无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (2): 60-.

• 论文 • 上一篇    

氧化铜作锂离子电池负极材料的制备及性能研究

李 菁,张 颖,韩恩山,杜奉娟   

  1. 河北工业大学化工学院,天津 300130
  • 出版日期:2013-02-10 发布日期:2013-02-21

Preparation and performance of copper oxide as anode materials for lithium-ion batteries

 LI   Jing, ZHANG   Ying, HAN  En-Shan, DU  Feng-Juan   

  1. School of Chemical Engineering and Technology,Hebei University of Technology,Tianjin 300130,China
  • Online:2013-02-10 Published:2013-02-21

摘要: 以Cu(NO32·3H2O和氢氧化钠为原料,通过水热法制备氧化铜样品。采用X射线衍射法对其进行物相结构的表征。针对pH、反应时间和反应体系浓度等反应条件,对氧化铜样品的物相结构和电化学性能的影响进行了讨论。结果表明,采用该方法制备的氧化铜负极材料在0.1 C(67 mA/g)电流密度下首次充放电容量分别为406.5 mA·h/g和867.4 mA·h/g,在大倍率循环下具有较高的容量保持率。

关键词: 氧化铜, 水热法, 锂离子电池, 负极

Abstract: The copper oxide(CuO) samples were prepared by hydrothermal synthesis method,with Cu(NO32·3H2O and NaOH as raw materials. X-ray diffraction was employed to characterize the structure of the CuO samples. Influences of pH, reaction time,and concentration of reactants on the structure and electrochemical performance of CuO were also discussed. Results showed that the initial charge and discharge specific capacity of the prepared CuO anode materials were 406.5 mA·h/g and 867.4 mA·h/g at 0.1 C(67 mA/g) respectively,and showed good capacity retention during high rate cycles. 

Key words: copper oxide, hydrothermal synthesis, lithium-ion batteries, anode

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