Inorganic Chemicals Industry ›› 2022, Vol. 54 ›› Issue (6): 38-45.doi: 10.19964/j.issn.1006-4990.2021-0450
• Reviews and Special Topics • Previous Articles Next Articles
YANG Shuang1(),ZHAO Siqin1,2,3(
),YANG Huiying1
Received:
2021-09-22
Online:
2022-06-10
Published:
2022-06-22
Contact:
ZHAO Siqin
E-mail:ys1410350082@163.com;zhaosq@imnu.edu.cn
CLC Number:
YANG Shuang,ZHAO Siqin,YANG Huiying. Research progress on photocatalysis by bismuth?based semiconductor composite TiO2[J]. Inorganic Chemicals Industry, 2022, 54(6): 38-45.
Table 1
Crystal structure data of TiO2"
TiO2结构 | 晶系 | 带隙能/eV | 参数/nm | 钛氧键长/nm | O—Ti—O 键角/(°) | 密度/ (g?cm-3) | 转化关系 |
---|---|---|---|---|---|---|---|
金红石相(最稳定) | 四方晶系 | 3.00 | a=0.458 4 c=0.295 3 | 0.193 7(4) 0.196 5(2) | 77.7 92.6 | 4.2~4.3 | — |
锐钛矿相 | 四方晶系 | 3.20 | a=0.377 6 c=0.948 6 | 0.149 4(4) 0.198 0(2) | 81.2 90.0 | 3.8~3.9 | 910 ℃完全转换为金红石相 |
板钛矿相 | 斜方晶系 | 2.96 | a=0.545 b=0.918 c=0.515 | 0.187~0.204 | 77.0~105.0 | 4.12~4.23 | 高于650 ℃转换为金红石相 |
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