生物质衍生物重整制氢研究进展

doi:10.19964/j.issn.1006-4990.2020-0553

摘要/Abstract

摘要：

氢能是公认的较为理想的绿色能源,开发利用氢能不仅能摆脱对传统化石能源的长期依赖,还能解决能源短缺及环境污染问题,低成本且高效环保地制取氢气有利于中国能源结构转变与可持续发展战略的实施,其中利用可再生生物质衍生物重整制氢技术越来越受到人们的关注。从化学与能源角度出发,综述和评论了国内外以生物醇类、苯酚类、酸类三大主要生物质衍生物为原料重整制氢的研究,分析了这些生物质衍生物重整制氢的反应机理,集中阐述了催化剂和载体对重整制氢的作用效果,以及催化体系所面临的问题及改进办法。结合目前制氢发展着重于催化剂改性、载体优化、工艺改进等方面的研究趋势,提出未来可深入开发新型载体和助剂、丰富催化剂体系、整合各种制氢工艺的研究方向。

关键词: 氢能, 生物质, 重整制氢, 催化剂

Abstract:

Hydrogen energy is recognized as an ideal green energy.The development and utilization of hydrogen energy can not only get rid of the long-term dependence on traditional fossil energy,but also solve the problems of energy shortage and environmental pollution.The low-cost,efficient and environmentally friendly production of hydrogen is conducive to the im-plementation of China′s energy structure transformation and sustainable development strategy.Among them,the use of renew-able biomass-derived compounds for hydrogen production has attracted more and more attention.From the perspective of chemistry and energy,the research on hydrogen production by reforming with the three major biomass-derived compounds of bio-alcohols,phenols and acids as raw materials at home and abroad was reviewed and commented,the reaction mechanism of hydrogen production from the reforming of these biomass-derived compounds was analyzed,and the effect of catalysts and carriers on hydrogen production from the reforming and the problems faced by the catalytic system and the improvement methods were centrally elaborated.In view of the current research trend of hydrogen production,which focused on catalyst modification,carrier optimization and process improvement,the future research direction of developing new carriers and additives,enriching catalyst systems and integrating various hydrogen production processes were proposed.

Key words: hydrogen energy, biomass, reforming for hydrogen production, catalyst

中图分类号:

O643.36

李亮荣,付兵,刘艳,孙戊辰. 生物质衍生物重整制氢研究进展[J]. 无机盐工业, 2021, 53(9): 12-17.

Li Liangrong,Fu Bing,Liu Yan,Sun Wuchen. Research progress of hydrogen production by reforming biomass-derived compounds[J]. Inorganic Chemicals Industry, 2021, 53(9): 12-17.

参考文献 28

[1]	孙海杰, 陈凌霞, 张玉凤, 等. 钴-硼/二氧化锆催化剂催化硼氢化钠水解制氢研究[J]. 无机盐工业, 2019, 51(3):72-76.
[2]	孙海杰, 陈志浩, 陈凌霞, 等. 自搅拌下CoB/SiO₂催化剂催化硼氢化钠水解制氢研究[J]. 无机盐工业, 2020, 52(3):101-106.
[3]	李婉晴. 乙二醇水相重整制氢催化剂制备及反应特性研究[D]. 天津:天津大学, 2016.
[4]	杨浩. 乙酸自热重整制氢的锌系镍基催化剂的研究[D]. 四川:成都理工大学, 2018.
[5]	江涛, 陈诗诗, 曹发海. 生物质多元醇水相重整制氢研究进展[J]. 化工进展, 2012, 31(5):1010-1017.
[6]	杨淑倩, 贺建平, 张娜, 等. 稀土掺杂改性对Cu/ZnAl水滑石衍生催化剂甲醇水蒸气重整制氢性能的影响[J]. 燃料化学学报, 2018, 46(2):179-188.
[7]	杨淑倩, 张娜, 贺建平, 等. Ce的浸渍顺序对Cu/Zn-Al水滑石衍生催化剂用于甲醇水蒸气重整制氢性能的影响[J]. 燃料化学学报, 2018, 46(4):479-488.
[8]	Liu Di, Men Yong, Wang Jinguo, et al. Highly active and durable Pt/In₂O₃/Al₂O₃ catalysts in methanol steam reforming[J]. International Journal of Hydrogen Energy, 2016, 41(47):21990-21999. doi: 10.1016/j.ijhydene.2016.08.184
[9]	Nielsen M, Alberico E, Baumann W, et al. Low-temperature aque-ous-phase methanol dehydrogenation to hydrogen and carbon dio-xide[J]. Nature, 2013, 495:85-89. doi: 10.1038/nature11891
[10]	Lin Lili, Zhou Wu, Gao Rui, et al. Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts[J]. Nature, 2017, 544:80-83. doi: 10.1038/nature21672
[11]	郭芳林. 反应与吸附耦合的乙醇水蒸气重整制氢[D]. 北京:北京化工大学, 2008.
[12]	杨欢, 何素芳, 王云珠, 等. Ni-CaO-La₂O₃催化剂在乙醇水蒸气重整制氢中的应用[J]. 石油化工, 2020, 49(2):107-112.
[13]	李亮荣, 丁永红, 王飞, 等. 乙醇水蒸气重整制氢双金属催化剂Ni-Co/La₂O₂CO₃的研究[J]. 应用化工, 2013, 42(5):866-869.
[14]	Zhang Xiaosong, Jin Hongguang. Thermodynamic analysis of che-mical-looping hydrogen generation[J]. Applied Energy, 2013, 112:800-807. doi: 10.1016/j.apenergy.2013.02.058
[15]	Isarapakdeetham S, Kim-Lohsoontorn P, Wongsakulphasatch S, et al. Hydrogen production via chemical looping steam reforming of ethanol by Ni-based oxygen carriers supported on CeO₂ and La₂O₃ promoted Al₂O₃[J]. International Journal of Hydrogen Energy, 2020, 45(3):1477-1491. doi: 10.1016/j.ijhydene.2019.11.077
[16]	王瑞义, 刘欢, 郑占丰, 等. 低温下Pt/Al₂O₃和 Pd/Al₂O₃光辅助乙二醇水相重整制氢研究[J]. 燃料化学学报, 2019, 47(12):1486-1494.
[17]	Kim H D, Park H J, Kim T W, et al. Hydrogen production through the aqueous phase reforming of ethylene glycol over supported Pt-based bimetallic catalysts[J]. International Journal of Hydrogen Energy, 2012, 37(10):8310-8317. doi: 10.1016/j.ijhydene.2012.02.160
[18]	Zhang Jianguang, Xu Ningge. Hydrogen production from ethylene glycol aqueous phase reforming over Ni-Al layered hydrotalcite-derived catalysts[J]. Catalysts, 2020, 10(1):54. doi: 10.3390/catal10010054
[19]	Chen Dong, Wang Wenju, Liu Chenlong. Hydrogen production through glycerol steam reforming over beehive-biomimetic graphene-encapsulated nickel catalysts[J]. Renewable Energy, 2020, 145:2647-2657. doi: 10.1016/j.renene.2019.08.022
[20]	Suffredini D F P, Thyssen V V, de Almeida P M M, et al. Renewable hydrogen from glycerol reforming over nickel aluminate-based catalysts[J]. Catalysis Today, 2017, 289:96-104. doi: 10.1016/j.cattod.2016.07.027
[21]	Ni Ying, Wang Chao, Chen Ying, et al. High purity hydrogen production from sorption enhanced chemical looping glycerol reforming:Application of NiO-based oxygen transfer materials and potassium promoted Li₂ZrO₃ as CO₂ sorbent[J]. Applied Thermal Engineering, 2017, 124:454-465. doi: 10.1016/j.applthermaleng.2017.06.003
[22]	贺仪平, 邓梦婷, 朱阁, 等. 双功能钙基催化剂催化苯酚重整制氢实验研究[J]. 环境科学与技术, 2019, 42(8):40-46.
[23]	Abbas T, Tahir M, Saidina Amin N A. Enhanced metal-support interaction in Ni/Co₃O₄/TiO₂ nanorods toward stable and dynamic hydrogen production from phenol steam reforming[J]. Industrial & Engineering Chemistry Research, 2018, 58(2):517-530. doi: 10.1021/acs.iecr.8b03542
[24]	Liu Chenlong, Chen Dong, Cao Yongan, et al. Catalytic steam reforming of in-situ tar from rice husk over MCM-41 supported LaNiO₃ to produce hydrogen rich syngas[J]. Renewable Energy, 2020, 161:408-418. doi: 10.1016/j.renene.2020.07.089
[25]	Choi I H, Hwang K R, Lee K Y, et al. Catalytic steam reforming of biomass-derived acetic acid over modified Ni/γ-Al₂O₃ for sustainable hydrogen production[J]. International Journal of Hydrogen Energy, 2019, 44(1):180-190. doi: 10.1016/j.ijhydene.2018.04.192
[26]	Zhou Qing, Zhong Xinyan, Xie Xingyue, et al. Auto-thermal reforming of acetic acid for hydrogen production by ordered mesoporous Ni-xSm-Al-O catalysts:Effect of samarium promotion[J]. Renewable Energy, 2020, 145:2316-2326. doi: 10.1016/j.renene.2019.07.078
[27]	杨浩, 李辉谷, 谢星月, 等. 乙酸自热重整制氢用类水滑石衍生Zn-Ni-Al-Fe-O催化剂研究[J]. 燃料化学学报, 2018, 46(11):1352-1358.
[28]	Kumar A, Sinha A S K. Comparative study of hydrogen production from steam reforming of acetic acid over synthesized catalysts via MOF and wet impregnation methods[J]. International Journal of Hydrogen Energy, 2020, 45(20):11512-11526. doi: 10.1016/j.ijhydene.2020.02.097

首页

全国无机盐信息中心

中国化工学会

无机酸碱盐专业委员会