无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (2): 56-.

• 论文 • 上一篇    下一篇

Co(OH)2/MWCNTs复合物的室温 固相合成及其电容性能

刘晓红,龚良玉,姚文红,孔祥平   

  1. 青岛农业大学化学与药学院,山东青岛266109
  • 出版日期:2013-02-10 发布日期:2013-02-21

Solid-state synthesis of Co(OH)2/MWCNTs composite at room temperature and capacitive performance thereof

 LIU  Xiao-Hong, GONG  Liang-Yu, YAO  Wen-Hong, KONG  Xiang-Ping   

  1. School of Chemistry & Pharmaceutical Science,Qingdao Agricultural University,Qingdao 266109,China
  • Published:2013-02-10 Online:2013-02-21

摘要: 采用室温固相反应法制备了Co(OH)2/MWCNTs复合物。借助XRD、FT-IR以及SEM对产物的晶形、组成及形貌进行了表征。结果表明,所得复合物中β-Co(OH)2 颗粒较好地覆盖于MWCNTs的表面。电化学测试结果表 明,复合物的比容量和循环性能均得到有效改善,MWCNTs的质量分数为10%时,充放电至200次时其比容量可达385 F/g并逐趋恒定,1 000次后其比容量增加了8%,达到415 F/g,表现出良好的循环稳定性。

关键词: 室温固相反应法, Co(OH)2/MWCNTs复合物, 电化学电容

Abstract: Co(OH)2/MWCNTs composite was prepared by room-temperature solid-state reaction method.The product′s crystal shape,composition,and morphology were characterized by XRD,FT-IR,and SEM.Results indicated that β-Co(OH)2 parti- cles prepared by solid-state reaction were uniformly coated on multi-walled carbon nanotubes(MWCNTs).Electrochemical tests showed that both the specific capacitance and cycle performance of the obtained composite were effectively improved.The specific capacitance became constant gradually and a high number of 385 F/g could be obtained for the Co(OH)2/MWCNTs composite with the MWCNTs mass fraction of 10% after 200 charge-discharge cycles.The capacitance increased by about 8% after 1 000 cycles,that was,415 F/g could be achieved,showing its excellent cyclic stability.

Key words: room-temperature solid-state reaction, Co(OH)2/MWCNTs composite, electrochemical capacitance

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