氨水微波改性活性炭及其吸附分离多环芳烃的研究

doi:10.19964/j.issn.1006-4990.2025-0166

Abstract

Abstract:

Excessive content of polycyclic aromatic hydrocarbons（PAHs） can significantly affect the quality of diesel and cause environmental pollution.In response to the demand for efficient removal of PAHs in diesel，modified activated carbon（WMAC） was prepared by ammonia water microwave modification method in this study.By characterizing the surface morphology，pore structure and surface properties of the samples under different modification conditions，and using simulated oil products as raw materials，the PAHs separation performance was investigated by using a fixed-bed adsorption separation device.The results showed that the specific surface area of WMAC-600W modified by 600 W microwave power reached 1 059 m²/g（65.7% higher than that of unmodified activated carbon AC），the total pore volume was 0.66 cm³/g（78.4% higher），and the average pore diameter was increased by 17.4%.The static adsorption capacity of methyl naphthalene was 98.34 mg/g（80.9% higher than AC）at 20 ℃，the dynamic saturated adsorption capacity reached 196.47 mg/g（99.0% higher），and it still maintained good adsorption stability after five regenerations.In the simulated diesel adsorption separation，the average desorption time of PAHs of WMAC-600W was shortened by 6 min compared with MAC-10-5，the desorption capacity was increased significantly，and the adsorption capacity of PAHs in commercial diesel was as high as 187.34 mg/g.The studies showed that microwave modification of ammonia water could significantly improve the adsorption and separation performance of activated carbon by optimizing its pore structure and surface chemical properties.WMAC-600W could be used as a potential adsorption material for the efficient removal of PAHs in diesel.

Key words: activated carbon, polycyclic aromatic hydrocarbons, adsorption separation, microwave modification

CLC Number:

TQ127.1

LI Lei, HAN Enshan, LI Bin, SUN Zhenhai, HE Yanzhen. Study on microwave modification of activated carbon by ammonia and its adsorption for separation of polycyclic aromatic hydrocarbons[J]. Inorganic Chemicals Industry, 2026, 58(3): 65-71.

Figures/Tables 13

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References 24

[1]	ABBAS A F， AHMED M J.Mesoporous activated carbon from date stones（Phoenix dactylifera L.） by one-step microwave assisted K₂CO₃ pyrolysis［J］.Journal of Water Process Engineering，2016，9：201-207.
[2]	YAN Yikang， YUVARAJA G， LIU Chunjiang，et al.Removal of Pb（Ⅱ） ions from aqueous media using epichlorohydrin crosslinked chitosan Schiff′s base@Fe₃O₄（ECCSB@Fe₃O₄）［J］.International Journal of Biological Macromolecules，2018，117：1305-1313.
[3]	ZADA S， ZHOU Haixin， XIE Jianmin，et al.Bacterial degradation of pyrene：Biochemical reactions and mechanisms［J］.International Biodeterioration & Biodegradation，2021，162：105233.
[4]	GAO Yan， WANG Sicen， ZHANG Nan，et al.Novel solid-phase extraction filter based on a zirconium meta-organic framework for determination of non-steroidal anti-inflammatory drugs residues［J］.Journal of Chromatography A，2021，1652：462349.
[5]	KOŁTOWSKI M， HILBER I， BUCHELI T D，et al.Activated biochars reduce the exposure of polycyclic aromatic hydrocarbons in industrially contaminated soils［J］.Chemical Engineering Journal，2017，310：33-40.
[6]	武鲁明，于海斌，臧甲忠，等.多级孔硅铝酸盐纳米球的合成及其吸附分离多环芳烃［J］.化工进展，2023，42（12）：6452-6460.
	WU Luming， YU Haibin， ZANG Jiazhong，et al.Synthesis of hierarchically porous aluminosilicate nanospheres and their adsorption and separation of polycyclic aromatic hydrocarbons［J］.Chemical Industry and Engineering Progress，2023，42（12）：6452-6460.
[7]	刘凡，温舒晴，王昌，等.活性炭固定床吸附分离溶液中表面活性剂和多环芳烃［J］.化工环保，2017，37（6）：693-698.
	LIU Fan， WEN Shuqing， WANG Chang，et al.Adsorption and separation of surfactants and polycyclic aromatic hydrocarbons from solution in activated carbon fixed bed［J］.Environmental Protection of Chemical Industry，2017，37（6）：693-698.
[8]	邓东丰，张新.活性炭固定床吸附分离多环芳烃研究［J］.环境科学导刊，2019，38（6）：63-65.
	DENG Dongfeng， ZHANG Xin.Study on adsorption and separation of polycyclic aromatic hydrocarbons by activated carbon fixed bed［J］.Environmental Science Survey，2019，38（6）：63-65.
[9]	ZHANG Lige， QIU Xiaoyu， HUANG Ling，et al.Microbial degradation of multiple PAHs by a microbial consortium and its application on contaminated wastewater［J］.Journal of Hazardous Materials，2021，419：126524.
[10]	ZHUO Ning， LAN Yaqian， YANG Weiben，et al.Adsorption of three selected pharmaceuticals and personal care products （PPCPs） onto MIL-101（Cr）/natural polymer composite bea-ds［J］.Separation and Purification Technology，2017，177：272- 280.
[11]	KONG Huoliang， HE Jiao， GAO Yanzheng，et al.Cosorption of phenanthrene and mercury（Ⅱ） from aqueous solution by soybean stalk-based biochar［J］.Journal of Agricultural and Food Chemistry，2011，59（22）：12116-12123.
[12]	SHI Qianqian， LI Aimin， ZHU Zhaolian，et al.Adsorption of naphthalene onto a high-surface-area carbon from waste ion exch-ange resin［J］.Journal of Environmental Sciences，2013，25（1）：188-194.
[13]	ANIA C O， CABAL B， PEVIDA C，et al.Effects of activated carbon properties on the adsorption of naphthalene from aqueous solutions［J］.Applied Surface Science，2007，253（13）：5741-5746.
[14]	EZUNG S L， BARUAH M， SUPONG A，et al.Experimental and theoretical insight into the adsorption of 2，4-dichlorophenol on low-cost bamboo sheath activated carbon［J］.Sustainable Chemistry and Pharmacy，2022，26：100643.
[15]	WANG Xiaoqing， GUO Zizhang， HU Zhen，et al.Adsorption of phenanthrene from aqueous solutions by biochar derived from an ammoniation-hydrothermal method［J］.Science of the Total Environment，2020，733：139267.
[16]	YAACOUBI H， ZUO Songlin.Effect of ammonia modification on activated carbons for the removal of acidic anthraquinone dyes［J］.International Journal of Chemical Reactor Engineering，2019，17（8）：20180216.
[17]	GE Xinyu， WU Zhansheng， WU Zhilin，et al.Microwave-assisted modification of activated carbon with ammonia for efficient pyrene adsorption［J］.Journal of Industrial and Engineering Chemistry，2016，39：27-36.
[18]	赵闯，张博宇，李犇，等.吸附剂对多环芳烃吸附分离技术的研究［J］.无机盐工业，2024，56（7）：61-68.
	ZHAO Chuang， ZHANG Boyu， LI Ben，et al.Study on adsorption and separation technology of polycyclic aromatic hydrocarbons by adsorbent［J］.Inorganic Chemicals Industry，2024，56（7）：61-68.
[19]	PREMNATH N， MOHANRASU K， GURU RAJ RAO R，et al.A crucial review on polycyclic aromatic Hydrocarbons-Environmental occurrence and strategies for microbial degradation［J］.Chemosphere，2021，280：130608.
[20]	HUSSAIN I， SAHOO S， LAMIEL C，et al.Research progress and future aspects：Metal selenides as effective electrodes［J］.Energy Storage Materials，2022，47：13-43.
[21]	KUPPUSAMY S， THAVAMANI P， MEGHARAJ M，et al.Isolation and characterization of polycyclic aromatic hydrocarbons （PAHs） degrading，pH tolerant，N-fixing and P-solubilizing novel bacteria from manufactured gas plant（MGP） site soils［J］.Environmental Technology & Innovation，2016，6：204-219.
[22]	LI Xiaodong， CAO Huizhen， CAO Yuan，et al.Insights into the mechanism of persulfate activation with biochar composite loaded with Fe for 2，4-dinitrotoluene degradation［J］.Journal of Environmental Management，2023，341：117955.
[23]	孙中海，武占省，刘丹丹.微波辅助表面活性剂改性活性炭及其对萘的吸附研究［C］∥2017中国环境科学学会科学与技术年会论文集（第四卷）.厦门，2017：214-222.
[24]	DEĞERMENCI G D， DEĞERMENCI N， AYVAOĞLU V，et al.Adsorption of reactive dyes on lignocellulosic waste；characterization，equilibrium，kinetic and thermodynamic studies［J］.Journal of Cleaner Production，2019，225：1220-1229.

组分	质量分数/%	备注
三甲苯	25	单环芳烃组分
十氢萘	25	环烷烃组分
四氢萘	20	环烷芳烃组分
十二烷	15	链烷烃组分
甲基萘	15	双环芳烃组分

样品	比表面积/ （m²·g^-1）	总孔容/ （cm³·g^-1）	平均孔径/ nm
AC	639	0.37	2.3
MAC-10-5	771	0.46	2.4
WMAC-400W	945	0.58	2.5
WMAC-600W	1 059	0.66	2.7
WMAC-800W	992	0.61	2.6

T/℃	静态饱和吸附量/（mg·g^-1）
T/℃	AC	MAC-10-5	WMAC-400W	WMAC-600W	WMAC-800W
20	54.37	69.12	87.31	98.34	91.18
40	52.38	63.92	82.48	92.25	85.47
60	48.23	62.62	78.52	87.46	82.94
80	43.73	57.45	71.28	81.12	75.47
100	41.97	51.22	66.80	79.82	73.05

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on microwave modification of activated carbon by ammonia and its adsorption for separation of polycyclic aromatic hydrocarbons

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