基于表/界面调控的金属氧化物半导体光催化剂的理性构筑

doi:10.11962/1006-4990.2020-0541

Abstract

Abstract:

In recent years,semiconductor based photocatalysis,as a green technology,has attracted wide attention in solving environmental problems and providing renewable energy,but the low efficiency still limits its practical application.Rational surface/interface design of metal oxide semiconductor is an effective approach to improve the performance of photocatalysts. Recent progress in the surface/interface structure engineering and structure-activity relationship of semiconductor photocata-lysts was systematically reviewed.The feasible measures to optimize the photocatalytic performance by the facet effect in sin-gle component were introduced.On this basis,the application of facet/interface engineering strategies in promoting photo-catalytic performance of multi-component composite photocatalysts were summarized.Finally,the challenges and opportunities in this field were briefly featured on the basis of its current development.

Key words: photocatalysis, metal oxide, facet, interface

CLC Number:

O643.36

Song Zhijia,Chen Qian,Kuang Qin. Surface/interface engineering of metal oxide semiconductor nanocrystals for enhanced photocatalysis[J]. Inorganic Chemicals Industry, 2021, 53(3): 1-6.

Figures/Tables 5

References 40

[1]	Xu Chunping, Anusuyadevi P R, Aymonier C, et al. Nanostructured materials for photocatalysis[J]. Chemical Society Reviews, 2019,48(14):3868-3902. doi: 10.1039/c9cs00102f pmid: 31173018
[2]	潘金波, 申升, 周威, 等. 光催化制氢研究进展[J]. 物理化学学报, 2019,36(3):1905068.
[3]	Zhu Shasha, Wang Dunwei. Photocatalysis:basic principles,diverse forms of implementations and emerging scientific opportunities[J]. Advanced Energy Materials, 2017,7(23):1700841.
[4]	Bai Song, Wang Lili, Li Zhengquan, et al. Facet-engineered surface and interface design of photocatalytic materials[J]. Advanced Sci-ence, 2017,4(1):1600216.
[5]	Kuang Qin, Wang Xue, Jiang Zhiyuan, et al. High-energy-surface en-gineered metal oxide micro-and nanocrystallites and their applicat-ions[J]. Accounts of Chemical Research, 2014,47(2):308-318. doi: 10.1021/ar400092x pmid: 24341353
[6]	Wang An, Wu Shijie, Dong Jialu, et al. Interfacial facet engineering on the Schottky barrier between plasmonic Au and TiO₂ in boosting the photocatalytic CO₂ reduction under ultraviolet and visible light irradiation[J]. Chemical Engineering Journal, 2021,404:127145.
[7]	何洪波, 张梦凡, 刘珍, 等. F掺杂制备具有高暴露(001)晶面的BiOCl纳米片及其光催化性能[J]. 无机化学学报, 2020,35(8):1413-1420.
[8]	Ye Liqun, Mao Jin, Peng Tianyou, et al. Opposite photocatalytic ac-tivity orders of low-index facets of anatase TiO₂ for liquid phase dye degradation and gaseous phase CO₂ photoreduction[J]. Physical Che-mistry Chemical Physics, 2014,16(29):15675-15680.
[9]	Li Junfang, Bai Hua, Yi Wencan, et al. Synjournal and facet-depen-dent photocatalytic activity of strontium titanate polyhedron nano-crystals[J]. Nano Research, 2016,9(5):1523-1531.
[10]	Wang Gang, Ma Xiangchao, Huang Baibiao, et al. Controlled synt-hesis of Ag₂O microcrystals with facet-dependent photocatalytic ac-tivities[J]. Journal of Materials Chemistry, 2012,22(39):21189-21194.
[11]	Xiao Chi, Lu Bangan, Xue Peng, et al. High-index-facet-and high-surface-energy nanocrystals of metals and metal oxides as highly efficient catalysts[J]. Joule, 2020,4:1-37.
[12]	Sun Shaodong, Zhang Xin, Cui Jie, et al. High-index faceted metal oxi-de micro-/nanostructures:a review on their characterization,syn-journal and applications[J]. Nanoscale, 2019,11(34):15739-15762. doi: 10.1039/c9nr05107d pmid: 31433431
[13]	Zhang Jiawei, Li Huiqi, Kuang Qin, et al. Toward rationally design-ing surface structures of micro-and nanocrystallites:Role of su-persaturation[J]. Accounts of Chemical Research, 2018,51(11):2880-2887. doi: 10.1021/acs.accounts.8b00344 pmid: 30346701
[14]	Hobbs R G, Petkov N, Holmes J D. Semiconductor nanowire fabri-cation by bottom-up and top-down paradigms[J]. Chemistry of Ma-terials, 2012,24(11):1975-1991.
[15]	Li Chuanhao, Koenigsmann C, Ding Wendu, et al. Facet-dependent dent photoelectrochemical performance of TiO₂ nanostructures:an experimental and computational study[J]. Journal of the American Chemical Society, 2015,137(4):1520-1529. doi: 10.1021/ja5111078 pmid: 25563343
[16]	Xu Hua, Reunchan P, Ouyang Shuxin, et al. Anatase TiO₂ single crystals exposed with high-reactive{111} facets toward efficient H₂ evolution[J]. Chemistry of Materials, 2013,25(3):405-411.
[17]	Kimijima T, Kanie K, Nakaya M, et al. Solvothermal synjournal of SrTiO₃ nanoparticles precisely controlled in surface crystal planes and their photocatalytic activity[J]. Applied Catalysis B:Environ-mental, 2014,144:462-467.
[18]	Jiang Dong, Wang Wenzhong, Zhang Ling, et al. Insights into the surface-defect dependence of photoreactivity over CeO₂ nanocryst-als with well-defined crystal facets[J]. ACS Catalysis, 2015,5(8):4851-4858.
[19]	Liu Chang, Tong Ruifeng, Xu Zhenkai, et al. Efficiently enhancing the photocatalytic activity of faceted TiO₂ nanocrystals by selecti-vely loading α-Fe₂O₃ and Pt co-catalysts[J]. RSC Advances, 2016,6(35):29794-29801.
[20]	Li Rengui, Zhang Fuxiang, Wang Donge, et al. Spatial separation of photogenerated electrons and holes among {010} and {110} crystal facets of BiVO₄[J]. Nature Communications, 2013,4(1):1-7.
[21]	Tachikawa T, Yamashita S, Majima T. Evidence for crystal-face-dependent TiO₂ photocatalysis from single-molecule imaging and kinetic analysis[J]. Journal of the American Chemical Society, 2011,133(18):7197-7204. doi: 10.1021/ja201415j pmid: 21495637
[22]	Chen Ruotian, Pang Shan, An Hongyu, et al. Charge separation via asymmetric illumination in photocatalytic Cu₂O particles[J]. Na-ture Energy, 2018,3(8):655-663.
[23]	Liu Xiaogang, Dong Guojun, Li Shaopeng, et al. Direct observation of charge separation on anatase TiO₂ crystals with selectively etch-ed {001} facets[J]. Journal of the American Chemical Society, 2016,138(9):2917-2920. doi: 10.1021/jacs.5b12521 pmid: 26924454
[24]	Ye Liqun, Liu Jinyan, Tian Lihong, et al. The replacement of {101} by{010} facets inhibits the photocatalytic activity of anatase TiO₂[J]. Applied Catalysis B:Environmental, 2013,134:60-65.
[25]	Yu Jiaguo, Low Jingxiang, Xiao Wei, et al. Enhanced photocatalytic CO₂-reduction activity of anatase TiO₂ by coexposed{001} and {101} facets[J]. Journal of the American Chemical Society, 2014,136(25):8839-8842. doi: 10.1021/ja5044787 pmid: 24918628
[26]	Wang Lili, Ge Jing, Wang Ailun, et al. Designing p-type semicon- ductor-metal hybrid structures for improved photocatalysis[J]. Angewandte Chemie, 2014,126(20):5207-5211. doi: 10.1002/ange.201310635
[27]	Li Ping, Zhou Yong, Zhao Zongyan, et al. Hexahedron prism-anc-hored octahedronal CeO₂:crystal facet-based homojunction promo-ting efficient solar fuel synjournal[J]. Journal of the American Che-mical Society, 2015,137(30):9547-9550.
[28]	Wang Bin, Shen Shaohua, Guo Liejin. Surface reconstruction of fa-cet-functionalized SrTiO₃ nanocrystals for photocatalytic hydrogen evolution[J]. ChemCatChem, 2016,8(4):798-804. doi: 10.1002/cctc.v8.4
[29]	Low Jingxiang, Yu Jiaguo, Jaroniec M, et al. Heterojunction photo-catalysts[J]. Advanced Materials, 2017,29(20):1601694. doi: 10.1002/adma.v29.20
[30]	Su Qian, Li Yao, Hu Ran, et al. Heterojunction photocatalysts ba-sed on 2D materials:the role of configuration[J]. Advanced Susta-inable Systems, 2020,4(9):2000130.
[31]	Gu Liuan, Wang Jingyu, Cheng Hao, et al. One-step preparation of graphene-supported anatase TiO₂ with exposed{001} facets and me-chanism of enhanced photocatalytic properties[J]. ACS Applied Materials & Interfaces, 2013,5(8):3085-3093. doi: 10.1021/am303274t pmid: 23527869
[32]	Shi Weina, Guo Xiaowei, Cui Chengxing, et al. Controllable synthe-sis of Cu₂O decorated WO₃ nanosheets with dominant(001) facets for photocatalytic CO₂ reduction under visible-light irradiation[J]. Applied Catalysis B:Environmental, 2019,243:236-242. doi: 10.1016/j.apcatb.2018.09.076
[33]	Mao Jin, Ye Liqun, Li Kan, et al. Pt-loading reverses the photoca-talytic activity order of anatase TiO₂{001} and{010} facets for pho-toreduction of CO₂ to CH₄[J]. Applied Catalysis B:Environmental, 2014,144:855-862. doi: 10.1016/j.apcatb.2013.08.027
[34]	Zhu Xing, Yamamoto A, Imai S, et al. Facet-selective deposition of a silver-manganese dual cocatalyst on potassium hexatitanate pho-tocatalyst for highly selective reduction of carbon dioxide by water[J]. Applied Catalysis B:Environmental, 2020,274:119085. doi: 10.1016/j.apcatb.2020.119085
[35]	Liu Chang, Han Xiguang, Xie Shuifen, et al. Enhancing the photo-catalytic activity of anatase TiO₂ by improving the specific facet-induced spontaneous separation of photogenerated electrons and holes[J]. Chemistry-An Asian Journal, 2013,8(1):282-289. doi: 10.1002/asia.201200886
[36]	Guo Meichen, Li Liping, Lin Haifeng, et al. Targeted deposition of ZnO₂ on brookite TiO₂ nanorods towards high photocatalytic acti-vity[J]. Chemical Communications, 2013,49(100):11752-11754. doi: 10.1039/c3cc47461e pmid: 24196455
[37]	Hu Yangguang, Gao Chao, Xiong Yujie. Surface and interface de-sign for photocatalytic water splitting[J]. Dalton Transactions, 2018,47(35):12035-12040. doi: 10.1039/c8dt02885k pmid: 30101959
[38]	Qin Yingying, Li Hong, Lu Jian, et al. Synergy between van der wa-als heterojunction and vacancy in ZnIn₂S₄/g-C₃N₄ 2D/2D photoca-talysts for enhanced photocatalytic hydrogen evolution[J]. App-lied Catalysis B:Environmental, 2020,277:119254.
[39]	Naresh G, Hsieh P L, Meena V, et al. Facet-dependent photocataly-tic behaviors of ZnS-decorated Cu₂O polyhedra arising from tuna-ble interfacial band alignment[J]. ACS Applied Materials & Inter-faces, 2018,11(3):3582-3589.
[40]	Zhang Jun, Zhou Dandan, Dong Shuangshi, et al. Respective cons-truction of Type-Ⅱ and direct Z-scheme heterostructure by selec-tively depositing CdS on{001} and{101} facets of TiO₂ nanosheet with CDots modification:A comprehensive comparison[J]. Journal of Hazardous Materials, 2019,366:311-320. doi: 10.1016/j.jhazmat.2018.12.013 pmid: 30530023

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Surface/interface engineering of metal oxide semiconductor nanocrystals for enhanced photocatalysis

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