氨法捕碳技术再生过程无机添加剂效应研究进展

doi:10.19964/j.issn.1006-4990.2021-0684

Abstract

Abstract:

In recent years,excessive emission of carbon dioxide（CO₂） and other greenhouse gases has increasingly become a serious global issue of climate change.In order to achieve the goal of“Carbon peak and carbon neutralization”,China actively participates in the carbon emission reduction in the world and closely follows the global trend of green and low-carbon development.China is in the transitional period from the old to the new energy structure,the most important source of carbon dioxide is the flue gas emission from fossil fuel fired thermal power plants.Therefore,it is still the key concern by reducing the flue gas emissions.Using ammonia method to capture carbon in carbon capture and storage（CCS） has become one of the current research highlights with many advantages.By analogying the effect of additives on the inhibition of ammonia escape and CO₂ removal effect during the ammonia absorption,the effect of inorganic additives on the desorption of rich liquid in regeneration was mainly analyzed,the research progress at home and abroad was reviewed,and the future development direction of this technology was prospected,including the regeneration mechanism,regeneration energy consumption,ammonia escape,recycling of additives and absorbents,and the attempts of transition metal oxides in the process,etc.

Key words: ammonia decarbonization, regeneration process, CO₂, ammonia escape, inorganic additives

CLC Number:

TQ127.1

QIAO Kun,LÜ Zening,YANG Lijun,DU Xiaoze. Research progress on effect of inorganic additives on regeneration process of carbon capture by ammonia[J]. Inorganic Chemicals Industry, 2022, 54(10): 79-86.

Figures/Tables 3

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Table 1

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添加剂名称	类型	实验条件	性能评价
乙醇^[34]	有机	反应温度为20 ℃,氨质量分数为5%	反应4 h时,CO₂脱除效率能达到95%,比空白组高10%,抑制氨逃逸效果研究较少
氨甲基丙醇、氨甲基丙二醇、烯丙基乙基丙二醇、氨基丁三醇^[35]	有机	反应温度为25 ℃,氨质量分数为10%,压力为0.1 MPa；反应温度为40 ℃,氨质量分数为 10%,压力为0.1 MPa	其中氨甲基丙二醇CO₂脱除效率最高,最高能达到71%,其余添加剂最高达到60%；抑制氨逃逸效果由弱到强分别是氨甲基丙二醇、烯丙基乙基丙二醇、氨甲基丙醇、氨基丁三醇,其中氨基丁三醇抑制率接近52%
聚乙二醇二甲醚^[36]	有机	反应温度为20 ℃,氨质量分数为1.2%	抑制氨逃逸效果达到24.8%
乙二醇、甘油、甘氨酸^[37]	有机	反应温度为40 ℃,氨质量分数为9%,添加剂质量分数为1%	在CO₂吸收过程中抑制氨效果最好的是甘油,达到63.9%,接下来是乙二醇、甘氨酸
ZnCl₂、Zn（NO₃）₂、ZnSO₄^[38]	无机	压力为0.1 MPa,反应温度为0 ℃,氨质量分数为0.77%	平均CO₂脱除效率为87.9%~89.4%,并且锌盐对其促进脱除效率影响较为轻微
Cu（OH）₂^[39]	无机	常压,氨质量分数为9%,反应温度为30 ℃,CO₂体积分数为20%	CO₂的脱除率达到95%以上,质量浓度为0.2 g/L的 Cu（OH）₂加入后抑制氨效果最好,约为40%,其效果优于0.1 g/L和0.5 g/L的Cu（OH）₂
CoCl₂^[33]	无机	反应温度为15 ℃,氨质量分数为8%,CO₂体积分数为15%	实验条件下Co离子的最佳添加浓度为0.05 mol/L左右,氨逃逸抑制效率为40.45%,且改变实验温度时,随着温度的增加,抑制效果提高

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Research progress on effect of inorganic additives on regeneration process of carbon capture by ammonia

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