芬顿铁泥资源化利用研究进展

doi:10.19964/j.issn.1006-4990.2021-0406

Abstract

Abstract:

Fenton sludge is a kind of industrial hazardous waste produced by Fenton oxidation technology after treating industrial organic wastewater.Fenton sludge contains a large amount of iron resources，which has a high resource recovery potential and has become a research hotspot at home and abroad.Various kinds of Fenton sludge resource utilization methods at home and abroad were summarized from two aspects of chemical method and thermal method of Fenton sludge.The research progress，advantages and disadvantages as well as core technologies of various typical methods were introduced.The future development goals of Fenton sludge resource utilization were prospected.Based on the actual operation situation of thermal power plants in China，a new way of Fenton sludge resource utilization was proposed.It was used as raw materials to prepare the iron?based selective catalytic reduction（SCR） denitration catalyst for thermal power plants，in order to fully recover and utilize the iron resources in Fenton iron slime and reduce the environmental harm caused by iron slime accumulation.

Key words: Fenton sludge, resource, chemical method, thermal energy method, iron-based catalyst

CLC Number:

YU Ziyang,YU Hewei,ZHAO Gaiju,WANG Luyuan,SUN Rongfeng. Research progress on resource utilization of Fenton sludge[J]. Inorganic Chemicals Industry, 2022, 54(6): 31-37.

Figures/Tables 7

Fig.1

Fig.2

Table 1

Application study on preparation of ferrous salt by reduction method"

还原剂（方法）	优点	缺点	产物/目的
铁屑还原^［24］	简化了结晶工艺，采用水-乙醇相使七水合硫酸亚铁快速结晶析出，缩短了生产时间，制得的产品可用于生产铁系染料	反应过程中需加入大量乙醇，工艺成本较高；对温度、pH、试剂浓度要求严格，不易操作且步骤繁琐	七水合硫酸亚铁
电化学还原^［27］	提高了COD去除率，Fe³⁺转化率可以达到98%以上，加入填料组成三维电极，使填料表面感应带电发生电化学还原发应	电能损耗大，运行费用较高，反应过程中需严格控制Fe³⁺浓度和多次测量COD浓度，操作难度较大	纯度较高的亚铁盐
微生物还原^［28］	将厌氧消化过程与芬顿铁泥的处置相结合，装置内所需温度较低，降低了系统能耗	需对厌氧微生物进行驯化培养，菌数不易控制，设备复杂，研发成本高	实现芬顿铁泥大幅减量化、无害化处理
H₂S烟气^［29］	省去了在常规烟气脱硫技术中对其中铁催化剂的单独氧化再生，降低了整体运行成本	需要使用大量化学试剂，易造成二次污染；实验步骤复杂，且反应所需条件过多	实现废水和废气的综合治理
碱性磷酸盐混合物^［30］	既避免了大量芬顿铁泥危险废弃物的产生，又能直接在线制得以FePO₄为主的磷铁化合物，具有较高的经济效益和环境效益	制备的FePO₄产品杂质较多，若要作为锂电池磷酸铁锂的原材料，还需对产物进一步提纯	FePO₄粗产品
紫外光^［31］	减少了原料和废弃物的处理成本，且无外排固体废弃物，不产生二次污染；工艺方法简单，便于大规模推广	循环利用芬顿铁泥会导致铁泥内的有机质不断积累，反应槽内的负载型半导体催化剂消耗较大	建立芬顿铁泥自循环体系

Table 1

Fig.3

Fig.4

Fig.5

Fig.6

References 52

1	AMOR C， FERNANDES J R， LUCAS M S，et al.Hydroxyl and sulfate radical advanced oxidation processes：Application to an agro⁃industrial wastewater［J］.Environmental Technology & Innovation，2021，21.Doi：10.1016/j.eti.2020.101183 . doi: 10.1016/j.eti.2020.101183
2	MACKUĽAK T， MOSNÝ M， GRABIC R，et al.Fenton⁃like reaction：A possible way to efficiently remove illicit drugs and pharmaceuticals from wastewater［J］.Environmental Toxicology and Pharmacology，2015，39（2）：483-488.
3	LAIJU A R， SIVASANKAR T， NIDHEESH P V.Iron⁃loaded mangosteen as a heterogeneous Fenton catalyst for the treatment of landfill leachate［J］.Environmental Science and Pollution Research International，2014，21（18）：10900-10907.
4	SAMY M， ALALM M G， MOSSAD M.Utilization of iron sludge resulted from electro⁃coagulation in heterogeneous photo-Fenton process［J］.Water Practice and Technology，2020，15（4）：1228-1237.
5	GHERNAOUT D， ELBOUGHDIRI N， GHAREBA S.Fenton technology for wastewater treatment：Dares and trends［J］.OALib，2020，7（1）：1-26.
6	章琴琴，宋诚，华亚妮，等.Fenton法降解垃圾渗滤液中的溶解性有机质［J］.环境工程学报，2017，11（4）：2219-2226.
	ZHANG Qinqin， SONG Cheng， HUA Yani，et al.Degradation of dissolved organic matter in landfill leachate by Fenton treatment［J］.Chinese Journal of Environmental Engineering，2017，11（4）：
	2219-2226.
7	FENG Dongqing， Jinhong LÜ， GUO Sen，et al.Biochar enhanced the degradation of organic pollutants through a Fenton process using trace aqueous iron［J］.Journal of Environmental Chemical Engineering，2021，9（1）.Doi：10.1016/J.JECE.2020.104677 . doi: 10.1016/J.JECE.2020.104677
8	YILDIZ S， CÖMERT A.Fenton process effect on sludge disintegration［J］.International Journal of Environmental Health Research，2020，30（1）：89-104.
9	顾汉念，郭腾飞，马时成，等.赤泥中铁的提取与回收利用研究进展［J］.化工进展，2018，37（9）：3599-3608.
	GU Hannian， GUO Tengfei， MA Shicheng，et al.Review on separation，recovery，extraction and comprehensive utilization of iron from red mud［J］.Chemical Industry and Engineering Progress，2018，37（9）：3599-3608.
10	李凌，姬瑞华.固体废物的处理与资源化利用分析及建议［J］.清洗世界，2020，36（11）：64-65.
	LI Ling， JI Ruihua.Analysis and suggestions on treatment and resource utilization of solid waste［J］.Cleaning World，2020，36（11）：64-65.
11	SHEN Minxian， HUANG Zhujian， QIU Linhui，et al.Recycling of Fenton sludge containing Ni as an efficient catalyst for tetracycline degradation through peroxymonosulfate activation［J］.Journal of Cleaner Production，2020，268.Doi：10.1016/j.jclepro.2020 . doi: 10.1016/j.jclepro.2020
	122174. doi: 10.1016/j.jclepro.2020
12	葛强，张哲，王慧，等.制浆造纸厂芬顿铁泥酸处理及其回用为污泥调理剂的研究［J］.纸和造纸，2021，40（2）：24-30.
	GE Qiang， ZHANG Zhe， WANG Hui，et al.Acid treatment and recycling as sludge conditioning agents of Fenton iron sludge from pulp and paper mill［J］.Paper and Paper Making，2021，40（2）：24-30.
13	巫俊楫，宁寻安.印染污泥性质对多环芳烃分布及降解的影响研究［J］.环境工程，2021，34（4）：1-9.
	WU Junji， NING Xun′an.Influence of the distribution and degradation of pahs by the properties of the textile dyeing sludge［J］.Environmental Engineering，2021，34（4）：1-9.
14	MAHTAB M S， FAROOQI I H， KHURSHEED A.Zero Fenton sludge discharge：A review on reuse approach during wastewater treatment by the advanced oxidation process［J］.International Journal of Environmental Science and Technology，2022，19（3）：2265-2278.
15	庄晓杰.Fenton铁泥资源化利用的研究进展［J］.广州化工，2021，49（10）：25-26，62.
	ZHUANG Xiaojie.Research progresson resource recovery of Fenton sludge［J］.Guangzhou Chemical Industry，2021，49（10）：25-26，62.
16	SHEN Minxian， HUANG Zhujian， LUO Xuewen，et al.Activation of persulfate for tetracycline degradation using the catalyst regenerated from Fenton sludge containing heavy metal：Synergistic effect of Cu for catalysis［J］.Chemical Engineering Journal，2020，396.Doi：10.1016/j.cej.2020.125238 . doi: 10.1016/j.cej.2020.125238
17	周耘，武书彬.Fenton污泥制备聚合硫酸铁的中试试验研究［J］.中国造纸，2019，38（5）：75-81.
	ZHOU Yun， WU Shubin.Pilot study on the preparation of PFS from Fenton treatment sludge［J］.China Pulp & Paper，2019，38（5）：75-81.
18	ZHANG Jinghui， YANG Hong， LI Wei，et al.Variations of sludge characteristics during the advanced anaerobic digestion process and the dewaterability of the treated sludge conditioning with PFS，PDMDAAC and synthesized PFS-PDMDAAC［J］.Water
	Science and Technology：a Journal of the International Association on Water Pollution Research，2018，78（5/6）：1189-1198.
19	阳帆，黄挺，张毅，等.Fenton铁泥制取硫酸亚铁效果与性能研究［J］.工业水处理，2019，39（8）：48-51.
	YANG Fan， HUANG Ting， ZHANG Yi，et al.Study on the effect and properties of ferrous sulfate prepared from Fenton iron sludge［J］.Industrial Water Treatment，2019，39（8）：48-51.
20	张娟.Fenton铁泥制备硫酸亚铁和聚合硫酸铁及其应用研究［D］.南宁：广西大学，2013.
	ZHANG Juan.Fenton iron mud preparation of ferrous sulfate and polymeric ferric sulfate and its application research［D］.Nanning：Guangxi University，2013.
21	王双飞，陈永利，张娟.一种Fenton铁泥资源化利用的方法：中国，103252340A［P］.2013-08-21.
	WANG Shuangfei， CHEN Yongli， ZHANG Juan.A method for resource utilization of Fenton sludge：CN，103252340A［P］.2013-08-21.
22	陈虎魁.利用铁泥和硝化废硫酸制备硫酸亚铁［J］.无机盐工业，2000，32（5）：23.
	CHEN Hukui.Preparation of ferrous sulfate from iron sludge and nitrification waste sulfuric acid［J］.Inorganic Chemicals Industry，2000，32（5）：23.
23	杨东奎，黄文博，朱顺广，等.聚合硫酸铁的制备及二次废渣减量化处理的工艺研究［J］.环境科技，2018，31（1）：30-33.
	YANG Dongkui， HUANG Wenbo， ZHU Shunguang，et al.The pre⁃
	paration of polymerization of ferric sulfate and the process study of the reduction of secondary waste residue［J］.Environmental Sci⁃
	ence and Technology，2018，31（1）：30-33.
24	张丽清，刘新锋，周华锋，等.由工业废料铁泥制备FeSO₄·7H₂O的研究［J］.化学工业与工程，2011，28（1）：35-38，52.
	ZHANG Liqing， LIU Xinfeng， ZHOU Huafeng，et al.Preparation of FeSO₄·7H₂O from iron mud of industry waste［J］.Chemical Industry and Engineering，2011，28（1）：35-38，52.
25	QIANG Zhimin， CHANG J H， HUANG C P.Electrochemical regeneration of Fe²⁺ in Fenton oxidation processes［J］.Water Research，2003，37（6）：1308-1319.
26	WANG Mingwei， ZHAO Zhiqiang， ZHANG Yaobin.Magnetite⁃contained biochar derived from Fenton sludge modulated electron transfer of microorganisms in anaerobic digestion［J］.Journal of Hazardous Materials，2021，403.Doi：10.1016/J.JHAZMAT. 2020.123972 . doi: 10.1016/J.JHAZMAT. 2020.123972
27	王雯婷，郭晓峰，吕伏建.一种芬顿铁泥资源化利用的方法：中国，105836987B［P］.2019-04-02.
	WANG Wenting， GUO Xiaofeng， LV Fujian.A method for resource utilization of Fenton sludge：CN，105836987B［P］.2019-04-02.
28	张树军，李彦刚，金秋燕，等.处理芬顿铁泥的装置和方法：中国，110877956A［J］.2020-03-13.
	ZHANG Shujun， LI Yangang， JIN Qiuyan，et al.Apparatus and method for treating Fenton sludge：CN，110877956A［J］.2020-03-13.
29	郦和生，吴颖，秦会敏，等.一种芬顿铁泥综合循环利用的方法：中国，105327596A［P］.2016-02-17.
	LI Hesheng， WU Ying， QIN Huimin，et al.A method of comprehensive recycling of Fenton sludge：CN，105327596A［P］.2016-02-17.
30	庄晓杰，邓红波，李云，等.一种同步处理Fenton铁泥并获得FePO₄的资源化利用方法：中国，111377558A［P］.2020-07-07.
	ZHAUNG Xiaojie， DENG Hongbo， LI Yun，et al.A resource utilization method for simultaneously processing Fenton sludge and obtaining FePO₄ ：CN，111377558A［P］.2020-07-07.
31	吕伏建，王路峰，田李嘉，等.一种膜法循环利用Fenton铁泥的方法：中国，105776783A［P］.2016-07-20.
	LV Fujian， WANG Lufeng， TIAN Lijia，et al.A membrane method for recycling Fenton sludge：CN，105776783A［P］.2016-07-20.
32	SONG Xin， GE Shifu， LI Yuan.Preparation and performance of sludge⁃based desulfurizer by calcification［J］.IOP Conference Series Earth and Environmental Science，2020，558（4）.Doi：10 . doi: 10
	1088/1755 -1315/558/4/042031. doi: 10
33	刘燕韶，张凤山，冯好伟，等.一种利用造纸废水厂化学污泥制备脱硫剂的方法：中国，109486542A［P］.2019-03-19.
	LIU Yanshao， ZHANG Fengshan， FENG Haowei，et al.A method for preparing desulfurizer from chemical sludge from papermaking wastewater plant：CN，109486542A［P］.2019-03-19.
34	陈伟燕，迟娟，张波，等.一种利用芬顿铁泥制备脱硫剂的方法：中国，110665362A［P］.2020-01-10.
	CHEN Weiyan， CHI Juan， ZHANG Bo，et al.A method of preparing desulfurizer using Fenton sludge：CN，110665362A［P］.2020-
	01-10.
35	Changjin OU， DAI Suwan， LI Shuxuan，et al.Adsorption performance and mechanism investigation of Mn²⁺ by facile synthesized ceramsites from lime mud and coal fly ash［J］.Korean Journal of Chemical Engineering，2021，38（3）：505-513.
36	WU Linjun， LIU Chao， HU Yikun，et al.Dephosphorization using ceramsites modified by coprecipitation with FeSO₄ and KMnO₄ and high⁃temperature combustion［J］.Journal of Water Process Engineering，2020，34.Doi：10.1016/j.jwpe.2020.101162 . doi: 10.1016/j.jwpe.2020.101162
37	FU Pingfeng， CHEN Zihao， YANG Tianwen.Removal of aqueous Cu²⁺ ions with Fe⁰/C ceramsites fabricated by direct reduction roasting of magnetite，coal，and paper mill sludge［J］.Water Science and Technology，2018，78（8）：1753-1761.
38	高宝玉，张飞龙，岳钦艳，等.一种芬顿铁泥阴阳极一体化陶粒及利用芬顿铁泥制备陶粒的方法：中国，106810204B［P］.2020-09-25.
	GAO Baoyu， ZHANG Feilong， YUE Qinyan，et al.A kind of Fenton sludge cathode and anode integrated ceramsite and method for preparing ceramsite by using Fenton sludge：CN，106810204B［P］.2020-09-25.
39	梁标，蔡德所，莫崇勋.利用底泥制备烧胀陶粒技术的研究进展［J］.功能材料，2020，51（11）：11017-11024，11030.
	LIANG Biao， CAI Desuo， MO Chongxun.Technology of manufacturing sintering-expanded ceramsite from sediments［J］.Journal of Functional Materials，2020，51（11）：11017-11024，11030.
40	龚娟.一种环保砖的制备方法：中国，111620614A［P］.2020-09-04.
	GONG Juan.A kind of preparation method of environmental protection brick：CN，111620614A［P］.2020-09-04.
41	ABDUL KADIR A， HALIM M K K， SARANI N A，et al.Leachability of heavy metals from steel mill sludge incorporated in fired clay brick［J］.Materials Science Forum，2016，857：347-351.
42	周超群.生态透水环保砖的制备及性能研究［D］.广州：华南理工大学，2018.
	ZHOU Chaoqun.Preparation and characterization of eco⁃premeable environmental brick［D］.Guangzhou：South China University of Technology，2018.
43	UKWATTA A， MOHAJERANI A.Effect of organic content in biosolids on the properties of fired⁃clay bricks incorporated with biosolids［J］.Journal of Materials in Civil Engineering，2017，29（7）.Doi：10.1061/（ASCE）MT.1943-5533.0001865 . doi: 10.1061/（ASCE）MT.1943-5533.0001865
44	周星辰，王璟奕.一种工业危废污泥制作环保砖的一体化技术：中国，109896790A［P］.2019-06-18.
	ZHOU Xingchen， WANG Jingyi.An integrated technology for making environmentally friendly bricks from industrial hazardous waste sludge：CN，109896790A［P］.2019-06-18.
45	BALDI M， MARTINOTTI A， SORLINI S，et al.Extraction and purification of phosphorus from the ashes of incinerated biological sewage sludge［J］.Water，2021，13（8）：1102-1112.
46	PANEQUE M， DE LA ROSA J M， PATTI A F，et al.Changes in the bio⁃availability of phosphorus in pyrochars and hydrochars derived from sewage sludge after their amendment to soils［J］.Agto⁃ nomy，2021，11（4）：623-635.
47	LAW K P， PAGILLA K R.A solution to the limited global phosphorus supply：Regionalization of phosphorus recovery from sewage sludge ash［J］.Journal of Cleaner Production，2021，290（2）.Doi：10.1016/J.JCLEPRO.2021.125874 . doi: 10.1016/J.JCLEPRO.2021.125874
48	XIAO Keke， YU Zecong， WANG Hui，et al.Investigation on emission control of NO _x precursors and phosphorus reclamation during pyrolysis of ferric sludge［J］.Science of the Total Environment，2019，670：932-940.
49	BURGOS-CASTILLO R， SILLANPÄÄ M， BRILLAS E，et al.Removal of metals and phosphorus recovery from urban anaerobically digested sludge by electro-Fenton treatment［J］.Science of the Total Environment，2018，644：173-182.
50	杜庆洋，于华芹，熊春月，等.一种利用芬顿铁泥制备高孔隙率臭氧氧化nbsCOD催化剂的方法：中国，108855084A［P］.2018-11-23.
	DU Qingyang， YU Huaqin， XIONG Chunyue，et al.A method for preparing high⁃porosity ozone oxidation nbsCOD catalyst by using Fenton sludge：CN，108855084A［P］.2018-11-23.
51	SANCHIS R， DEJOZ A， VÁZQUEZ I，et al.Ferric sludge derived from the process of water purification as an efficient catalyst and/or support for the removal of volatile organic compounds［J］.Chemosphere，2019，219：286-295.
52	ZHANG He， XUE Gang， CHEN Hong，et al.Magnetic biochar catalyst derived from biological sludge and ferric sludge using hydrothermal carbonization：Preparation，characterization and its circulation in Fenton process for dyeing wastewater treatment［J］.Chemosphere，2018，191：64-71.

[1]	YAO Jiankang, HU Shuozhen, NIU Dongfang, WU Jianping, ZHANG Xinsheng. Study on electrochemical treatment of sodium chloride organic waste salt in spice industry [J]. Inorganic Chemicals Industry, 2024, 56(3): 105-115.
[2]	YANG Fengling, QIAO Guoxin, YANG Pu, REN Lei, WANG Qiong, WU Haibin, CHENG Fangqin. Research progress and application of α-hemihydrate gypsum preparation from desulfurization gypsum [J]. Inorganic Chemicals Industry, 2024, 56(2): 11-20.
[3]	PEI Hongchang, YUE Maowen, LIU Jianlu, LI Zhongfang, CHEN Xiaoyu. Research progress of comprehensive development and efficient utilization of seawater [J]. Inorganic Chemicals Industry, 2024, 56(2): 21-29.
[4]	LI Yan, MA Zhen, SONG Xingfu. New development advance and industrial development proposals of chloride-type salt lake potassium resources in Qinghai [J]. Inorganic Chemicals Industry, 2023, 55(8): 84-90.
[5]	LI Yu, ZHAO Wei, ZHANG Xinghua, WANG Rui, YAN Bingji, GUO Hongwei. Syudy on preparation of high-strength ceramsite from fluorite tailings and its properties [J]. Inorganic Chemicals Industry, 2023, 55(5): 100-108.
[6]	LU Dachuan, GU Weihua, ZHAO Jing, ZHUANG Xuning, DONG Bin, BAI Jianfeng. Research progress of influencing factors of pyrolysis of municipal sludge and residue recycling [J]. Inorganic Chemicals Industry, 2023, 55(5): 8-15.
[7]	JIN Suna, LÜ Ruiliang. Research and application progress of wet flue gas desulfurization wastewater treatment technology [J]. Inorganic Chemicals Industry, 2023, 55(4): 27-37.
[8]	WEN Yuan, ZHOU Chenliang, ZHANG Qiang, YU Linfei, HE Wenxiu, LIU Quansheng. Research progress of electronic and structure promoters of iron-based catalysts for FTO reaction [J]. Inorganic Chemicals Industry, 2023, 55(3): 36-46.
[9]	XU Wenzhen,LI Canhua,JI Hongfeng,LI Zimu,WU Zhaoyang,LI Minghui. Research progress of red mud in field of recycled metals and building materials [J]. Inorganic Chemicals Industry, 2023, 55(2): 10-18.
[10]	JIANG Ziwen,QUAN Xuejun,LI Gang,LU Cunfang,GUO Yijun,CHEN Hao,ZHOU Yankuo,CHENG Zhiliang. Research progress of resource utilization of chromium slag [J]. Inorganic Chemicals Industry, 2023, 55(2): 26-35.
[11]	XU Enhao, WU Kaipeng. Research progress of preparation and application of nano-sized chromium oxide [J]. Inorganic Chemicals Industry, 2023, 55(10): 24-34.
[12]	LI Li,LI Yu,JIN Yan,QIU Jun,YANG Ying,ZHANG Yonghong,XIAO Fang,YU Jianguo. Key technology and application of lithium extraction from produced water in high sulfur and high hardness gas fields [J]. Inorganic Chemicals Industry, 2023, 55(1): 74-80.
[13]	WANG Ping. Quantitative analysis of linkage between lithium supply and demand and lithium price [J]. Inorganic Chemicals Industry, 2022, 54(9): 1-13.
[14]	MIAO Linping,XU Miao,WANG Xinlong,YAN Zhengjuan,XU Dehua,YANG Jingxu. Study on preparation of calcium magnesium polyphosphate [J]. Inorganic Chemicals Industry, 2022, 54(9): 63-68.
[15]	KUANG Xinliang,LIU Chuixiang,XIONG Peng. Industry analysis and market prospect of lithium ion battery [J]. Inorganic Chemicals Industry, 2022, 54(8): 12-19.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Research progress on resource utilization of Fenton sludge

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 7

References 52

Related Articles 15

Metrics

Comments

Recommended 0