工业过氧化氢品质提升方案研究进展

doi:10.19964/j.issn.1006-4990.2024-0116

Abstract

Abstract:

In the industrial grade hydrogen peroxide production process，the iron ion content was reduced through reasonable selection of pipeline equipment materials，high-quality passivation，and the use of precision filtration.The total organic carbon TOC content was reduce by selecting efficient solvents，appropriately reducing the temperature of regeneration and reaction，stripping or purification.The content of phosphate ions was reduced by improving the cleanliness of the system，reducing the amount of stable phosphoric acid used and using stabilizers with no or low phosphorus.By controlling temperature，pH，and impurities，product stability could be improved，and stabilizer types could be selected based on downstream products.The pH of hydrogen peroxide was controlled to not exceed 6，and it was recommended to maintain it at 2~3 to increase safety and improve quality.The sensitive elements of different downstream products such as caprolactam and tetrabromobisphenol A was controlled to meet production needs.Through the above control measures，industrial grade hydrogen peroxide could meet downstream chemical manufacturing quality standards，without the need for new purification and purification devices，reducing costs and increasing safety.

Key words: hydrogen peroxide, iron ions, TOC, pH, quality improvement

CLC Number:

TQ123.6

QI Guoqing, LI Tong. Research progress of quality improvement plans for industrial hydrogen peroxide[J]. Inorganic Chemicals Industry, 2025, 57(1): 36-41.

Figures/Tables 3

References 37

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项目		w （H₂O₂）	w［游离酸（以H₂SO₄计）］	w （不挥发物）	稳定度/%	w［总碳（以C计）］	w［硝酸盐（以NO₃计）］
27.5%	优等品	≥27.5	≤0.040	≤0.06	≥97.0	≤0.030	≤0.020
27.5%	合格品	≥27.5	≤0.050	≤0.10	≥90.0	≤0.040	≤0.020
35%		≥35.0	≤0.040	≤0.08	≥97.0	≤0.025	≤0.020
50%		≥50.0	≤0.040	≤0.08	≥97.0	≤0.035	≤0.025
60%		≥60.0	≤0.040	≤0.06	≥97.0	≤0.045	≤0.028
70%		≥70.0	≤0.050	≤0.06	≥97.0	≤0.050	≤0.030

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Research progress of quality improvement plans for industrial hydrogen peroxide

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