异质结构碳材料的金属空气电池应用研究进展

doi:10.19964/j.issn.1006-4990.2021-0235

摘要/Abstract

摘要：

金属空气电池在可穿戴电子产品和能源储存领域中具有巨大的应用潜力,然而稳定性差和能量效率低的问题限制其性能的进一步提高。电化学氧还原反应（ORR）和氧析出反应（OER）对于金属空气电池的性能起着至关重要的作用。发展催化活性高、稳定性好的空气电极催化剂是未来的研究趋势。碳材料因具有导电性优异、结构多样等优势已被广泛用作金属空气电池的导电骨架支撑材料和电催化材料,成为研究的热点。对非金属原子掺杂碳材料、过渡金属及其衍生物掺杂碳材料以及单原子催化剂作为单功能或双功能催化剂的研究进行综述,着重介绍了其在金属空气电池中的应用,对空气电极催化剂存在的问题进行总结,并对未来的发展方向进行展望。

关键词: 金属空气电池, 碳材料, 异质结构, 空气电极催化剂

Abstract:

Metal-O₂ batteries have great potential in the fields of wearable electronic devices and energy storages.However,poor stability and low energy efficiency limit further improvement in their electrochemical performance.Electrochemical oxy-gen reduction reaction（ORR） and oxygen evolution reaction（OER） play a vital role in the performance of metal-O₂ batteries. The research trend focus on the development of catalysts as electrodes with high catalytic activity and good stability.Carbon materials have been widely used as conductive framework support and electro-catalysts for Metal-O₂ due to their excellent electrical conductivity and diverse structures,which have been become the research hotspot.In this paper,the research of non-metal heteroatomic doped carbon materials,transition metal and its derivatives doped carbon materials,and single-atom cata-lysts as mono-functional or bi-functional catalysts were reviewed.Their application in metal-O₂ batteries were introduced in detail.The existing problems of air-electrode catalyst were summarized,and the future development direction was prospected.

Key words: metal-O₂ battery, carbon materials, hetero-structures, catalysts

中图分类号:

TQ131.11

郝跃辉,成怀刚,钱阿妞. 异质结构碳材料的金属空气电池应用研究进展[J]. 无机盐工业, 2021, 53(6): 23-30.

Hao Yuehui,Cheng Huaigang,Qian Aniu. Research progress of hetero-structured carbon materials for metal-O₂ batteries applications[J]. Inorganic Chemicals Industry, 2021, 53(6): 23-30.

图/表 6

图1

图2

图3

图4

图5

图6

参考文献 54

[1]	Zhou J, Cheng J, Wang B, et al. Flexible metal-gas batteries:A po- tential option for next-generation power accessories for wearable electronics[J]. Energy & Environmental Science, 2020,13(7):1933-1970.
[2]	Lee D U, Xu P, Cano Z P, et al. Recent progress and perspectives on bi-functional oxygen electrocatalysts for advanced rechargeable metal-air batteries[J]. Journal of Materials Chemistry A, 2016,4(19):7107-7134. doi: 10.1039/C6TA00173D
[3]	Shi F, Zhu X, Yang W. Micro-nanostructural designs of bifunctional electrocatalysts for metal-air batteries[J]. Chinese Journal of Catal- ysis, 2020,41(3):390-403.
[4]	Singh S K, Takeyasu K, Nakamura J. Active sites and mechanism of oxygen reduction reaction electrocatalysis on nitrogen-doped carbon materials[J]. Advanced materials, 2019,31(13).Doi: 10.1002/adma. 201804297.
[5]	Yang Z D, Yang X Y, Liu T, et al. In situ CVD derived Co-N-C co- mposite as highly efficient cathode for flexible Li-O₂ batteries[J]. Small, 2018,14(43).Doi: 10.1002/smll.201800590.
[6]	Xu Y, Deng P, Chen G, et al. 2D nitrogen-doped carbon nanotubes/ graphene hybrid as bifunctional oxygen electrocatalyst for long-life rechargeable Zn-air batteries[J]. Advanced Functional Materials, 2019,30(6).Doi: 10.1002/adfm.201906081.
[7]	Zhao Z, Li M, Zhang L, et al. Design principles for heteroatom-doped carbon nanomaterials as highly efficient catalysts for fuel cells and metal-air batteries[J]. Advanced Materials, 2015,27(43):6834-6840. doi: 10.1002/adma.201503211
[8]	Liu J, Song P, Xu W. Structure-activity relationship of doped-nitro- gen(N)-based metal-free active sites on carbon for oxygen reduc- tion reaction[J]. Carbon, 2017,115:763-772. doi: 10.1016/j.carbon.2017.01.080
[9]	Wu F, Xing Y, Li L, et al. Facile synjournal of boron-doped r-GO as cathode material for high nergy Li-O₂ batteries[J]. ACS applied materials & interfaces, 2016,8(36):23635-23645.
[10]	Shu C, Lin Y, Zhang B, et al. Mesoporous boron-doped onion-like carbon as long-life oxygen electrode for sodium-oxygen batteri- es[J]. Journal of Materials Chemistry A, 2016,4(17):6610-6619. doi: 10.1039/C6TA00901H
[11]	Sakaushi K, Fellinger T P, Antonietti M. Bifunctional metal-free catalysis of mesoporous noble carbons for oxygen reduction and vvolution reactions[J]. Chem.Sus.Chem., 2015,8(7):1156-1160. doi: 10.1002/cssc.v8.7
[12]	Zhang Z, Bao J, He C, et al. Hierarchical carbon-nitrogen architec- tures with both mesopores and macrochannels as excellent cathodes for rechargeable Li-O₂ batteries[J]. Advanced Functional Materi- als, 2014,24(43):6826-6833.
[13]	Pendashteh A, Palma J, Anderson M, et al. Doping of self-standing CNT fibers:Promising flexible air-cathodes for high-energy-densi- ty structural Zn-air batteries[J]. ACS Applied Energy Materials, 2018,1(6):2434-2439. doi: 10.1021/acsaem.8b00583
[14]	Li R, Liu F, Zhang Y, et al. Nitrogen,Sulfur Co-doped hierarchically porous carbon as a metal-free electrocatalyst for oxygen reduction and carbon dioxide reduction reaction[J]. ACS Applied Materials & Interfaces, 2020,12(40):44578-44587.
[15]	Chen S, Zhao L, Ma J, et al. Edge-doping modulation of N,P-codo- ped porous carbon spheres for high-performance rechargeable Zn-air batteries[J]. Nano Energy, 2019,60:536-544. doi: 10.1016/j.nanoen.2019.03.084
[16]	Wang J, Wu H, Gao D, et al. High-density iron nanoparticles enca- psulated within nitrogen-doped carbon nanoshell as efficient oxy- gen electrocatalyst for zinc-air battery[J]. Nano Energy, 2015,13:387-396. doi: 10.1016/j.nanoen.2015.02.025
[17]	Chen Z, Wang Q, Zhang X, et al. N-doped defective carbon with trace Co for efficient rechargeable liquid electrolyte-/all-solid-state Zn-air batteries[J]. Science Bulletin, 2018,63(9):548-555. doi: 10.1016/j.scib.2018.04.003
[18]	Burke M S, Kast M G, Trotochaud L, et al. Cobalt-iron(oxy)hydro- xide oxygen evolution electrocatalysts:The role of structure and co- mposition on activity,stability,and mechanism[J]. Journal of the American Chemical Society, 2015,137(10):3638-3648. doi: 10.1021/jacs.5b00281
[19]	Friebel D, Louie M W, Bajdich M, et al. Identification of highly ac- tive Fe sites in(Ni,Fe)OOH for electrocatalytic water splitting[J]. Journal of the American Chemical Society, 2015,137(3):1305-1313. doi: 10.1021/ja511559d
[20]	Li S, Chen W, Pan H, et al. FeCo Alloy nanoparticles coated by an ultrathin N-doped carbon layer and encapsulated in carbon nano- tubes as a highly efficient bifunctional air electrode for rechargea- ble Zn-air batteries[J]. ACS Sustainable Chemistry & Engineer- ing, 2019,7(9):8530-8541.
[21]	Zhao X, Abbas S C, Huang Y, et al. Robust and highly active FeNi@NCNT nanowire arrays as integrated air electrode for flexi- ble solid-state rechargeable Zn-air batteries[J]. Advanced Materials Interfaces, 2018,5(9).Doi: 10.1002/admi.201701448.
[22]	Fu Y, Yu H Y, Jiang C, et al. NiCo alloy nanoparticles decorated on N-doped carbon nanofibers as highly active and durable oxygen electrocatalyst[J]. Advanced Functional Materials, 2018,28(9). Doi: 10.1002/adfm.201705094.
[23]	Han C, Li W, Liu H K, et al. Design strategies for developing non- precious metal based bi-functional catalysts for alkaline electrolyte based zinc-air batteries[J]. Materials Horizons, 2019,6(9):1812-1827. doi: 10.1039/C9MH00502A
[24]	Bag S, Roy K, Gopinath C S, et al. Facile single-step synjournal of nitrogen-doped reduced graphene oxide-Mn₃O₄ hybrid functional material for the electrocatalytic reduction of oxygen[J]. ACS App- lied Materials & Interfaces, 2014,6(4):2692-2699.
[25]	Varga T, Ballai G, Vásárhelyi L, et al. Co₄N/nitrogen-doped grap- hene:A non-noble metal oxygen reduction electrocatalyst for alka- line fuel cells[J]. Applied Catalysis B:Environmental, 2018,237:826-834. doi: 10.1016/j.apcatb.2018.06.054
[26]	Yang W, Liu X, Yue X, et al. Bamboo-like carbon nanotube/Fe₃C nanoparticle hybrids and their highly efficient catalysis for oxygen reduction[J]. Journal of the American Chemical Society, 2015,137(4):1436-1439. doi: 10.1021/ja5129132
[27]	Zhang W, Zhao X, Zhao Y, et al. Mo-doped Zn,Co zeolitic imida- zolate framework-derived Co₉S₈ quantum dots and MoS₂ embedded in three-dimensional nitrogen-doped carbon nanoflake arrays as an efficient trifunctional electrocatalysts for the oxygen reduction reaction,oxygen evolution reaction,and hydrogen evolution reac- tion[J]. ACS Applied Materials & Interfaces, 2020,12(9):10280-10290.
[28]	Prabu M, Ramakrishnan P, Nara H, et al. Zinc-air battery:Underst- anding the structure and morphology changes of graphene-sup- ported CoMn₂O₄ bifunctional catalysts under practical rechargeable conditions[J]. ACS Applied Materials & Interfaces, 2014,6(19):16545-16555.
[29]	Xu J, Chen C, Han Z, et al. Recent advances in oxygen electrocat- alysts based on perovskite oxides[J]. Nanomaterials, 2019,9(8):1161.Doi: 10.3390/nano9081161. doi: 10.3390/nano9081161
[30]	Maiyalagan T, Jarvis K A, Therese S, et al. Spinel-type lithium co- balt oxide as a bifunctional electrocatalyst for the oxygen evolution and oxygen reduction reactions[J]. Nature Communications, 2014,5.Doi: 10.1038/ncomms.4949.
[31]	Fu J, Hassan F M, Li J, et al. Flexible rechargeable zinc-air batteri- es through morphological emulation of human hair array[J]. Adva- nced Materials, 2016,28(30):6421-6428.
[32]	Li B, Chien S W, Ge X, et al. Ni/NiO_x-decorated carbon nanofibers with enhanced oxygen evolution activity for rechargeable zinc-air batteries[J]. Materials Chemistry Frontiers, 2017,1(4):677-682. doi: 10.1039/C6QM00151C
[33]	Shui Z, Liao X, Lei Y, et al. MnO₂ synergized with N/S Co doped graphene as a flexible cathode efficient electrocatalyst for advanc- ed honeycomb-shaped stretchable aluminum-air batteries[J]. Lan- gmuir, 2020,36(43):12954-12962.
[34]	Chen S, Chen S, Zhang B, et al. Bifunctional oxygen electrocatalysis of N,S-Co doped porous carbon with interspersed hollow CoO na- noparticles for rechargeable Zn-air batteries[J]. ACS Applied Ma- terials & Interfaces, 2019,11(18):16720-16728.
[35]	Li C S, Sun Y, Lai W H, et al. Ultrafine Mn₃O₄ nanowires/three-di- mensional graphene/single-walled carbon nanotube composites: Superior electrocatalysts for oxygen reduction and enhanced Mg/air batteries[J]. ACS Applied Materials & Interfaces, 2016,8(41):27710-27719.
[36]	Jiang Y, Cheng J, Zou L, et al. Graphene foam decorated with geria microspheres as a flexible cathode for foldable lithium-air batteri- es[J]. Chem.Cat.Chem., 2017,9(22):4231-4237. doi: 10.1002/cctc.201700942
[37]	Li Y, Zhong C, Liu J, et al. Atomically thin mesoporous Co₃O₄ layers strongly coupled with N-rGO nanosheets as high-performance bi- functional catalysts for 1D knittable zinc-air batteries[J]. Advanc- ed Materials, 2018,30(4).Doi: 10.1002/adma.201703657.
[38]	Guan C, Sumboja A, Wu H, et al. Hollow Co₃O₄ nanosphere embe- dded in carbon arrays for stable and flexible solid-state zinc-air Batteries[J]. Advanced Materials, 2017,29(44).Doi: 10.1002/adma.201704117.
[39]	Athika M, Elumalai P. Porous carbon networks decorated with Co- balt on CoFe₂O₄ as an Air-breathing electrode for high-capacity rechargeable lithium-air batteries:Role of metallic cobalt nano- particles[J]. Chem Electro Chem, 2020,7(20):4188-4200.
[40]	Wei L, Karahan H E, Zhai S, et al. Amorphous bimetallic oxide- graphene hybrids as bifunctional oxygen electrocatalysts for rechar- geable Zn-air batteries[J]. Advanced Materials, 2017,29(38). Doi: 10.1002/adma.201701410.
[41]	Ge X, Goh F W T, Li B, et al. Efficient and durable oxygen reduc- tion and evolution of a hydrothermally synthesized La(Co_0.55Mn_0.45)_0.99O₃-_δ nanorod/graphene hybrid in alkaline me- dia[J]. Nanoscale, 2015,7(19):9046-9054. doi: 10.1039/C5NR01272D
[42]	Prabu M, Ramakrishnan P, Ganesan P, et al. LaTi_0.65Fe_0.35O₃-_δ nano- particle-decorated nitrogen-doped carbon nanorods as an advanc- ed hierarchical air electrode for rechargeable metal-air batteri- es[J]. Nano Energy, 2015,15:92-103. doi: 10.1016/j.nanoen.2015.04.005
[43]	Xue Y, Huang H, Miao H, et al. Electrostatic selfassembly of the composite La_0.7Sr_0.3MnO₃@Ce_0.75Zr_0.25O₂ as electrocatalyst for the oxygen reduction reaction in aluminum-air batteries[J]. Energy Technology, 2017,5(12):2226-2233. doi: 10.1002/ente.v5.12
[44]	Xu J J, Xu D, Wang Z L, et al. Synjournal of perovskite-based porous La_0.75Sr_0.25MnO₃ nanotubes as a highly efficient electrocatalyst for rechargeable lithium-oxygen batteries[J]. Angew Chem Int Ed Engl, 2013,52(14):3887-3890. doi: 10.1002/anie.v52.14
[45]	Song M, Tan H, Li X, et al. Atomic-layer-deposited amorphous MoS₂ for durable and flexible Li-O₂ batteries[J]. Small Methods, 2020,4(6).Doi: 10.1002/smtd.201900274.
[46]	Liu W, Ren B, Zhang W, et al. Defect-enriched nitrogen doped- graphene quantum dots engineered NiCo₂S₄ nanoarray as high-effi- ciency bifunctional catalyst for flexible Zn-air battery[J]. Small, 2019,15(44).Doi: 10.1002/smll.201903610.
[47]	Shao Q, Liu J, Wu Q, et al. In situ coupling strategy for anchoring monodisperse Co₉S₈ nanoparticles on S and N dual-doped graphene as a bifunctional electrocatalyst for rechargeable Zn-air battery[J]. Nano-Micro Letters, 2019,11(1).Doi: 10.1007/s40820-018-0231-3.
[48]	Zhang H, Wang T, Sumboja A, et al. Integrated hierarchical carbon flake arrays with hollow P-doped CoSe₂ nanoclusters as an advanc- ed bifunctional catalyst for Zn-air batteries[J]. Advanced Functio- nal Materials, 2018,28(40).Doi: 10.1002/adfm.201804846.
[49]	Kattel S, Wang G. A density functional theory study of oxygen reduc- tion reaction on Me-N₄ (Me=Fe,Co,or Ni) clusters between grap- hitic pores[J]. Journal of Materials Chemistry A, 2013,1(36):10790-10797. doi: 10.1039/c3ta12142a
[50]	Yin H, Zhang C, Liu F, et al. Hybrid of iron nitride and nitrogendo- ped graphene aerogel as synergistic catalyst for oxygen reduction reaction[J]. Advanced Functional Materials, 2014,24(20):2930-2937. doi: 10.1002/adfm.v24.20
[51]	Jiang W J, Gu L, Li L, et al. Understanding the high activity of Fe-N-C electrocatalysts in oxygen reduction:Fe/Fe₃C nanoparticles boost the activity of Fe-N_x[J]. Journal of the American Chemical Society, 2016,138(10):3570-3578. doi: 10.1021/jacs.6b00757
[52]	Ma L, Chen S, Pei Z, et al. Single-site active iron-based bifunc- tional oxygen catalyst for a compressible and rechargeable zinc- air battery[J]. ACS Nano, 2018,12(2):1949-1958. doi: 10.1021/acsnano.7b09064
[53]	Cheng C, Li S, Xia Y, et al. Atomic Fe-N_x coupled open-mesopor- ous carbon nanofibers for efficient and bioadaptable oxygen elec- trode in Mg-air batteries[J]. Advanced Materials, 2018.Doi: 10.1002/adma.201802669.
[54]	Zhang L, Wilkinson D P, Liu Y, et al. Progress in nanostructured (Fe or Co)/N/C non-noble metal electrocatalysts for fuel cell oxy- gen reduction reaction[J]. Electrochimica Acta, 2018,262:326-336. doi: 10.1016/j.electacta.2018.01.046

首页

全国无机盐信息中心

中国化工学会

无机酸碱盐专业委员会