钒酸铋晶面调控制备及其降解四环素类抗生素性能研究

doi:10.19964/j.issn.1006-4990.2021-0091

Abstract

Abstract:

The monoclinic scheelite bismuth vanadate（m-BiVO₄） catalytic material was synthesized by a solvothermal method and characterized by XRD,BET,SEM,TEM,etc.It was found that the morphology and crystal facet of BiVO₄ could be con-trolled by the pH value of the reaction solution,and m-BiVO₄ with preferentially exposed（010） facet（BVO-010） was pre-pared at pH=7.With chlortetracycline hydrochloride（CTC-HCl）,oxytetracycline（OTC）,tetracycline（TC） and tetracycline hydrochloride（TCN） solutions as target pollutants,the degradation performance of the samples was evaluated.It was disclosed that compared to m-BiVO₄ that mainly exposed the thermodynamically more stable（-121） facets（BVO-121）,BVO-010 ex-hibited more outstanding photocatalytic performance,and the degradation rates of CTC-HCl,OTC,TC,and TCN were 77.9%,79.2%,63.6%,and 73.9%,respectively after 150 min illumination,which was expected to treat wastewater containing antibiotic drugs.

Key words: BiVO₄, crystal facet regulation, photocatalysis, tetracycline antibiotics

CLC Number:

TQ135.11

SHI Suqi,ZHANG Shouchen,ZHANG Dijia,NING Guiling,YE Junwei. Study on crystal facet regulation of bismuth vanadate and its degradation properties of tetracycline antibiotics[J]. Inorganic Chemicals Industry, 2021, 53(11): 114-121.

Figures/Tables 9

Fig.1

Table 1

Fig.2

Fig.3

Fig.4

Fig. 5

Fig.6

Fig.7

Fig.8

References 31

[1]	JIANG L, HU X, YIN D, et al. Occurrence,distribution and seasonal variation of antibiotics in the Huangpu River,Shanghai,China[J]. Chemosphere, 2011, 82(6):822-828. doi: 10.1016/j.chemosphere.2010.11.028
[2]	TIAN J, ZHAO Z, KUMAR A, et al. Recent progress in design,syn-journal,and applications of one-dimensional TiO₂ nanostructured sur-face heterostructures:A review[J]. Chemical Society Reviews, 2014, 43(20):6920-6937. doi: 10.1039/C4CS00180J
[3]	KUDO A, MISEKI Y. Heterogeneous photocatalyst materials for wa-ter splitting[J]. Chemical Society Reviews, 2009, 38(1):253-278. doi: 10.1039/B800489G
[4]	LI Y, SUN Z, ZHU S, et al. Fabrication of BiVO₄ nanoplates with ac-tive facets on graphene sheets for visible-light photocatalyst[J]. Carbon, 2015, 94:599-606. doi: 10.1016/j.carbon.2015.07.042
[5]	赵国升, 李玉鑫, 牛思宇, 等. {010}择优取向BiVO₄亚微米片的制备及其光催化活性研究[J]. 硅酸盐通报, 2014, 33(8):2011-2015.
[6]	冯飞, 李书文, 汪铁林, 等. 片状铋/钒酸铋复合催化剂的制备及其光催化性能[J]. 无机盐工业, 2021, 53(1):107-112.
[7]	LIN Y, LU C, WEI C. Microstructure and photocatalytic performance of BiVO₄ prepared by hydrothermal method[J]. Journal of Alloys and Compounds, 2019, 781:56-63. doi: 10.1016/j.jallcom.2018.12.071
[8]	DONG L, GUO S, ZHU S, et al. Sunlight responsive BiVO₄ photoca-talyst:Effects of pH on L-cysteine-assisted hydrothermal treatment and enhanced degradation of ofloxacin[J]. Catalysis Communica-tions, 2011, 16(1):250-254.
[9]	YE L, LI L, GUO L, et al. Facile synjournal and photocatalytic perfor-mance of BiVO₄ with controllable pumpkin-like microstructure[J]. Materials Letters, 2018, 211:171-174. doi: 10.1016/j.matlet.2017.09.109
[10]	CHAHKANDI M, ZARGAZI M. New water based EPD thin BiVO₄ film:Effective photocatalytic degradation of amoxicillin antibio-tic[J]. Journal of Hazardous Materials, 2020, 389.Doi: 10.1016/j.jhazmat.2019.121850. doi: 10.1016/j.jhazmat.2019.121850
[11]	郑小燕, 徐后涛, 王丽卿, 等. 水产养殖业抗生素新型污染物防控关键技术研究成果[J]. 净水技术, 2020, 39(11):55-58.
[12]	朱颖, 张蕾, 张寒冰, 等. BiVO₄光催化去除废水中的四环素和环丙沙星[J]. 分子科学学报, 2020, 36(1):41-48
[13]	LIU W, ZHAO G, AN M, et al. Solvothermal synjournal of nanostruc-tured BiVO₄ with highly exposed (010) facets and enhanced sun-light-driven photocatalytic properties[J]. Applied Surface Science, 2015, 357:1053-1063. doi: 10.1016/j.apsusc.2015.09.117
[14]	YANG J, WANG D, ZHOU X, et al. A theoretical study on the me-chanism of photocatalytic oxygen evolution on BiVO₄ in aqueous solution[J]. Chemistry—A European Journal, 2013, 19(4):1320-1326. doi: 10.1002/chem.201202365
[15]	LI R, ZHANG F, WANG D, et al. Spatial separation of photogen-erated electrons and holes among{010} and{110} crystal facets of BiVO₄[J]. Nature Communications, 2013, 4(1):1432. doi: 10.1038/ncomms2401
[16]	TAN H L, WEN X, AMAL R, et al. BiVO₄ {010} and {110} relative exposure extent:Governing factor of surface charge population and photocatalytic activity[J]. Journal of Physical Chemistry Letters, 2016, 7(7):1400-1405. doi: 10.1021/acs.jpclett.6b00428
[17]	WANG D, JIANG H, ZONG X, et al. Crystal facet dependence of water oxidation on BiVO₄ sheets under visible light irradiation[J]. Chemistry—A European Journal, 2011, 17(4):1275-1282. doi: 10.1002/chem.v17.4
[18]	THALLURI S M, MARTINEZ SUAREZ C, HERNÁNDEZ S, et al. Elucidation of important parameters of BiVO₄ responsible for pho-to-catalytic O₂ evolution and insights about the rate of the cataly-tic process[J]. Chemical Engineering Journal, 2014, 245:124-132. doi: 10.1016/j.cej.2014.02.017
[19]	ZHANG L, CHEN D, JIAO X. Monoclinic structured BiVO₄ nano-sheets:Hydrothermal preparation,formation mechanism,and colo-ristic and photocatalytic properties[J]. The Journal of Physical Chemistry B, 2006, 110(6):2668-2673. doi: 10.1021/jp056367d
[20]	THALLURI S M, HERNÁNDEZ S, BENSAID S, et al. Green-sy-nthesized W-and Mo-doped BiVO₄ oriented along the{040} facet with enhanced activity for the sun-driven water oxidation[J]. App-lied Catalysis B:Environmental, 2016, 180:630-636.
[21]	THALLURI S M, HUSSAIN M, SARACCO G, et al. Green-synthe-sized BiVO₄ oriented along{040} facets for visible-light-driven et-hylene degradation[J]. Industrial & Engineering Chemistry Rese-arch, 2014, 53(7):2640-2646.
[22]	ZHAO G, LIU W, LI J, et al. Facile synjournal of hierarchically st-ructured BiVO₄ oriented along(010) facets with different morpho-logies and their photocatalytic properties[J]. Applied Surface Sci-ence, 2016, 390:531-539.
[23]	XI G, YE J. Synjournal of bismuth vanadate nanoplates with expo-sed {001} facets and enhanced visible-light photocatalytic proper-ties[J]. Chemical Communications, 2010, 46(11):1893. doi: 10.1039/B923435G
[24]	CHEN L, WANG J, MENG D, et al. The pH-controlled {040} facets orientation of BiVO₄ photocatalysts with different morphologies for enhanced visible light photocatalytic performance[J]. Materials Letters, 2016, 162:150-153. doi: 10.1016/j.matlet.2015.09.138
[25]	GUO L, LI J, LEI N, et al. Morphological evolution and enhanced photoelectrochemical performance of V⁴⁺ self-doped,[010]oriented BiVO₄ for water splitting[J]. Journal of Alloys and Compounds, 2019, 771:914-923. doi: 10.1016/j.jallcom.2018.09.037
[26]	CHEN L, WANG J X, MENG D W. Enhanced photocatalytic acti-vity of hierarchically structured BiVO₄ oriented along {040} facets with different morphologies[J]. Materials Letters, 2015, 147:1-3. doi: 10.1016/j.matlet.2015.02.021
[27]	ZHAO G, WEI L, YAN H, et al. Nanostructured shuriken-like BiVO₄ with preferentially exposed {010} facets:Preparation,formation me-chanism,and enhanced photocatalytic performance[J]. Dalton Tr-ansactions, 2018, 47(4):1325-1336.
[28]	SHANG M, WANG W, REN J, et al. A novel BiVO₄ hierarchical nanostructure:Controllable synjournal,growth mechanism,and app-lication in photocatalysis[J]. CrystEngComm, 2010, 12(6):1754-1758. doi: 10.1039/b923115c
[29]	VO T G, KAO C C, KUO J L, et al. Unveiling the crystallographic facet dependence of the photoelectrochemical glycerol oxidation on bismuth vanadate[J]. Applied Catalysis B:Environmental, 2020, 278.Doi: 10.1016/j.apcatb.2020.119303. doi: 10.1016/j.apcatb.2020.119303
[30]	MADHUSUDAN P, RAN J, ZHANG J, et al. Novel urea assisted hy-drothermal synjournal of hierarchical BiVO₄/Bi₂O₂CO₃ nanocompo-sites with enhanced visible-light photocatalytic activity[J]. Applied Catalysis B:Environmental, 2011, 110:286-295. doi: 10.1016/j.apcatb.2011.09.014
[31]	SERPONE N. Is the band gap of pristine TiO₂ narrowed by anion-and cation-doping of titanium dioxide in second-generation photo-catalysts?[J]. The Journal of Physical Chemistry B, 2006, 110(48):24287-24293. doi: 10.1021/jp065659r

样品	I_（040）/ I_（-121）	晶胞参数						晶胞体积/（nm³）	晶粒尺寸/ nm
样品	I_（040）/ I_（-121）	a	b	c	α	β	γ	晶胞体积/（nm³）	晶粒尺寸/ nm
BVO-2	0.17	5.149	11.705	5.136	90	89.97	90	0.310	32.5
BVO-4	0.18	5.173	11.700	5.111	90	90.11	90	0.309	25.0
BVO-6	1.31	5.195	11.712	5.106	90	90.33	90	0.311	70.8
BVO-7	1.40	5.195	11.701	5.097	90	90.39	90	0.310	98.1

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on crystal facet regulation of bismuth vanadate and its degradation properties of tetracycline antibiotics

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 9

References 31

Related Articles 15

Metrics

Comments

Recommended 0

[1]	TANG Bei. Preparation of ZnO/g-C₃N₄ heterojunction photocatalytic material and its degradation of pyridine [J]. Inorganic Chemicals Industry, 2024, 56(4): 133-142.
[2]	HUANG Jianan, LU Xiaoyu, WANG Mitang. Effect of Ba-La co-doping on degradation of methylene blue dye by TaON [J]. Inorganic Chemicals Industry, 2024, 56(2): 146-151.
[3]	YANG Bo, LIANG Zhiyan, LIU Wenyuan, CAO Jiazhen, LIU Xinyue, XING Mingyang. Research progress of application of molybdenum-based catalytic materials for water pollution control [J]. Inorganic Chemicals Industry, 2023, 55(8): 1-12.
[4]	YU Hongchao, ZHANG Mengmeng, JIN Tianxiang. Research progress of microstructure and crystal surface effect of Ag₃PO₄ photocatalysts [J]. Inorganic Chemicals Industry, 2023, 55(8): 13-20.
[5]	ZHAO Yan, HAO Xuewei, SHI Hainan, LI Jiahui, LI Keyan, GUO Xinwen. Study on photocatalytic CO₂reduction performance of Cu-doped TiO₂/PCN heterojunction [J]. Inorganic Chemicals Industry, 2023, 55(8): 21-27.
[6]	SUN Haijie, CHENG Yuan, TIAN Yuan, LIU Hongyan, CHEN Zhihao. Preparation of BiOI/g-C₃N₄ catalyst and its photocatalytic degradation performance of Rhodamine B [J]. Inorganic Chemicals Industry, 2023, 55(8): 36-44.
[7]	SONG Zhijia, WANG Suisui, KUANG Qin. Hollow Cu-doped TiO₂ for enhancing photocatalytic CO₂ reduction performance [J]. Inorganic Chemicals Industry, 2023, 55(8): 45-50.
[8]	LAN Yinghua, CHEN Yanmei, MA Ruixiao, ZHANG Yanhui. Preparation and photocatalytic performance of Ce-Ti oxide-attapulgite composites [J]. Inorganic Chemicals Industry, 2023, 55(4): 133-140.
[9]	CHEN Zhangxu, FU Minglian, ZHU Danchen, ZHENG Bingyun. Preparation of carbon/graphite carbon nitride composites and their methylene blue removal performance [J]. Inorganic Chemicals Industry, 2023, 55(3): 134-139.
[10]	QIU Xiaokui, ZHANG Ruofan, WANG Xiaoyan, WANG Hailong, ZHANG Qixue, WAN Chao, XU Lixin. Research on bamboo shavings carbon supported ruthenium catalysts for hydrogen generation from photocatalytic hydrolysis of ammonia borane [J]. Inorganic Chemicals Industry, 2023, 55(10): 153-158.
[11]	ZHANG Zhe,LIAO Mingyu,CHEN Ming,YU Shanshan,ZHOU Kangdi,LI Jiachun,ZHANG Linfeng,WU Huadong,GUO Jia. Application of CeO₂-ZnO/KIT-6 catalyst in photocatalytic adsorption desulfurization [J]. Inorganic Chemicals Industry, 2022, 54(9): 143-149.
[12]	TONG Haijuan,LI Siqi,FAN Fangfang,ZUO Weiyuan,SHI Bingfang. Facile synthesis of bismuth oxychloride and its photocatalytic degradation performance of p-nitrophenol [J]. Inorganic Chemicals Industry, 2022, 54(9): 157-162.
[13]	YANG Wenbo,WU Pan,HE Jian,LIU Changjun,JIANG Wei. Study on effect of heating rate on structure-activity of g-C₃N₄photocatalyst by pyrolysis of urea [J]. Inorganic Chemicals Industry, 2022, 54(4): 169-174.
[14]	LIANG Fang,SHI Fanian. Research progress on synthesis of bismuth based bimetallic photocatalyst and degradation of organic pollutants [J]. Inorganic Chemicals Industry, 2022, 54(4): 61-68.
[15]	BAN Changsheng,LI Jun,JIN Yang,CHEN Ming,ZUO Longtao. Study on preparation of g-C₃N₄/g-C₃N₄ homojunction by supramolecular precursor and its photocatalytic property [J]. Inorganic Chemicals Industry, 2022, 54(3): 125-131.