): 41-.

• 论文 • 上一篇    下一篇

锂云母硫酸盐法提锂研究

郭春平,周 健,文小强,普 建,王玉香,袁德林   

  1. 赣州有色冶金研究所,江西赣州 341000
  • 出版日期:2014-03-10 发布日期:2014-03-07

Extraction of lithium from lepidolite by sulfate process

GUO  Chun-Ping, ZHOU   Jian, WEN  Xiao-Qiang, PU   Jian, WANG  Yu-Xiang, YUAN  De-Lin   

  1. Ganzhou Nonferrous Metallurgy Research Institute,Ganzhou 341000,China
  • Online:2014-03-10 Published:2014-03-07

摘要: 江西宜春锂云母矿与一定量的经改进种类和比例的硫酸盐均混,高温焙烧一定时间,粉碎后稀酸浸出过滤,得到含锂硫酸盐溶液。检测溶液及浸出渣中氧化锂含量,计算氧化锂浸出率。实验结果表明,以硫酸钾、硫酸钙作为硫酸盐混合物,在锂云母与硫酸盐质量比为1∶ 0.45、焙烧温度为900 ℃,焙烧时间为1 h条件下,氧化锂的浸出率可高达95%左右。

关键词: 硫酸盐, 锂云母, 提取, 锂, 焙烧

Abstract: Lepidolite from Yichun,Jiangxi was calcinated by uniformly mixing with improved sulfates(several different kinds of sulfate mixed in a fixed proportion) to extract lithium.After calcination,crashing,leaching with dilute  acid solution and filtration,lithium-containing sulfate solution was obtained.Lithium contents from the leached solution and the leached residue were detected respectively,and the leaching rate of lithium oxide was calculated.Results showed that the extraction rate could be as high as about 95% when taking potassium sulfate and calcium sulfate as the sulfate mixture and under such conditions as mass ratio of lepidolite to sulfates of 1∶ 0.45,calcination temperature of 900 ℃,and calcination time of 1 h.

Key words: sulfate;lepidolite;leaching;lithium;calcination 

中图分类号: